Semicontinuous heterophase polymerization of methyl methacrylate in the presence of reactive surfactant HITENOL BC10

Polymer Bulletin

Volumn 68, Issue 9, 2012, Pages 2313-2322

  Ovando Medina, Víctor M ^a   Piña García, Piedad S ^a   Corona Rivera, Miguel A ^a   Díaz Flores, Paola E ^a   Peralta, René D ^b   Martínez Gutiérrez, Hugo ^c   Lara Ceniceros, Tania E ^d  

^a UNIVERSIDAD AUTÓNOMA DE SAN LUIS POTOSÍ   (Mexico)

^b CENTRO DE INVESTIGACIÓN EN QUÍMICA APLICADA   (Mexico)

^c INSTITUTO POLITÉCNICO NACIONAL   (Mexico)

^d Parque Industrial de Investigación e Innovación Tecnológica   (Mexico)

Author keywords

Heterophase polymerization; Hitenol; Nanoparticles; Reactive surfactant

Indexed keywords

AVERAGE MOLECULAR WEIGHT; CONSTANT RATE; CONTINUOUS MODE; HETEROPHASE POLYMERIZATION; HITENOL; METHYL METHACRYLATES; PARTICLE DIAMETERS; PARTICLE STABILIZATION; POLYDISPERSITY INDICES; POLYMER CONTENT; POTASSIUM PERSULFATE; REACTIVE SURFACTANTS; SEMI-CONTINUOUS; SODIUM DODECYL SULFATE; WEIGHT RATIOS;

ESTERS; NANOPARTICLES; POLYMERIZATION; POTASSIUM; SODIUM; SODIUM SULFATE; SURFACE ACTIVE AGENTS;

ACRYLIC MONOMERS;

EID: 84861340951     PISSN: 01700839     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00289-012-0726-x     Document Type: Article

References (20)

1. Ovando-Medina VM, Peralta RD, Mendizábal E, Martínez- Gutiérrez H, Corona-Rivera MA (2011) Microemulsion copolymerization of vinyl acetate and butyl acrylate using a mixture of anionic and non-ionic surfactants. Polym Bull 66:133-146
2. Pavel Florentina M (2004) Microemulsion polymerization. J Disp Sci Tech 25:1-16
3. Ovando-Medina VM, Peralta RD, Mendizábal E (2009) Semicontinuous microemulsion copolymerization of vinyl acetate and butyl acrylate: high solid content and effect of monomer addition rate. Colloid Polym Sci 287:561
4. Ledezma R, Treviño ME, Elizalde LE, Pérez-Carrillo LA, Mendizábal E, Puig JE, López RG (2007) Semicontinuous heterophase polymerization under monomer starved conditions to prepare nano-particles with narrow size distribution. J Polym Sci A 45:1463
5. Esquivel O, Treviño ME, Saade H, Puig JE, Mendizábal E, López RG (2011) Mesoporous polystyrene nanoparticles synthesized by semicontinuous heterophase polymerization. Polym Bull 67:217-226
6. Asua JM (2004) Emulsion polymerization: from fundamental mechanisms to process developments. J Polym Sci A 42:1025-1041 (Pubitemid 38302450)
7. Lai Z, Sudol ED, Dimonie VL, El-Aasser MS (2005) Determination of the extent of incorporation of a reactive surfactant in polystyrene latex particles via GPC. J Polym Sci A 43:2675-2678 (Pubitemid 40860144)
8. Lai Z, Sudol ED, Dimonie VL, El-Aasser MS (2008) Kinetics of emulsion polymerization of styrene using the reactive surfactant HITENOL BC20. J App Polym Sci 109:2275-2282
9. Guyot A, Tauer K (2001) Polymerizable and polymeric surfactants. In: Texter J (ed) Reactions and synthesis in surfactant systems. Marcel Dekker, New York, pp 547-575
10. Huang H, Lu D, Sheng L, Guan R (2008) Reactive surfactant in the emulsion copolymerization of methyl methacrylate and octyl acrylate. J Macromol Sci A 45:242-247 (Pubitemid 351205596)
11. Guyot A (2002) Recent progress in reactive surfactants in emulsion polymerization. Macromol Symp 179:105-132
12. Hu W, Sarveswaran K, Lieberman M, Bernstein GH (2004) Sub-10 nm electron beam lithography using cold development of poly(methylmethacrylate). J Vac Sci Technol, B 22:1711-1716
13. Hailer I, Feder R, Hatzakis M, Spiller E (1979) Copolymers of methyl methacrylate and methacrylic acid and their metal salts as radiation sensitive resists. J Electrochem Soc 126:154-161 (Pubitemid 9420234)
14. Fischer PB, Chou SY (1993) 10 nm electron beam lithography and sub-50 nm overlay using a modified scanning electron microscope. Appl Phys Lett 62:2989-2991
15. Allara DL, Baca A, Pryde CA (1978) Distortions of band shapes in external reflection infrared spectra of thin polymer films on metal substrates. Macromolecules 11:1215-1220
16. Zhang JM, Shen DY (2002) Near-infrared SERS study of the adsorption of a PMMA dip-coated onto silver mirror substrate. Chinese Chem Lett 13:563-566 (Pubitemid 40767432)
17. Dimonie VL, Sudol ED, El-Aasser MS (2008) Role of surfactants in emulsion polymerization polymers by design. Rev Chim (Bucureti) 59:1218-1221
18. Urquiola MB, Dimonie VL, Sudol ED, El-Aasser MS (1992) Emulsion polymerization of vinyl acetate using a polymerizable surfactant. I. Kinetic studies. J Polym Sci A 30:2619-2629 (Pubitemid 23576494)
19. Urquiola MB, Dimonie VL, Sudol ED, El-Aasser MS (1992) Emulsion polymerization of vinyl acetate using a polymerizable surfactant. II. Polymerization mechanism. J Polym Sci A 30:2631-2644 (Pubitemid 23576493)
20. Aguilar J, Rabelero M, Nuño-Donlucas SM, Mendizábal E, Martínez-Richa A, López RG, Arellano M, Puig JE (2011) Narrow size-distribution poly(methyl methacrylate) nanoparticles made by semicontinuous heterophase polymerization. J Appl Polym Sci 119:1827-1834