Volumetric properties of binary mixtures of glycerol + tert-butanol over the temperature range 293.15 to 348.15 K at atmospheric pressure

Journal of Solution Chemistry

Volumn 41, Issue 3, 2012, Pages 536-554

  Egorov, Gennadiy I ^a   Makarov, Dmitriy M ^a  

^a INSTITUTE OF SOLUTION CHEMISTRY   (Russian Federation)

Author keywords

Density; Excess molar volume; Glycerol; Partial molar property; Tert butanol; Thermal isobaric expansivities

Indexed keywords

EID: 84861228084     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-012-9813-8     Document Type: Article

References (77)

1. Towey, J. J., Soper, A. K., Dougan, L.: The structure of glycerol in the liquid state: a neutron diffraction study. Phys. Chem. Chem. Phys. 13, 9397-9406 (2011)
2. Champeney, D. C., Joarder, R. N., Dore, J. C.: Structural studies of liquid D-glycerol by neutrondiffraction. Mol. Phys. 58, 337-347 (1986)
3. Chelli, R., Gervasio, F. L., Gellini, C., Procacci, P., Cardini, G., Schettino, V.: Density functional calculation of structural and vibrational properties of glycerol. J. Phys. Chem. A 104, 5351-5357 (2000)
4. Chelli, R., Procacci, P., Cardini, G., Della Valle, R. G., Califano, S.: Glycerol condensed phases Part I. A molecular dynamics study. Phys. Chem. Chem. Phys. 1, 871-877 (1999)
5. van Koningsveld, H.: The crystal structure of glycerol and its conformation. Recl. Trav. Chim. Pays-Bas. 87, 243-254 (1968)
6. Dawidowski, J., Bermejo, F. J., Fayos, R., Perea, R. F., Bennington, S. M., Criado, A.: Coherent neutron scattering response from glassy glycerol. Phys. Rev. E 53, 5079-5088 (1996) (Pubitemid 126598783)
7. Garawia, M., Dorea, J. C., Champeney, D. C.: Structural studies of liquid D-glycerol II. Molecular conformation and long range correlations. Mol. Phys. 62, 475-487 (1987)
8. Dashnau, J. L., Nucci, N. V., Sharp, K. A., Vanderkooi, J. M.: Hydrogen bonding and the cryoprotective properties glycerol/water mixtures. J. Phys. Chem. B 110, 13670-13677 (2006) (Pubitemid 44115607)
9. 13C NMR spectroscopy. J. Chem. Phys. 130, 194506-194506-5 (2009)
10. Marcus, Y.: Some thermodynamic and structural aspects of mixtures of glycerol with water. Phys. Chem. Chem. Phys. 2, 4891-4896 (2000)
11. 2O: towards understanding the Hofmeister series (V). J. Solution Chem. 40, 93-105 (2011)
12. Zelent, B., Nucci, N. V., Vanderkooi, J. M.: Liquid and ice water and glycerol/water glasses compared by infrared spectroscopy from 295 to 12 K. J. Phys. Chem. A 108, 11141-11150 (2004) (Pubitemid 40011143)
13. Callam, C. S., Singer, S. J., Lowary, T. L., Hadad, C. M.: Computational analysis of the potential energy surfaces of glycerol in the gas and aqueous phases: effects of level of theory, basis set, and solvation on strongly intramolecularly hydrogen-bonded systems. J. Am. Chem. Soc. 123, 11743-11754 (2001) (Pubitemid 33121794)
14. Chelli, R., Procacci, P., Cardini, G., Califano, S.: Glycerol condensed phases. Part II: a molecular dynamics study of the conformational structure and hydrogen bonding. Phys. Chem. Chem. Phys. 1, 879-885 (1999)
15. Perron, G., Desnoyers, J. E.: Heat capacities and volumes of interaction between mixtures of alcohols in water at 298.15 K. J. Chem. Thermodyn. 13, 1105-1121 (1981)
16. Alary, I. F., Simard, M. A., Dumont, J., Jolicoeur, C.: Simultaneous flow measurement of specific heats and thermal expansion coefficients of liquids: aqueous t-BuOH mixtures and neat alkanols and alkanediols at 25 °C. J. Solution Chem. 11, 755-776 (1982)
17. Tamura, K., Osaki, A., Koga, Y.: Compressibilities of aqueous tert-butanol in the water-rich region at 25 °C: partial molar fluctuations and mixing schemes. Phys. Chem. Chem. Phys. 1, 121-126 (1999)
18. Franks, F., Smith, H. T.: Precision densities of dilute aqueous solutions of the isomeric butanols. J. Chem. Eng. Data 13, 538-541 (1968)
19. Sakurai, M., Nakamura, K., Nitta, K.: Volumetric properties of dilute aqueous alcohol solutions at different temperatures. Bull. Chem. Soc. Jpn. 67, 1580-1587 (1994)
20. Sakurai, M.: Partial molar volumes in aqueous mixtures of nonelectrolytes. I. t-Butyl alcohol. Bull. Chem. Soc. Jpn. 60, 1-7 (1987)
21. Hvidt, A., Moss, R., Nielsen, G.: Volume properties of aqueous solutions of tert-butyl alcohol at temperatures between 5 and 25 °C. Acta Chem. Scand. 32, 274-280 (1978)
22. Kim, E. S., Marsh, K. N.: Excess volumes for 2-methyl-2-propanol-water at 5 K intervals from 303.15 to 323.15 K. J. Chem. Eng. Data 33, 288-292 (1988) (Pubitemid 18649206)
23. Egorov, G. I., Makarov, D. M.: Densities and volume properties of (water + tert-butanol) over the temperature range of (274.15 to 348.15) K at pressure of 0.1 MPa. J. Chem. Thermodyn. 43, 430-441 (2011)
24. Rabinovich, V. A., Havin, Z. Ya.: In: Potekhin, A. A., Efimov, A. I. (eds.) Short Chemical Handbook, 3th edn. Khimiya Press, Moscow (1991)
25. Lide, D. R. (ed.): Handbook of Chemistry and Physics, 82nd edn. CRC Press, New York (2001)
26. Weissberger, F., Proskauer, E. S., Riddik, J. A., Toops, E. E.: Organic Solvents. Physical Properties and Methods of Purification. Interscience, New York (1955)
27. 2O-DMF mixture at the pressure 0.101 MPa in the temperature range 278.15-323.15 K. Russ. J. Gen. Chem. 72, 693-696 (2002)
28. Egorov, G. I., Afanas'ev, V. N., Kolker, A. M.: V T x properties of the system water-2-propanol in the range 275.15-338.15 K. Russ. J. Gen. Chem. 74, 171-173 (2004) (Pubitemid 39030367)
29. Egorov, G. I., Makarov, D. M.: The bulk properties of ethylene glycol-dimethylsulfoxide mixtures over the temperature range 278-323 K at p = 0.1 MPa. Russ. J. Phys. Chem. A 82, 1778-1784 (2008)
30. Egorov, G. I., Makarov, D. M.: The bulk properties of the water-dimethylsulfoxide system at 278-323.15 K and atmospheric pressure. Russ. J. Phys. Chem. A 83, 693-698 (2009)
31. Egorov, G. I., Makarov, D. M., Kolker, A. M.: Volumetric properties of the water-ethylene glycol mixtures in the temperature range 278-333.15 K at atmospheric pressure. Russ. J. Gen. Chem. 80, 1577-1585 (2010)
32. m-T-x properties of water-acetone mixtures over the temperature range 298-323 K and pressures from 1 to 1000 bar: isothermal compressibility, volume expansion coefficients and inner pressure of water-acetone mixtures. Russ. J. Phys. Chem. A 70, 197-204 (1996)
33. m-x properties of water-acetamide mixtures at 298.15 K over the pressure range of 1-1000 bar. J. Phys. Chem. A 73, 1949-1951 (1999) (Pubitemid 129327331)
34. Egorov, G. I., Kolker, A. M.: Effect of pressure and temperature on volume properties of water-N, N-dimethylformamide mixtures. J. Mol. Liq. 106, 239-248 (2003)
35. Egorov, G. I., Makarov, D. M.: Compressibility coefficients of water-2-propanol mixtures over the temperature and pressure ranges 278-323.15 K and 1-1000 bar. Russ. J. Phys. Chem. A 82, 1037-1041 (2008) (Pubitemid 351769868)
36. Egorov, G. I., Makarov, D. M.: The compressibility of water-dimethyl sulfoxide mixtures over the temperature and pressure ranges 278-323.15 K and 1-1000 bar. Russ. J. Phys. Chem. A 83, 2058-2065 (2009)
37. Egorov, G. I., Makarov, D. M., Kolker, A. M.: Densities and volumetric properties of ethylene glycol + dimethylsulfoxide mixtures at temperatures of (278.15 to 323.15) K and pressures of (0.1 to 100) MPa. J. Chem. Eng. Data 55, 3481-3488 (2010)
38. Gordon, A. J., Ford, R. A.: The Chemist's Companion. A Handbook of Practical Data, Techniques, and References. Wiley, New York (1972)
39. Xu, L., Hu, X., Lin, R.: Volumetric properties of glycerol with N, N-dimethylformamide and with water at 25 and 35 °C. J. Solution Chem. 32, 363-370 (2003)
40. Li, Q.-S., Su, M.-G., Wang, S.: Densities and excess molar volumes for binary glycerol + 1-propanol, + 2-propanol, + 1, 2-propanediol, and + 1, 3-propanediol mixtures at different temperatures. J. Chem. Eng. Data 52, 1141-1145 (2007) (Pubitemid 46848292)
41. Ge, M.-L., Ma, J.-L., Chu, B.: Densities and viscosities of propane-1, 2, 3-triol + ethane-1, 2-diol at T = (298.15 to 338.15) K. J. Chem. Eng. Data 55, 2649-2651 (2010)
42. Martinez, S., Garriga, R., Perez, P., Gracia, M.: Densities and viscosities of binary mixtures of butanenitrile with butanol isomers at several temperatures. J. Chem. Eng. Data 45, 1182-1188 (2000) (Pubitemid 32023015)
43. Redlich, O., Kister, A. T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345-348 (1948)
44. Torres, R. B., Marchiore, A. C. M., Volpe, P. L. O.: Volumetric properties of binary mixtures of (water + organic solvents) at temperatures between T = 288.15 K and T = 303.15 K at p = 0.1 MPa. J. Chem. Thermodyn. 38, 526-541 (2006) (Pubitemid 44389591)
45. Narten, A. H., Sandler, S. I.: X-ray diffraction study of liquid tertiary butyl alcohol at 26 °C. J. Chem. Phys. 71, 2069-2073 (1979)
46. Bowron, D. T., Finney, J. L., Soper, A. K.: The structure of pure tertiary butanol. Mol. Phys. 93, 531-543 (1998) (Pubitemid 128476594)
47. Kusalik, P. G., Lyubartsev, A. P., Bergman, D. L., Laaksonen, A.: Computer simulation study of tert-butyl alcohol. 2. Structure in aqueous solution. J. Phys. Chem. B 104, 9533-9539 (2000)
48. Fukasawa, T., Tominaga, Y, Wakisaka, A.: Molecular association in binary mixtures of tert-butyl alcohol-water and tetrahydrofuran-heavy water studied by mass spectrometry of clusters from liquid droplets. J. Phys. Chem. A 108, 59-63 (2004)
49. Wojtkow, D., Czarnecki, M. A.: Effect of temperature and concentration on the structure of tert-butyl alcohol/water mixtures: near-infrared spectroscopic study. J. Phys. Chem. A 109, 8218-8224 (2005) (Pubitemid 41361373)
50. Yoshida, K., Yamaguchi, T., Kovalenko, A., Hirata, F.: Structure of tert-butyl alcohol-water mixtures studied by the RISM theory. J. Phys. Chem. B 106, 5042-5049 (2002) (Pubitemid 35281959)
51. Nath, P. P., Sarkar, S., Krishna, P. S. R., Joarder, R. N.: Intermolecular structure of liquid D-tert-butanol by neutron-diffraction data. Appl. Phys. A 74, S348-S351 (2002)
52. Hamilton, D., Stokes, R. H.: Apparent molar volumes of urea in several solvents as functions of temperature and concentration. J. Solution Chem. 1, 213-221 (1972)
53. Abrosimov, V. K., Ivanov, E. V.: Water, structure, state and solvation, achievements of last years. In: Kutepov, A. M. (ed.) Water in Nonaqueous Solutions: State and Solvation, pp. 277-346. Nauka, Moscow (2003)
54. Nakajima, T., Komatsu, T., Nakagawa, T.: Apparent molal volumes and adiabatic compressibilities of nalkanols and α, ω-alkane diols in dilute aqueous solutions at 5, 25, and 45 °C. I. Apparent molal volumes. Bull. Chem. Soc. Jpn. 48, 783-787 (1975)
55. Sakurai, M.: Partial molar volumes in aqueous mixtures of nonelectrolytes. II. Isopropyl alcohol. J. Solution Chem. 17, 267-276 (1988)
56. Franks, F., Smith, H. T.: Volumetric properties of alcohols in dilute aqueous solutions. Trans. Faraday Soc. 64, 2962-2972 (1968)
57. de Visser, C, Perron, G., Desnoyers, J. E.: The heat capacities, volumes, and expansibilities of tert-butyl alcohol-water mixtures from 6 to 65 °C. Can. J. Chem. 55, 856-862 (1977)
58. Hyncica, P., Hnedkovsky, L., Cibulka, I.: Partial molar volumes of organic solutes in water. XIII. Butanols (aq) at temperatures T = 298 K to 573 K and at pressures up to 30 MPa. J. Chem. Thermodyn. 38, 418-426 (2006)
59. Sakurai, M., Nakagawa, T: Densities of dilute solutions of water in n-alkanols at 278. 15, 288.15, 298.15, 308.15, and 318.15 K. Partial molar volumes of water in n-alkanols. J. Chem. Thermodyn. 16, 171-174 (1984)
60. Sakurai, M.: Partial molar volumes in aqueous mixtures of nonelectrolytes. III. t-Pentyl alcohol. J. Solution Chem. 18, 37-44 (1989)
61. Egorov, G. I., Makarov, D. M.: Volumetric properties of the binary mixture of ethylene glycol + tertbutanol at T = (278.15, 288.15, 298.15, 308.15, 323.15, 333.15, 348.15) K under atmospheric pressure. J. Mol. Liq. (in press)
62. Riddick, J. A., Bunger, W. B., Sakano, T. K.: Organic Solvents: Physical Properties and Methods of Purification; Techniques of Chemistry. Wiley-Interscience, New York (1986)
63. Soujanya, J., Satyavathi, B., Vittal Prasad, T. E.: Experimental (vapour + liquid) equilibrium data of (methanol + water), (water + glycerol) and (methanol + glycerol) systems at atmospheric and subatmospheric pressures. J. Chem. Thermodyn. 42, 621-624 (2010)
64. Adamenko, I. I., Bulavin, L. A., Ilyin, V, Zelinsky, S. A., Moroz, K. O.: Anomalous behavior of glycerolwater solutions. J. Mol. Liq. 127, 90-92 (2006)
65. Sanz, M. T., Blanco, B., Beltran, S., Cabezas, J. L., Coca, J.: Vapor liquid equilibria of binary and ternary systems with water, 1, 3-propanediol, and glycerol. J. Chem. Eng. Data 46, 635-639 (2001) (Pubitemid 32508708)
66. Verhoeye, L., Lauwers, E.: Vapor-liquid equilibrium of the system 2-propanol-water-1, 2, 3-propanetriol at 760 mm of Hg. J. Chem. Eng. Data 14, 306-309 (1969)
67. 3 in glycerol-water mixtures. Electrochim. Acta 14, 1089-1096 (1969)
68. Murthy, M. N., Subrahmahyan, S. V: Behaviour of excess heat capacity of aqueous non-electrolytes. Indian J. Pure Appl. Phys. 15, 485-489 (1977)
69. Uosaki, Y, Kitaura, S., Moriyoshi, T: Static relative permittivities of water + ethane-1, 2-diol and water + propane-1, 2, 3-triol under pressures up to 300 MPa at 298.15 K. J. Chem. Eng. Data 51, 423-429 (2006)
70. Darbari, G. S., Singh, R. P, Verma, G. S., Rajagopalan, S.: Acoustic absorption in mixtures of glycerol and water below 1 MHz. II. Nuovo Cimento B 52, 1-17 (1967)
71. Nain, A. K.: Densities and volumetric properties of binary mixtures of aniline with 1-propanol, 2-propanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at temperatures from 293.15 to 318.15 K. Int. J. Thermophys. 28, 1228-1244 (2007) (Pubitemid 350025877)
72. Anson, A., Garriga, R., Martinez, S., Perez, P., Gracia, M.: Densities and viscosities of binary mixtures of 1-chlorobutane with butanol isomers at several temperatures. J. Chem. Eng. Data 50, 677-682 (2005)
73. Kenttaemaa, J., Tommila, E., Martti, M.: Some thermodynamic properties of the system t-butanol + water. Ann. Acad. Sci. Fenn. Ser. A2 93, 1-20 (1959)
74. TRC Thermodynamic Tables. Non-Hydrocarbons. Thermodynamic Research Center, Texas A&M University, College Station, TX, d-5030 (1966)
75. Langa, E., Mainar, A. M., Pardo, J. I., Urieta, J. S.: Excess enthalpy, density, and speed of sound for the mixtures β-pinene + 2-methyl-1-propanol or 2-methyl-2-propanol at several temperatures. J. Chem. Eng. Data 52, 2182-2187 (2007) (Pubitemid 350229750)
76. Kubota, H., Tanaka, Y., Makita, T.: Volumetric behavior of pure alcohols and their water mixtures under high pressure. Inter. J. Thermophys. 8, 47-70 (1987) (Pubitemid 17516188)
77. Harris, K. R., Newitt, P. J., Back, P. J., Woolf, L. A.: Thermodynamic property measurements for 2-methyl-2-propanol + water from the freezing surface to 75 °C. High Temp., High Press. 30, 51-62 (1998) (Pubitemid 128363758)