Dramatically enhanced cleavage of the C-C bond using an electrocatalytically coupled reaction

Journal of the American Chemical Society

Volumn 134, Issue 20, 2012, Pages 8655-8661

  He, Qinggang ^a,d   Shyam, Badri ^b,e   MacOunová, Kateřina ^c   Krtil, Petr ^c   Ramaker, David ^b   Mukerjee, Sanjeev ^a  

^a NORTHEASTERN UNIVERSITY   (United States)

^b GEORGE WASHINGTON UNIVERSITY   (United States)

^c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^d LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^e ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC ALCOHOL; AQUEOUS MEDIA; C-C BONDS; CATALYST SURFACES; CO OXIDATION; COCATALYST; COUPLED REACTION; DIRECT ACTIVATION; ELECTROCATALYTIC; FULL OXIDATION; HIGH PH; LOW TEMPERATURES; OVER POTENTIAL; TIME-SCALES;

ADSORPTION; CARBON DIOXIDE; ELECTROCATALYSIS; ETHANOL; LEAD; VOLATILE FATTY ACIDS;

CATALYST SELECTIVITY;

ALCOHOL; ALKANOL; CARBON; CARBON DIOXIDE; CARBON MONOXIDE; HYDROXIDE; LEAD ACETATE; LEAD HYDROXIDE; UNCLASSIFIED DRUG;

ADSORPTION; AMPEROMETRY; AQUEOUS SOLUTION; ARTICLE; CARBON BOND; CATALYSIS; CATALYST; CHEMICAL BOND; CHRONOAMPEROMETRY; CONTROLLED STUDY; CYCLIC POTENTIOMETRY; ELECTROCATALYTIC CARBON BOND SPLITTING; ELECTROCHEMISTRY; ELECTROOXIDATION; LOW TEMPERATURE; OXIDATION; PH; REACTION TIME; SURFACE PROPERTY;

EID: 84861403612     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja301992h     Document Type: Article

References (44)

1. Bocarsly, A. B.; Barton, E. E. Abstracts of Papers, 237th ACS National Meeting, Salt Lake City, UT, United States, March 22-26, 2009; American Chemical Society: Washington, DC, 2009; INOR-632.
2. Kim, I.; Han, O. H.; Chae Seen, A.; Paik, Y.; Kwon, S.-H.; Lee, K.-S.; Sung, Y.-E.; Kim, H. Angew. Chem., Int. Ed. 2011, 50, 2270-2274
3. Antolini, E. J. Power Sources 2007, 170, 1-12
4. Corma, A.; Diaz-Cabanas, M. J.; Martinez-Triguero, J.; Rey, F.; Rius, J. Nature (London, U.K.) 2002, 418, 514-517
5. Lai, S. C. S.; Koper, M. T. M. Faraday Discuss. 2008, 140, 399-416
6. Wang, H.; Jusys, Z.; Behm, R. J. J. Power Sources 2006, 154, 351-359
7. Jiang, L.; Colmenares, L.; Jusys, Z.; Sun, G. Q.; Behm, R. J. Electrochim. Acta 2007, 53, 377-389
8. Wang, H.; Zhao, Y.; Jusys, Z.; Behm, R. J. J. Power Sources 2006, 155, 33-46
9. Lai Stanley, C. S.; Koper Marc, T. M. Phys. Chem. Chem. Phys. 2009, 11, 10446-10456
10. Tripkovic, A. V.; Popovic, K. D.; Grgur, B. N.; Blizanac, B.; Ross, P. N.; Markovic, N. M. Electrochim. Acta 2002, 47, 3707-3714
11. Rao, V.; Hariyanto; Cremers, C.; Stimming, U. Fuel Cells (Weinheim, Ger.) 2007, 7, 417-423
12. Mondelli, C.; Grunwaldt, J.-D.; Ferri, D.; Baiker, A. Phys. Chem. Chem. Phys. 2010, 12, 5307-5316
13. Mondelli, C.; Ferri, D.; Grunwaldt, J.-D.; Krumeich, F.; Mangold, S.; Psaro, R.; Baiker, A. J. Catal. 2007, 252, 77-87
14. Grunwaldt, J.-D.; Caravati, M.; Baiker, A. J. Phys. Chem. B 2006, 110, 25586-25589
15. Haan, J. L.; Masel, R. I. ECS Trans. 2008, 16, 627-638
16. Cuesta, A. ChemPhysChem 2011, 12, 2375-2385
17. Xu, C.; Shen, P. K.; Ji, X.; Zeng, R.; Liu, Y. Electrochem. Commun. 2005, 7, 1305-1308
18. Xu, C.; Shen Pei, K. Chem. Commun. (Cambridge, U.K.) 2004, 2238-2239
19. Bai, Y.; Wu, J.; Xi, J.; Wang, J.; Zhu, W.; Chen, L.; Qiu, X. Electrochem. Commun. 2005, 7, 1087-1090
20. Kowal, A.; Li, M.; Shao, M.; Sasaki, K.; Vukmirovic, M. B.; Zhang, J.; Marinkovic, N. S.; Liu, P.; Frenkel, A. I.; Adzic, R. R. Nat. Mater. 2009, 8, 325-330
21. Schmiemann, U.; Mueller, U.; Baltruschat, H. Electrochim. Acta 1995, 40, 99-107
22. Gomes Janaina, F.; Busson, B.; Tadjeddine, A. J. Phys. Chem. B 2006, 110, 5508-5514
23. Li, G.; Pickup, P. G. Electrochim. Acta 2006, 52, 1033-1037
24. McBreen, J.; O'Grady, W. E.; Pandya, K. I.; Hoffman, R. W.; Sayers, D. E. Langmuir 1987, 3, 428-433
25. Newville, M. J. Synchrotron Radiat. 2001, 8, 322-324
26. Newville, M.; Livins, P.; Yacoby, Y.; Stern, E. A.; Rehr, J. J. Phys. Rev. B 1993, 47, 14126
27. Scott, F. J.; Mukerjee, S.; Ramaker, D. E. J. Phys. Chem. C 2010, 114, 442-453
28. Teliska, M.; O'Grady, W. E.; Ramaker, D. E. J. Phys. Chem. B 2004, 108, 2333-2344
29. Teliska, M.; O'Grady, W. E.; Ramaker, D. E. J. Phys. Chem. B 2005, 109, 8076-8084
30. van Dorssen, G. E.; Koningsberger, D. C.; Ramaker, D. E. J. Phys.: Condens. Matter 2002, 14, 13529-13541
31. Ankudinov, A. L.; Ravel, B.; Rehr, J. J.; Conradson, S. D. Phys. Rev. B: Condens. Matter Mater. Phys. 1998, 58, 7565-7576
32. Arruda, T. M.; Shyam, B.; Ziegelbauer, J. M.; Mukerjee, S.; Ramaker, D. E. J. Phys. Chem. C 2008, 112, 18087-18097
33. Janin, E.; von Schenck, H.; Gothelid, M.; Karlsson, U. O.; Svensson, M. Phys. Rev. B: Condens. Matter Mater. Phys. 2000, 61, 13144-13149
34. Wang, H.-F.; Liu, Z.-P. J. Am. Chem. Soc. 2008, 130, 10996-11004
35. Souza-Garcia, J.; Herrero, E.; Feliu, J. M. ChemPhysChem 2010, 11, 1391-1394
36. Lai, S. C. S.; Kleijn, S. E. F.; Oeztuerk, F. T. Z.; van Rees Vellinga, V. C.; Koning, J.; Rodriguez, P.; Koper, M. T. M. Catal. Today 2010, 154, 92-104
37. Melke, J.; Schoekel, A.; Dixon, D.; Cremers, C.; Ramaker, D. E.; Roth, C. J. Phys. Chem. C 2010, 114, 5914-5925
38. Pourbaix, M. Atlas of Electrochemical Equilibria in Aqueous Solutions; National Association of Corrosion Engineers: Houston, TX, 1974.
39. Lai, S. C. S.; Kleijn, S. E. F.; Oeztuerk, F. T. Z.; van Rees Vellinga, V. C.; Koning, J.; Rodriguez, P.; Koper, M. T. M. Catal. Today 2010, 154, 92-104
40. Markovic, N. M.; Lucas, C. A.; Rodes, A.; Stamenkovic, V.; Ross, P. N. Surf. Sci. 2002, 499, L149-L158
41. Scott, F. J.; Mukerjee, S.; Ramaker, D. E. J. Electrochem. Soc. 2007, 154, A396-A406
42. Bus, E.; Ramaker, D. E.; van Bokhoven, J. A. J. Am. Chem. Soc. 2007, 129, 8094-8102
43. Strmcnik, D.; Kodama, K.; van der Vliet, D.; Greeley, J.; Stamenkovic, V. R.; Markovic, N. M. Nat. Chem. 2009, 1, 466-472
44. Marken, F.; Leslie, W. M.; Compton, R. G.; Moloney, M. G.; Sanders, E.; Davies, S. G.; Bull, S. D. J. Electroanal. Chem. 1997, 424, 25-34