Pt 3Y electrocatalyst for oxygen reduction reaction in proton exchange membrane fuel cells

International Journal of Hydrogen Energy

Volumn 37, Issue 12, 2012, Pages 9758-9765

  Yoo, Sung Jong ^a   Lee, Kug Seung ^a   Hwang, Seung Jun ^a   Cho, Yong Hun ^b   Kim, Soo Kil ^c   Yun, Jeong Woo ^d   Sung, Yung Eun ^e   Lim, Tae Hoon ^a  

^a Korea Institute of Science and Technology   (South Korea)

^b Kookmin University   (South Korea)

^c Chung Ang University   (South Korea)

^d School of Applied Chemical Engineering   (South Korea)

^e Seoul National University   (South Korea)

Author keywords

Multilayer MEA; Proton exchange membrane fuel cells; PtY alloy; Sputtering technique; Utilization of catalysts

Indexed keywords

ALLOY NANOPARTICLE; ALLOY PARTICLES; AVERAGE PARTICLE SIZE; CELL PERFORMANCE; CONVENTIONAL SPUTTERING; DENSE FILMS; ELECTROCATALYST FOR OXYGEN REDUCTION REACTIONS; GASEOUS MIXTURE; HIGH PRESSURE SPUTTERING; HIGH RESOLUTION; KINETIC ACTIVITY; MEMBRANE ELECTRODE ASSEMBLIES; MULTIPLE LAYERS; NANO-CATALYST; NANOCATALYSTS; OXYGEN REDUCTION REACTION; POROUS CATALYSTS; SCANNING ELECTRONS; SPRAY-DEPOSITED; SPUTTERING PRESSURES; SPUTTERING TECHNIQUES; THIN-FILM ELECTRODE; X-RAY ABSORPTION NEAR EDGE SPECTROSCOPY;

ALLOYS; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROLYTIC REDUCTION; FILM PREPARATION; NANOPARTICLES; PHOTOELECTRONS; PLATINUM; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

PLATINUM ALLOYS;

EID: 84861185399     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.03.089     Document Type: Article

References (21)

1. H.A. Gasteiger, S.S. Kocha, B. Sompalli, and F.T. Wagner Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Appl Catal B-Environ 56 2005 9 35
2. C.K. Dyer Fuel cells for portable applications J Power Sources 106 2002 31 34
3. S.J. Yoo, and Y.E. Sung Design of palladium-based alloy electrocatalysts for hydrogen oxidation reaction in fuel cell A. Wieckowski, J.K. Norskov, Fuel cell science: theory, fundamentals, and biocatalysis 2010 John Wiley & Sons Inc 111 146
4. O. Savadogo, K. Lee, K. Oishi, S. Mitsushima, N. Kamiya, and K.I. Ota New palladium alloys catalyst for the oxygen reduction reaction in an acid medium Electrochem Commun 6 2004 105 109
5. J. Zhang, M.B. Vukmirovic, Y. Xu, M. Mavrikakis, and R.R. Adzic Controlling the catalytic activity of platinum-monolayer electrocatalysts for oxygen reduction with different substrates Angew Chem 117 2005 2170 2173
6. J.L. Fernandez, D.A. Walsh, and A.J. Bard Thermodynamic guidelines for the design of bimetallic catalysts for oxygen electroreduction and rapid screening by scanning electrochemical microscopy. M-Co (M: Pd, Ag, Au) J Am Chem Soc 127 2005 357 365 (Pubitemid 40094397)
7. S. Koh, and P. Strasser Electrocatalysis on bimetallic surfaces: modifying catalytic reactivity for oxygen reduction by voltammetric surface dealloying J Am Chem Soc 129 2007 12624 12625 (Pubitemid 350004447)
8. T. Toda, H. Igarashi, H. Uchida, and M. Watanabe Enhancement of the electroreduction of oxygen on Pt alloys with Fe, Ni, and Co J Electrochem Soc 146 1999 3750 3756 (Pubitemid 30515051)
9. J. Greeley, I.E.L. Stephens, A.S. Bondarenko, T.P. Johansson, H.A. Hansen, and T.F. Jaramillo Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Nat Chem 1 2009 552 556
10. 3Ni(111) via increased surface site availability Science 315 2007 493 497 (Pubitemid 46175748)
11. J.K. Norskov, J. Rossmeisl, A. Logadottir, L. Lindqvist, J.R. Kitchin, and T. Bligaard Origin of the overpotential for oxygen reduction at a fuel-cell cathode J Phys Chem B 108 2004 17886 17892
12. J. Zhang, M.B. Vukmirovic, K. Sasaki, A.U. Nilekar, M. Mavrikakis, and R.R. Adzic Mixed-metal Pt monolayer electrocatalysts for enhanced oxygen reduction kinetics J Am Chem Soc 127 2005 12480 12481 (Pubitemid 41292153)
13. V.R. Stamenkovic, B.S. Mun, M. Arenz, K.J.J. Mayrhofer, C.A. Lucas, and G. Wang Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Nat Mater 6 2007 241 247 (Pubitemid 46353773)
14. S. Hirano, J. Kim, and S. Srinivasan High performance proton exchange membrane fuel cells with sputter-deposited Pt layer electrodes Electrochim Acta 42 1997 1587 1593 (Pubitemid 127380906)
15. R. O'Hayre, S.J. Lee, S.W. Cha, and F.B. Prinz A sharp peak in the performance of sputtered platinum fuel cells at ultra-low platinum loading J Power Sources 109 2002 483 493
16. Cavalca CA, Arps JH, Murthy M.Fuel cell membrane electrode assemblies with improved power outputs and poison resistance. US Pat No 6300000 2001.
17. S.J. Yoo, Y.H. Cho, H.S. Park, J.K. Lee, and Y.E. Sung High utilization of Pt nanocatalysts fabricated using a high-pressure sputtering technique J Power Sources 178 2008 547 553 (Pubitemid 351317882)
18. J.R. Kitchin, J.K. Norskov, M.A. Barteau, and J.G. Chen Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals J Chem Phys 120 2004 10240 10246
19. B. Hammer, and J.K. Norskov Theoretical surface science and catalysis - calculations and concepts Adv Catal 45 2000 71 129
20. M.V. Ganduglia-Pirovano, V. Natoli, M.H. Cohen, J. Kudrnovsky, and I. Turek Potential, core-level, and d band shifts at transition-metal surfaces Phys Rev B 54 1996 8892 8898
21. A.E. Russell, and A. Rose X-ray absorption spectroscopy of low temperature fuel cell catalysts Chem Rev 104 2004 4613 4636