Oil-in-alcohol highly concentrated emulsions as templates for the preparation of macroporous materials

Langmuir

Volumn 28, Issue 20, 2012, Pages 7614-7621

  Vílchez, Susana ^a   Pérez Carrillo, Lourdes A ^a,b   Miras, Jonathan ^a   Solans, Conxita ^a   Esquena, Jordi ^a  

^a BIOMATERIALES Y NANOMEDICINA CIBER BBN   (Spain)

^b UNIVERSITY OF GUADALAJARA   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

DROPLET SIZES; EXTERNAL PHASE; HIGHLY CONCENTRATED EMULSION; INTERCONNECTED NETWORK; INTERNAL STRUCTURE; LASER DIFFRACTIONS; MACROPOROUS; MACROPOROUS MATERIALS; OIL PHASE; ONE-STEP METHODS; POLYFURFURYL ALCOHOLS;

DROPS; MONOLITHIC INTEGRATED CIRCUITS; OPTICAL MICROSCOPY; POROUS MATERIALS; SCANNING ELECTRON MICROSCOPY; SURFACE ACTIVE AGENTS;

CONCENTRATION (PROCESS);

ALCOHOL DERIVATIVE; FURAN DERIVATIVE; FURFURYL ALCOHOL; OIL; POLYMER;

ARTICLE; CHEMISTRY; EMULSION; POROSITY;

ALCOHOLS; EMULSIONS; FURANS; OILS; POLYMERS; POROSITY;

EID: 84861378934     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la205018z     Document Type: Article

References (48)

1. Lissant, K. J. The geometry of high-internal-phase-ratio emulsions J. Colloid Interface Sci. 1966, 22, 462-468
2. Lissant, K. J.; Mayhan, K. G. A study of medium and high internal phase ratio water/polymer emulsions J. Colloid Interface Sci. 1973, 42, 201-208
3. Princen, H. M. Highly concentrated emulsions. I. Cylindrical systems J. Colloid Interface Sci. 1979, 71, 55-66
4. Kunieda, H.; Fukui, Y.; Uchiyama, H.; Solans, C. Spontaneous formation of highly concentrated water-in-oil emulsions (gel-emulsions) Langmuir 1996, 12, 2136-2140
5. Solans, C.; Pons, R.; Kunieda, H. In Modern Aspects of Emulsion Science; Binks, B.P., Ed.; Royal Society of Chemistry: Cambridge, 1998.
6. Solans, C.; Esquena, J.; Azemar, N.; Rodríguez, C.; Kunieda, H. In Emulsions: Structure, Stability and Interactions; Petsev, D.N., Ed.; Elsevier: Amsterdam, 2004.
7. Barby, D.; Haq, Z. Low density porous cross-linked polymeric materials and their preparation. European patent 0060138, 1982.
8. Williams, J. M.; Wrobleski, D. A. Spatial distribution of the phases in water-in-oil emulsions. Open and closed microcellular foams form cross-linked polystyrene Langmuir 1988, 4, 656-662
9. Williams, J. M. Toroidal microstructures from water-in-oil emulsions Langmuir 1988, 4, 44-49
10. Ruckenstein, E.; Park, J. S. Hydrophilic-hydrophobic polymer composites J. Polym. Sci., Polym. Lett. 1988, 26, 529-536
11. Hainey, P.; Huxham, I. M.; Rowatt, B.; Sherrington, D. C.; Tetley, L. Synthesis and ultrastructural studies of styrene-divinylbenzene polyHIPE polymers Macromolecules 1991, 24, 117-121
12. Ruckenstein, E.; Park, J. S. Stable concentrated emulsions as precursors for hydrophilic-hydrophobic polymers composites Polymer 1992, 33, 405-417
13. Cameron, N. R.; Sherrington, D. C.; Albiston, L.; Gregory, D. P. Study of the formation of the open-cellular morphology of poly(styrene/divinylbenzene) polyHIPE materials by cryo-SEM Colloid Polym. Sci. 1996, 274, 592-595
14. Cameron, N. R.; Sherrington, D. C. High Internal Phase Emulsions (HIPEs) - Structure, Properties and Use in Polymer Preparation Adv. Polym. Sci. 1996, 126, 163-214
15. Esquena, J.; Sankar, G. S. R. R.; Solans, C. Highly concentrated W/O emulsions prepared by the PIT method as templates for solid foams Langmuir 2003, 19, 2983-2988
16. Maekawa, H.; Esquena, J.; Bishop, S.; Solans, C.; Chmelka, B. F. Meso/macroporous inorganic oxide monoliths from polymer foams Adv. Mater. 2003, 15, 591-596
17. Esquena, J.; Solans, C. In Emulsions and emulsion stability; Sjöblom, J., Ed.; Surfactant Science Series; Francis & Taylor: New York, 2006.
18. Solans, C.; Esquena, J.; Azemar, N. Highly concentrated (gel) emulsions, versatile reaction media Curr. Opin. Colloid Interface Sci. 2003, 8, 156-163
19. Lépine, O.; Birot, M.; Deleuze, H. Preparation of a poly(furfuryl alcohol)-coated highly porous polystyrene matrix Macromol. Mater. Eng. 2009, 294, 599-604
20. Menner, A.; Powell, R.; Bismarck, A. Open porous polymer foams via inverse emulsion polymerization: Should the definition of high phase (ratio) emulsions be extended? Macromolecules 2006, 39, 2034-2035
21. Ikem, V. O.; Menner, A.; Bismarck, A. High internal phase emulsions stabilized solely by functionalized silica particles Angew. Chem., Int. Ed. 2008, 47, 8277-8279
22. Imhof, A.; Pine, D. J. Ordered macroporous materials by emulsion templating Nature 1997, 389, 948-951
23. Yi, G. R.; Moon, J. H.; Manoharan, V. N.; Pine, D. J.; Yang, S. M. Packings of uniform microspheres with ordered macroporous fabricated by double templating J. Am. Chem. Soc. 2002, 124, 13354-13355
24. Carn, F.; Colin, A.; Achard, M. F.; Deleuze, H.; Sellier, E.; Birot, M.; Backov, R. Inorganic monoliths hierarchically textured via concentrated direct emulsion and micellar templates J. Mater. Chem. 2004, 14, 1370-1376
25. Ungureanu, S.; Birot, M.; Laurent, G.; Deleuze, H.; Babot, O.; Julián-López, B.; Achard, M. F.; Popa, M. I.; Sanchez, C.; Backov, R. One-pot synthesis of the first series of emulsion based hierarchical hybrid organic-inorganic open-cell monolith possessing tunable functionally (organo-Si(HIPE) series) Chem. Mater. 2007, 19, 5786-5796
26. Brun, N.; Prabaharan, S. R. S.; Surcin, C.; Morcrette, M.; Deleuze, H.; Birot, M.; Babot, O.; Achard, M. F.; Backov, R. Design of hierarchical porous carbonaceous foams a dual-template approach and their use as electrochemical capacitor and Li ion battery negative electrodes J. Phys. Chem. C 2012, 116, 1408-1421
27. Binks, B. P. Macroporous silica from solid-stabilized emulsion templates Adv. Mater. 2002, 14, 1824-1827
28. Chiu, J. J.; Pine, D. J.; Bishop, S. T.; Chmelka, B. F. Friedel-Crafts alkylation properties of aluminosilica SBA-15 meso/macroporous monoliths and mesoporous powders J. Catal. 2004, 221, 400-412
29. Sen, T.; Tiddy, G. J. T.; Casci, J. L.; Anderson, M. W. Meso-cellular silica foams, macro-cellular silica foams and mesoporous solids: A study of emulsion-mediated synthesis Microporous Mesoporous Mater. 2005, 78, 255-263
30. Blin, J. L.; Bleta, R.; Ghanbaja, J.; Stébé, M. J. Fluorinated emulsions: Templates for the direct preparation of macroporous-mesoporous silica with a highly ordered array of large mesopores Microporous Mesoporous Mater. 2006, 94, 74-80
31. Sen, T.; Tiddy, G. J. T.; Casci, J. L.; Anderson, M. W. Silica materials with meso- and macropores. WO/2003/064322 Patent Application, 2003.
32. Hu, Y.; Nareen, M.; Humphries, A.; Christian, P. A novel preparation of macroscopic beads of porous silica J. Sol-Gel Sci. Technol. 2010, 53, 300-306
33. Fournier, A. C.; McGrath, K. M. Synthesis of porous oxide ceramics using a soft responsive scaffold J. Mater. Sci. 2012, 47, 1217-1222
34. Franklin, R. E. Crystalline growth in graphitizing and non-graphitizing carbons Proc. R. Soc. London 1951, 209, 196-218
35. Liu, D.; Lei, J. H.; Guo, L. P.; Qu, D.; Li, Su, B.L. One-pot aqueous route to synthesize highly ordered cubic and hexagonal mesoporous carbons from resorcinol and hexamine Carbon 2012, 50, 476-487
36. Fitzer, E.; Schaefer, W.; Yamada, S. The formation of glasslike carbon by pyrolysis of polyfurfuryl alcohol and phenolic resin Carbon 1969, 7, 643-646
37. Zarbin, A. J. G.; Bertholdo, R.; Oliveira, M. A. F. C. Preparation, characterization and pyrolysis of poly(furfuryl alcohol)/porous silica glass nanocomposites: novel route to carbon template Carbon 2002, 40, 2413-2422
38. Bertarione, S.; Bonino, F.; Cesano, F.; Jain, S.; Zanetti, M.; Scarano, D.; Zecchina, A. Micro-FTIR and micro-raman studies of a carbon film prepared from furfuryl alcohol polymerization J. Phys. Chem. C 2009, 113, 10571-10574
39. Shirahama, K.; Kashiwabara, T. The CMC-decreasing effects of some added alcohols on the aqueous sodium dodecyl sulfate solutions J. Colloid Interface Sci. 1971, 36, 65-70
40. Singh, H. N.; Swarup, S. Effect of monohydroxy alcohols and urea on the cmc of surfactants Bull. Chem. Soc. Jpn. 1978, 51, 1534-1538
41. Zana, R. Aqueous surfactant-alcohol systems: A review Adv. Colloid Interface Sci. 1995, 57, 1-64
42. The Merck Index: an encyclopedia of chemical drugs, and biologicals, 11 th ed.; Budavari, S., Ed; Merck & Co. Inc.: Rahway, NJ, 1989.
43. álvarez, S.; Fuertes, A. B.; Esquena, J.; Solans, C. Meso/macroporous carbon monoliths from polymeric foams Adv. Mater. 2004, 6, 897-899
44. álvarez, S.; Fuertes, A. B. Synthesis of macro/mesoporous silica and carbon monoliths by using a commercial polyurethane foam as sacrificial template Mater. Lett. 2007, 61, 2378-2381
45. Brunauer, S.; Emmett, P. H.; Teller, E. Adsorption of gases in multimolecular layers J. Am. Chem. Soc. 1938, 60, 309-319
46. Barrett, E. P.; Joyner, L. G.; Halenda, P. H. The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms J. Am. Chem. Soc. 1951, 73, 373-380
47. Bancroft, W. D. The theory of emulsification, V J. Phys. Chem. 1913, 17, 501-519
48. Burket, C. L.; Rajagopalan, R.; Marencic, A. P.; Dronvajjala, K.; Foley, H. C. Genesis of porosity in polyfurfuryl alcohol derived nanoporous carbon Carbon 2006, 44, 2957