Continuous production of fatty acid ethyl esters from sunflower oil using supercritical ethanol

Fuel

Volumn 97, Issue , 2012, Pages 703-709

  Velez, A ^a   Soto, G ^a   Hegel, P ^a   Mabe, G ^a   Pereda, S ^a  

^a UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

Biodiesel; Ethanolysis; Kinetics; Supercritical reactor

Indexed keywords

CONTINUOUS PRODUCTION; ENVIRONMENTAL POLICY; ENVIRONMENTALLY FRIENDLY PROCESS; ETHANOLYSIS; EXPERIMENTAL DATA; FATTY ACID ETHYL ESTER; FATTY ESTERS; HIGH SENSITIVITY; HIGHER YIELD; IDEAL SOLUTIONS; KINETIC MODELS; LOW QUALITIES; MASS FLOW RATE; MASS FRACTION; MIXTURE DENSITY; MOLAR RATIO; NON-CATALYTIC; OPERATING CONDITION; PENG-ROBINSON EQUATION OF STATE; PRESSURE RANGES; REACTIVE MIXTURES; RESIDENCE TIME; SUNFLOWER OIL; SUPER-CRITICAL; SUPERCRITICAL ETHANOL; SUPERCRITICAL MIXTURES; SUPERCRITICAL REACTORS;

BIODIESEL; ENZYME KINETICS; ESTERIFICATION; ESTERS; ETHANOL; FOSSIL FUELS; MIXTURES; PROFITABILITY;

VEGETABLE OILS;

EID: 84861199496     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2012.02.024     Document Type: Article

References (19)

1. F. Ma, and M. Hanna Biodiesel production: a review Bioresour Technol 70 1999 1 5
2. S. Pinzi, I.L. Garcia, F.J. Lopez-Gimenez, M.D. Luque de Castro, G. Dorado, and M.P. Dorado The ideal vegetable oil-based biodiesel composition: a review of social, economical and technical implications Energy Fuel 23 2009 2325 2341
3. M. Canakci, and J.V. Gerpen Biodiesel production from oils and fats with high free fatty acids Trans ASAE 44 2001 1429 1436
4. D. Kusdiana, and D.S. Saka Effects of water on biodiesel fuel production by Supercritical methanol treatment Bioresour Technol 91 2004 289 295
5. R. Sawangkeaw, K. Bunyakiat, and S. Ngamprasertsith A review of laboratory-scale research on lipid conversion to biodiesel with supercritical methanol (2001-2009) J Supercrit Fluids 55 2010 1 13
6. Tanawan. Pinnarat, and Phillip E. Savage Assessment of noncatalytic biodiesel synthesis using supercritical reaction conditions Ind Eng Chem Res 47 2008 6801 6808
7. M. Varma, and G. Madras Synthesis of biodiesel from castor oil and linseed oil in supercritical fluids Ind Eng Chem Res 46 2007 1 6
8. K. Bunyakiat, S. Makmee, R. Sawangkeaw, and S. Ngamprasertsith Continuous production of biodiesel via transesterification from vegetable oils in supercritical methanol Energy Fuel 20 2006 812 817
9. H. He, T. Wang, and S. Zhu Continuous production of biodiesel fuel from vegetable oil using supercritical methanol process Fuel 86 2007 442 447
10. E. Minami, and S. Saka Kinetic of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process Fuel 85 2006 2479 2483
11. C. Silva, T.A. Weschenfelder, S. Rovani, F.C. Corazza, M.L. Corazza, and C. Dariva Continuous production of fatty acid ethyl esters from soybean oil in compressed ethanol Ind Eng Chem Res 46 2007 5304 5309
12. I. Vieitez, C. da Silva, G. Borges, F. Corazza, J. Oliveira, and M. Grompone Continuous production of soybean biodiesel in supercritical ethanol-water mixtures Energy Fuel 22 2008 2805 2809
13. A. Velez, P. Hegel, G. Mabe, and E. Brignole Density and conversion in biodiesel production with supercritical methanol Ind Eng Chem Res 49 2010 7666 7670
14. A. Velez, S. Pereda, and E. Brignole Isochoric lines and determination of phase transition in supercritical reactors J Supercrit Fluid 55 2010 643 647
15. D. Peng, and D.B. Robinson A new two-constant equation of state Ind Eng Chem Fundam 15 1976 59 64
16. Y. Yang, Project 801, Evaluated process design data. Public release documentation, AIChE Design Institute for Physical Properties (DIPPR) BYU-DIPPR Thermophysical Properties Laboratory. Department of Chemical Engineering, Brigham Young University; 2003.
17. J. Marrero, and R. Gani Group contribution based estimation of pure component properties Fluid Phase Equilibr 183 2001 183 208
18. H.Y. Lo, and L.I. Stiel PVT behavior of ethyl alcohol at elevated pressure and temperatures Ind Eng Chem Fund 39 1969 713 718
19. J.D. Halvorsen, W.C. Mammel, and L.D. Clements Density estimation for fatty acids and vegetable oils based on their fatty acid composition JAOCS 70 1993 875 880