35Cl/ 37Cl isotope effects in 103Rh NMR of [RhCl n(H 2O) 6-n] 3-n complex anions in hydrochloric acid solution as a unique 'NMR finger-print' for unambiguous speciation

Analytica Chimica Acta

Volumn 730, Issue , 2012, Pages 93-98

  Geswindt, Theodor E ^a   Gerber, Wilhelmus J ^a   Brand, D Jacobus ^a   Koch, Klaus R ^a  

^a STELLENBOSCH UNIVERSITY   (South Africa)

Author keywords

103Rh NMR; 35Cl 37Cl isotope effects in RhCl n(H 2O) 6 n 3 n complexes; Direct 103Rh NMR speciation; Isotopologues and isotopomers in NMR

Indexed keywords

ACIDIC SOLUTIONS; ASSIGNMENT OF; COMPLEX ANIONS; DIRECT 103RH NMR SPECIATION; DIRECT IDENTIFICATIONS; FINE STRUCTURES; HYDROCHLORIC ACID SOLUTION; ISOTOPE EFFECT; ISOTOPOLOGUES; ISOTOPOMER DISTRIBUTIONS; ISOTOPOMERS; LINE SHAPE; RESONANCE STRUCTURE;

CARRIER MOBILITY; CHEMICAL SHIFT; CHLORINE COMPOUNDS; HYDROCHLORIC ACID; ISOTOPES; RESONANCE; RHODIUM; STEREOCHEMISTRY;

RHODIUM COMPOUNDS;

CHLORINE; CHLORINE 37; HYDROCHLORIC ACID; RADIOISOTOPE; RHODIUM 103; RHODIUM COMPLEX; UNCLASSIFIED DRUG;

ACCURACY; AQUEOUS SOLUTION; ARTICLE; COMPLEX FORMATION; CONTROLLED STUDY; IONIC STRENGTH; ISOTOPE ANALYSIS; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; RADIOISOTOPE DISTRIBUTION; STEREOISOMERISM; TEMPERATURE SENSITIVITY;

EID: 84861347337     PISSN: 00032670     EISSN: 18734324     Source Type: Journal    
DOI: 10.1016/j.aca.2012.02.009     Document Type: Article

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