In-situ activation of hydrogen evolution in pH-neutral electrolytes by additions of multivalent cations

International Journal of Hydrogen Energy

Volumn 37, Issue 12, 2012, Pages 9496-9503

  Gustavsson, John ^a   Lindbergh, Göran ^a   Cornell, Ann ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Hydrogen evolution; In situ activation; Ligand bound water reduction; Rare earth metal ions

Indexed keywords

BOUND LIGANDS; CATHODE FILM; CATHODE SURFACE; DIFFUSION LAYERS; ELECTRODE SURFACES; HYDROGEN EVOLUTION; HYDROGEN EVOLUTION REACTIONS; IN-SITU; METAL HYDROXIDE; METAL-ION COMPLEXES; MULTIVALENT CATIONS; RARE EARTH METAL IONS; STEADY STATE POLARIZATION; TRIVALENT CATIONS; WATER REDUCTION;

ACTIVATION ANALYSIS; ALKALINITY; CATHODES; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTROLYTES; HYDROGEN; LIGANDS; METAL IONS; POSITIVE IONS; RARE EARTH ELEMENTS; SCANDIUM; SCANDIUM COMPOUNDS; YTTRIUM;

BIOACTIVITY;

EID: 84861201363     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.03.061     Document Type: Article

References (30)

1. L. Nylén, J. Gustavsson, and A. Cornell Cathodic reactions on an iron RDE in the presence of Y(III) J Electrochem Soc 155 2008 E136 E142
2. T. Hurlen, S. Gunvaldsen, and F. Blaker Effects of buffers on hydrogen evolution at iron electrodes, Electrochim Acta 29 1984 1163 1164
3. L. Nylén, and A. Cornell Effects of electrolyte parameters on the Iron/Steel cathode potential in the chlorate process J Appl Electrochem 39 2009 71 81
4. V. Artero, M. Chavarot-Kerlidou, and M. Fontecave Splitting water with cobalt Angew Chem 50 2011 7238 7266
5. A.W. Jeremiasse, J. Bergsma, J.M. Kleijn, M. Saakes, C.J.N. Buisman, and M.C. Stuart Performance of metal alloys as hydrogen evolution reaction catalysts in a microbial electrolysis cell Int J Hydrogen Energy 36 2011 10482 10489
6. A.W. Jeremiasse, H.V.M. Hamelers, J.M. Klein, and C.J.N. Buisman Use of biocompatible buffers to reduce the concentration overpotential for hydrogen evolution Environ Sci Techn 43 2009 6882 6887
7. M.D. Merrill, and B.E. Logan Electrolyte effects on hydrogen evolution and solution resistance in microbial electrolysis cells J Power Sources 19 2009 203 208
8. J.E. Colman Electrolytic production of sodium chlorate, A.I.Che.E Symp 77 204 1981 244 263
9. T.N. Andersen, B.S. Dandapani, and J.M. Berry Hydrogen evolution studies in neutral media J Electroanal Chem 357 1993 77 89
10. L. De Silva Menoz, A. Bergel, D. Feron, and R. Basséguy Hydrogen production by electrolysis of a phosphate solution on a stainless steel cathode Int J Hydrogen Energy 35 2010 8561 8568
11. V. Marinovic, and A.R. Despic Cathodic hydrogen evolution from aqueous solutions of acetic acid Russ J Electrochem 40 2004 995 999
12. S. Da Silva, R. Basséguy, and A. Bergel Electrochemical deprotonation of phosphate on stainless steel Electrochim Acta 49 2004 4553 4561
13. V. Marinovic, and A. Despic Phosphoric acid as a source of hydrogen in cathodic hydrogen evolution J Serb Chem Soc 63 1998 545 553 (Pubitemid 128381484)
14. V. Marinovic, and A.R. Despic Hydrogen evolution from solutions of citric acids J Electroanal Chem 431 1997 127 132 (Pubitemid 127379637)
15. V. Marinovic, and A. Despic Pyrophosphoric acid as a source of hydrogen in cathodic hydrogen evolution on silver Electrochim Acta 44 1999 4073 4077
16. M. Tran, C. Fiaud, and E.M.M. Sutter Cathodic reactions on steel in aqueous solutions containing Y(III) J Electrochem Soc 153 2006 B83 B89
17. M. Tran, D. Mohammedi, C. Fiaud, and E.M.M. Sutter Corrosion behaviour of steel in the presence of Y(III) salts: kinetic and mechanistic studies Corros Sci 48 2006 4257 4273 (Pubitemid 44692200)
18. M. Tran, P. Dubot, and E.M.M. Sutter Activation of water in the presence of REM salts in aqueous solution Int J Hydrogen Energy 33 2008 937 944
19. 3 coating on IN617 Superalloy J Electrochem Soc 152 2005 C813 C816
20. J. Gustavsson, L. Nylén, and A. Cornell Rare earth metal salts as potential alternatives to Cr(VI) in the chlorate process J Appl Electrochem 40 2010 1529 1536
21. S. Vasudevan Studies Relating To cathodic reactions in neutral chloride solutions used in chlorate process Ind Eng Chem Res 47 2008 5742 5745
22. ® in chlorate electrolysis - effects of electrolyte composition on the anode potential J Electrochem Soc 150 2003 D6 12
23. M. Della Monica, A. Ceglie, and A. Agostiano A conductivity equation for concentrated aqueous solutions Electrochim Acta 29 7 1984 933 937 (Pubitemid 14626507)
24. Handbook of chemistry and physics 70th ed. 1989 1990 CRC Press p. F-40
25. M.L. Miller, and D. Doran Concentrated salt solutions. II. Viscosity and density of sodium thiocyanate, sodium perchlorate and sodium iodide J Phys Chem 60 1956 186 189
26. R. Mills, and V.M.M. Lobo Physical sciences data No. 36, self-diffusion in electrolyte solutions 1989 Elsevier Amsterdam p. 316
27. M. Heyrovsky Polarographic wave of aluminium, collection Czechoslov Chem Commun 25 1960 3120 3135
28. G. Wulfsberg Inorganic Chemistry 2000 University Science Books Sausalito, California p. 57
29. C.F. Baes, and R.E. Mesmer The hydrolysis of cations 1976 Wiley New York
30. I. Zhitomirsky, and A. Petric Electrochemical deposition of yttrium oxide J Mater Chem 10 2000 1215 1218