메뉴 건너뛰기




Volumn 41, Issue 4, 2012, Pages 630-645

Raman-spectroscopic measurements of the first dissociation constant of aqueous phosphoric acid solution from 5 to 301 °C

Author keywords

Aqueous phosphoric acid solutions; First dissociation constant of phosphoric acid; High temperature chemistry; Raman spectroscopy; Structure of aqueous phosphoric acid

Indexed keywords


EID: 84861227078     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-012-9825-4     Document Type: Article
Times cited : (39)

References (38)
  • 2
    • 0004053611 scopus 로고
    • 2nd edn., Wiley, New York
    • Voet, D., Voet, J.: Biochemistry, 2nd edn., pp. 428-434. Wiley, New York (1995)
    • (1995) Biochemistry , pp. 428-434
    • Voet, D.1    Voet, J.2
  • 4
    • 77957669666 scopus 로고
    • Electrometric measurements with hydrogen electrodes in mixtures of acids and bases with salts; the dissociation constants of water, phosphoric acid, citric acid, and glycine
    • Bjerrum, N., Unmack, U.: Electrometric measurements with hydrogen electrodes in mixtures of acids and bases with salts; the dissociation constants of water, phosphoric acid, citric acid, and glycine. Kgl. Danske Videnskab. Selskab, Math.-Fys. Medd. 9, 221-227 (1929)
    • (1929) Kgl. Danske Videnskab. Selskab, Math.-Fys. Medd. , vol.9 , pp. 221-227
    • Bjerrum, N.1    Unmack, U.2
  • 5
    • 0001606887 scopus 로고
    • Electrical conductivity of orthophosphoric acid and of sodium and potassium dihydrogen phosphates at 25 °C
    • Mason, C. M., Culvern, J. B.: Electrical conductivity of orthophosphoric acid and of sodium and potassium dihydrogen phosphates at 25 °C. J. Am. Chem. Soc. 71, 2387-2393 (1949)
    • (1949) J. Am. Chem. Soc. , vol.71 , pp. 2387-2393
    • Mason, C.M.1    Culvern, J.B.2
  • 6
    • 0001010975 scopus 로고
    • Diffusion of aqueous solutions of phosphoric acid at 25 °C
    • Edwards, O. W., Huffman, E. O.: Diffusion of aqueous solutions of phosphoric acid at 25 °C. J. Phys. Chem. 63, 1830-1833 (1959)
    • (1959) J. Phys. Chem. , vol.63 , pp. 1830-1833
    • Edwards, O.W.1    Huffman, E.O.2
  • 7
    • 0000572840 scopus 로고
    • The heats of ionization of water, ammonium hydroxide, carbonic, phosphoric, and sulfuric acids. The variation of ionization constants with temperature and the entropy change with ionization
    • Pitzer, K. S.: The heats of ionization of water, ammonium hydroxide, carbonic, phosphoric, and sulfuric acids. The variation of ionization constants with temperature and the entropy change with ionization. J. Am. Chem. Soc. 59, 2365-2371 (1937)
    • (1937) J. Am. Chem. Soc. , vol.59 , pp. 2365-2371
    • Pitzer, K.S.1
  • 8
    • 33947444329 scopus 로고
    • Activity of orthophosphoric acid in aqueous solution at 25 °C from vapour pressure measurements
    • Elmore, K. L., Mason, C. M., Christensen, J. H.: Activity of orthophosphoric acid in aqueous solution at 25 °C from vapour pressure measurements. J. Am. Chem. Soc. 68, 2528-2532 (1946)
    • (1946) J. Am. Chem. Soc. , vol.68 , pp. 2528-2532
    • Elmore, K.L.1    Mason, C.M.2    Christensen, J.H.3
  • 9
  • 11
    • 0001206202 scopus 로고
    • Metal complexing by phosphorus compounds-IX. Thermodynamics of ionization of ortho-, pyro-and tripolyphosphoric acids
    • Irani, R. R., Taulli, T. A.: Metal complexing by phosphorus compounds-IX. Thermodynamics of ionization of ortho-, pyro-and tripolyphosphoric acids. J. Inorg. Nucl. Chem. 28, 1011-1020 (1966)
    • (1966) J. Inorg. Nucl. Chem. , vol.28 , pp. 1011-1020
    • Irani, R.R.1    Taulli, T.A.2
  • 13
    • 0014575233 scopus 로고
    • Equilibria in dilute aqueous solutions of orthophosphates
    • Childs, C. W.: Equilibria in dilute aqueous solutions of orthophosphates. J. Phys. Chem. 76, 2956-2960 (1969)
    • (1969) J. Phys. Chem. , vol.76 , pp. 2956-2960
    • Childs, C.W.1
  • 14
    • 0004077163 scopus 로고
    • Proton transfer conductance in aqueous solution. Part 2. Effect of pressure on the electrical conductivity of concentrated ortho-phosphoric acid in water at 25 °C
    • Lown, D. A., Thirsk, H. R.: Proton transfer conductance in aqueous solution. Part 2. Effect of pressure on the electrical conductivity of concentrated ortho-phosphoric acid in water at 25 °C. Trans. Faraday Soc. 67, 149-152 (1971)
    • (1971) Trans. Faraday Soc. , vol.67 , pp. 149-152
    • Lown, D.A.1    Thirsk, H.R.2
  • 15
    • 8844279858 scopus 로고
    • Potentiometric studies on association and dissociation equilibria of orthophosphoric acid water-KCl 3 M medium at 25 °C
    • Ferroni, G.: Potentiometric studies on association and dissociation equilibria of orthophosphoric acid water-KCl 3 M medium at 25 °C. Electrochim. Acta 21, 283-286 (1976)
    • (1976) Electrochim. Acta , vol.21 , pp. 283-286
    • Ferroni, G.1
  • 16
    • 0038914585 scopus 로고
    • Acid dissociation constants and rates as studied ultrasonic absorption
    • Green, L. W., Kruus, P., McGuire, M. J.: Acid dissociation constants and rates as studied ultrasonic absorption. Can. J. Chem. 54, 3152-3162 (1976)
    • (1976) Can. J. Chem. , vol.54 , pp. 3152-3162
    • Green, L.W.1    Kruus, P.2    McGuire, M.J.3
  • 17
    • 21344478276 scopus 로고
    • The effect of temperature and pressure on the protonation of o-phosphate ions at 348.15 and 398.15 K, and at 1.52 and 12.50 MPa
    • Izatt, R. M., Gillespie, S. E., Oscarson, J. L., Wang, P., Renuncio, J. A. R., Pando, C.: The effect of temperature and pressure on the protonation of o-phosphate ions at 348.15 and 398.15 K, and at 1.52 and 12.50 MPa. J. Solution Chem. 23, 449-468 (1994)
    • (1994) J. Solution Chem. , vol.23 , pp. 449-468
    • Izatt, R.M.1    Gillespie, S.E.2    Oscarson, J.L.3    Wang, P.4    Renuncio, J.A.R.5    Pando, C.6
  • 18
    • 0000146981 scopus 로고
    • The first dissociation constant of phosphoric acid from 0 to 50 °C
    • Nims, L. F.: The first dissociation constant of phosphoric acid from 0 to 50 °C. J. Am. Chem. Soc. 56, 1110-1112 (1934)
    • (1934) J. Am. Chem. Soc. , vol.56 , pp. 1110-1112
    • Nims, L.F.1
  • 19
    • 0000978449 scopus 로고
    • First dissociation constant of phosphoric acid from 0 to 60 °C; Limitations of the electromotive force method for moderately strong acids
    • Bates, R. G.: First dissociation constant of phosphoric acid from 0 to 60 °C; Limitations of the electromotive force method for moderately strong acids. J. Res. Natl. Bur. Stand. 47, 127-134 (1951)
    • (1951) J. Res. Natl. Bur. Stand. , vol.47 , pp. 127-134
    • Bates, R.G.1
  • 20
    • 0345450317 scopus 로고
    • Phosphoric acid dissociation equilibria in aqueous solutions to 300 °C
    • Mesmer, R. E., Baes, C. F. Jr.: Phosphoric acid dissociation equilibria in aqueous solutions to 300 °C. J. Solution Chem. 3, 307-322 (1974)
    • (1974) J. Solution Chem. , vol.3 , pp. 307-322
    • Mesmer, R.E.1    Baes Jr., C.F.2
  • 21
    • 0001538650 scopus 로고
    • The first ionization constant from 25 to 200 °C and 2000 bar for orthophosphoric acid
    • Read, A. J.: The first ionization constant from 25 to 200 °C and 2000 bar for orthophosphoric acid. J. Solution Chem. 17, 213-224 (1988)
    • (1988) J. Solution Chem. , vol.17 , pp. 213-224
    • Read, A.J.1
  • 22
    • 77957662735 scopus 로고    scopus 로고
    • Raman-and infrared-spectroscopic investigations of dilute aqueous phosphoric acid solutions
    • Rudolph, W. W.: Raman-and infrared-spectroscopic investigations of dilute aqueous phosphoric acid solutions. Dalton Trans. 39, 9642-9653 (2010)
    • (2010) Dalton Trans. , vol.39 , pp. 9642-9653
    • Rudolph, W.W.1
  • 25
    • 0000993523 scopus 로고
    • I. Zur schwingungsspektroskopischen charakterisierung des hexaquoaluminium (III)-komplexions
    • Rudolph, W., Schönherr, S.: I. Zur schwingungsspektroskopischen Charakterisierung des Hexaquoaluminium (III)-komplexions. Z. Phys. Chem. (Leipzig) 270, 1121-1134 (1989)
    • (1989) Z. Phys. Chem. (Leipzig) , vol.270 , pp. 1121-1134
    • Rudolph, W.1    Schönherr, S.2
  • 27
    • 11644269647 scopus 로고
    • Kinetics of thermal decomposition of aqueous perchloric acid
    • Henderson, M. P., Miasek, V. I., Swaddle, T. W.: Kinetics of thermal decomposition of aqueous perchloric acid. Can. J. Chem. 49, 317-324 (1971)
    • (1971) Can. J. Chem. , vol.49 , pp. 317-324
    • Henderson, M.P.1    Miasek, V.I.2    Swaddle, T.W.3
  • 28
    • 0001808266 scopus 로고    scopus 로고
    • Structure and dissociation of hydrogen sulphate ion in aqueous solution over a broad temperature range: A Raman study
    • Rudolph, W.: Structure and dissociation of hydrogen sulphate ion in aqueous solution over a broad temperature range: a Raman study. Z. Phys. Chem. 194, 73-79 (1996)
    • (1996) Z. Phys. Chem. , vol.194 , pp. 73-79
    • Rudolph, W.1
  • 29
    • 0040306551 scopus 로고
    • Dissoziation, struktur und schneller protonenaustausch der phosphorsäure in verdünnter wäβriger lösung
    • Rudolph, W., Steger, W. E.: Dissoziation, Struktur und schneller Protonenaustausch der Phosphorsäure in verdünnter wäβriger Lösung. Z. Phys. Chem. 172, 49-59 (1991)
    • (1991) Z. Phys. Chem. , vol.172 , pp. 49-59
    • Rudolph, W.1    Steger, W.E.2
  • 31
    • 0000041609 scopus 로고
    • A laser Raman spectroscopic study of aqueous phosphoric acid
    • Preston, C. M., Adams, W. A.: A laser Raman spectroscopic study of aqueous phosphoric acid. Can. J. Spectrosc. 22, 125-136 (1977)
    • (1977) Can. J. Spectrosc. , vol.22 , pp. 125-136
    • Preston, C.M.1    Adams, W.A.2
  • 32
    • 4243713811 scopus 로고
    • The vibrational spectrum of ortho-phosphoric acid in some nonaqueous solvents
    • Levene, R. J., Powell, D. B., Steele, D.: The vibrational spectrum of ortho-phosphoric acid in some nonaqueous solvents. Spectrochim. Acta 22, 2033-2038 (1966)
    • (1966) Spectrochim. Acta , vol.22 , pp. 2033-2038
    • Levene, R.J.1    Powell, D.B.2    Steele, D.3
  • 33
    • 0013329889 scopus 로고
    • Raman spectroscopy of aqueous phosphate solutions at temperatures up to 450 °C. Two liquid phases, supercritical fluids, and pyro-to ortho-phosphate conversions
    • Marshall, W. L., Begun, G. M.: Raman spectroscopy of aqueous phosphate solutions at temperatures up to 450 °C. Two liquid phases, supercritical fluids, and pyro-to ortho-phosphate conversions. J. Chem. Soc. Faraday Trans. 2(85), 1963-1978 (1989)
    • (1989) J. Chem. Soc. Faraday Trans. , vol.2 , Issue.85 , pp. 1963-1978
    • Marshall, W.L.1    Begun, G.M.2
  • 34
    • 77957652790 scopus 로고
    • Vibrational and 31-P NMR studies of molten phosphoric acid and highly concentrated aqueous solutions
    • Hussey, Ch. L., Newman, D. S., Mamantov, G., Ito, Y. eds., The Electrochemical Society, Pennington
    • Rudolph, W.: Vibrational and 31-P NMR studies of molten phosphoric acid and highly concentrated aqueous solutions. In: Hussey, Ch. L., Newman, D. S., Mamantov, G., Ito, Y. (eds.) Proceedings of the Ninth International Symposium on Molten Salts. Physical Electrochemistry Proceedings, vol. 94-13, pp. 313-317. The Electrochemical Society, Pennington (1994)
    • (1994) Proceedings of the Ninth International Symposium on Molten Salts. Physical Electrochemistry Proceedings , vol.94 , Issue.13 , pp. 313-317
    • Rudolph, W.1
  • 35
    • 84861235364 scopus 로고    scopus 로고
    • Vibrational and 31-P NMR studies of concentrated aqueous solutions
    • Memorial University
    • Rudolph, W.: Vibrational and 31-P NMR studies of concentrated aqueous solutions. Unpublished material, Memorial University (1998)
    • (1998) Unpublished Material
    • Rudolph, W.1
  • 36
    • 0034147275 scopus 로고    scopus 로고
    • A new investigation of aqueous orthophosphoric acid speciation using Raman spectroscopy
    • Cherif, M., Mgaidi, A., Ammar, N., Vallée, G., Fürst, W.: A new investigation of aqueous orthophosphoric acid speciation using Raman spectroscopy. J. Solution Chem. 29, 255-269 (2000)
    • (2000) J. Solution Chem. , vol.29 , pp. 255-269
    • Cherif, M.1    Mgaidi, A.2    Ammar, N.3    Vallée, G.4    Fürst, W.5
  • 37
    • 0000872131 scopus 로고
    • Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures; II. Debye-Hückel parameters for activity coefficients and relative partial molal properties
    • Helgeson, H. C., Kirkham, D. H.: Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures; II. Debye-Hückel parameters for activity coefficients and relative partial molal properties. Am. J. Sci. 274, 1199-1261 (1974)
    • (1974) Am. J. Sci. , vol.274 , pp. 1199-1261
    • Helgeson, H.C.1    Kirkham, D.H.2
  • 38
    • 77957663463 scopus 로고    scopus 로고
    • Chemical speciation of environmentally significant heavy metals with inorganic ligands (IUPAC technical report)
    • Powell, K. J., Brown, P. L., Byrne, R. H., Gajda, T., Hefter, G., Sjöberg, S., Wanner, H.: Chemical speciation of environmentally significant heavy metals with inorganic ligands (IUPAC technical report). Pure Appl. Chem. 77, 739-800 (2005)
    • (2005) Pure Appl. Chem. , vol.77 , pp. 739-800
    • Powell, K.J.1    Brown, P.L.2    Byrne, R.H.3    Gajda, T.4    Hefter, G.5    Sjöberg, S.6    Wanner, H.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.