Continuous production of biodiesel using supercritical fluids: A comparative study between methanol and ethanol

Fuel Processing Technology

Volumn 102, Issue , 2012, Pages 110-115

  Santana, Aline ^a   MaçAira, José ^b   Larrayoz, M Angeles ^a  

^a UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

^b UNIVERSITY OF PORTO   (Portugal)

Author keywords

Biodiesel; Ethyl esters; Kinetic equations; Solid acid catalyst; Supercritical fluids; Vegetable oil

Indexed keywords

BIODIESEL PRODUCTION; COMPARATIVE STUDIES; CONTINUOUS PRODUCTION; CONTINUOUS REACTORS; COSOLVENTS; ETHYL ESTERS; EXPERIMENTAL INVESTIGATIONS; KINETIC EQUATIONS; MOLAR RATIO; SHORT REACTION TIME; SOLID ACID CATALYSTS; SUPERCRITICAL CONDITION; SUPERCRITICAL ETHANOL;

CARBON DIOXIDE; EFFLUENT TREATMENT; ETHANOL; GAS CHROMATOGRAPHY; INTEGRAL EQUATIONS; METHANOL; SUPERCRITICAL FLUID EXTRACTION; SUPERCRITICAL FLUIDS; VEGETABLE OILS;

BIODIESEL;

EID: 84861068207     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2012.04.014     Document Type: Article

References (43)

1. J. Sheehan, V. Cambresco, J. Duffield, M. Garboski, and H.H. Shapouri An overview of biodiesel and petroleum diesel life cycles A report by US Department of Agrigulture and Energy 1998 1 35
2. G. Antolin, F. Tinaut, Y. Briceno, V. Castano, C. Perez, and A. Ramirez Optimization of biodiesel production by sunflower oil transesterification Bioresource Technology 83 2002 111 114
3. G. Vicent, M. Martinez, and J. Aracil Integrated biodiesel production: a comparison of different homogeneous catalysts systems Journal of Bioresource Technology 92 2004 297 305
4. N. Khan, M.A. Warith, and G. Luk A comparison of acute toxicity of biodiesel, biodiesel blends, and diesel on aquatic organisms Journal of the Air & Waste Management Association 57 2007 286 296
5. H.J. Wright, J.B. Segur, H.V. Clark, S.K. Coburn, E.E. Langdon, and E.N. DuPuis A report on ester interchange Oil Soap 21 1944 145 148
6. B. Freedman, R.O. Butterfield, and E.H. Pryde Transesterification kinetics of soybean oil Jounal Americal Oil Chemists' Society 63 1986 1375 1380
7. Y. Zhang, M.A. Dubé, D.D. McLean, and M. Kates Biodiesel production from waste cooking oil: 1. Process design and technological assessment Bioresource Technology 89 2003 1 16
8. F. Ma, and M.A. Hanna Biodiesel production: a review Bioresource Technology 70 1999 1 15
9. L.C. Meher, D. Vidya Sagar, and S.N. Naik Technical aspects of biodiesel production by transesterification - a review Renewable and Sustainable Energy Reviews 10 2006 248 268
10. J. Van Gerpen Biodiesel processing and production Fuel Processing Technology 86 2005 1097 1107
11. H. Noureddini, and D. Zhu Kinetics of transesterification of soybean oil Applied Engineering in Agriculture 74 1997 1457 1463
12. D. Darnoko, and M. Cheryan Kinetics of palm oil transesterification in a batch reactor Journal of the American Oil Chemists' Society 77 2000 1263 1267
13. G.W. Huber, S. Iborra, and A. Corma Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering Chemical Review 106 2006 4044 4098
14. S. Saraf, and B. Thomas Influence of feedstock and process chemistry on biodiesel quality Process Safety and Environmental Protection 85 2007 360 364
15. K.S. Tyson Biodiesel Handling and Use Guidelines, National Renewable Energy Laboratory, NREL/TP-580-30004 September 2001 Golden
16. G. Vicente, M. Martinez, and J. Aracil Optimisation of integrated biodiesel production. Part I. A study of the biodiesel purity and yield Bioresource Technology 98 2007 1724 1733
17. Y. Xu, W. Du, D. Liu, and J. Zeng A novel enzymatic route for biodiesel production from renewable oils in a solvent-free medium Biotechnology Letters 25 2003 1239 1241
18. G. Knothe, J. van Gerpen, and J. Krahl The Biodiesel Handbook 2005 AOCS Press Champaign, IL, USA
19. F. Cao, Y. Chen, F. Zhai, J. Li, J. Wang, X. Wang, S. Wang, and W. Zhu Biodiesel production from high acid value waste frying oil catalyzed by superacid heteropolyacid Biotechnology and Bioengineering 101 2008 93 100
20. L. Bournay, D. Casanave, B. Delfort, G. Hillion, and J.A. Chodorg New heterogeneous process for biodiesel production: a way to improve the quality and the value of the crude glycerin produced by biodiesel plants Catalyst Today 106 2005 190 192
21. J.A. Melero, J. Iglesias, and G. Morales Heterogeneous acid catalysts for biodiesel production: current status and future challenges Green Chemistry 11 2009 1285 1308
22. D. Kusidiana, and S. Saka Biodiesel fuel from rapeseed oil as prepared in supercritical methanol Fuel 80 2001 225 231
23. A. Dermidas Biodiesel from vegetable oils via transesterification in supercritical methanol Energy Conversion and Management 43 2002 2349 2356
24. G. Madras, C. Kolluru, and R. Kumar Synthesis of biodiesel in supercritical fluids Fuel 83 2004 2029 2033
25. Y. Warabi, D. Kusadiana, and S. Saka Reactity of triglycerides and fatty acids of rapeseed oil in supercritical alcohols Bioresource Technology 91 2004 283 287
26. J. Maçaira, A. Santana, F. Recasens, and M.A. Larrayoz Biodiesel production using supercritical metanol/carbon dioxide mixtures in a continuous reactor Fuel 90 2011 2280 2288
27. J.Z. Yin, M. Xiao, and J.B. Song Biodiesel from soybean oil in supercritical methanol with co-solvent Energy Conversion Management 49 2008 908 912
28. H. Han, W. Cao, and J. Zhang Preparation of biodiesel from soybean oil using supercritical methanol and carbon dioxide as cosolvent Process Biochemistry 40 2005 3148 3151
29. M.N. Varma, and G. Madras Synthesis of biodiesel from castor oil and linseed oil in supercritical fluids Industrial and Engineering Chemistry Research 46 2007 1 6
30. M.N. Varma, A. Deshpande, and G. Madras Synthesis of biodiesel in supercritical alcohols and supercritical carbon dioxide Fuel 89 2010 1641 1646
31. UNE-EN 14103 Fat and oil derivatives. Fatty acid methyl esters (FAME) Determination of Ester and Linolenic Acid Methyl Ester Contents 2003 European Committee for Standardization Brussels (Belgium)
32. UNE-EN 14105 Fat and oil derivatives. Fatty acid methyl esters (FAME) Determination of Free and Total Glycerol and Mono-, Di-, Triglyceride Contents 2003 European Committee for Standardization Brussels (Belgium)
33. D. Darnoko, and M. Cheryan Kinetics of palm oil transesterification in a batch reactor Journal of the American Oil Chemists' Society 77 2000 1263 1267
34. UNE-EN 14214 Automotive fuels. Fatty acid methyl esters (FAME) for diesel engines Requirements and Test Methods 2003 European Committee for Standardization Brussels (Belgium)
35. C. Silva, T.A. Weschenfelder, S. Rovani, F.C. Corazza, M.L. Corazza, C. Dariva, and J.V. Oliveira Continuous production of fatty acid ethyl esters from soybean oil in compressed ethanol Industrial and Engineering Chemistry Research 46 2007 5304 5309
36. I. Vietez, M.J. Pardo, C. Silva, C. Bertoldi, F. Castilhos, V.J. Oliveira, M.A. Grompone, and I. Jachmanián Continuous synthesis of castor oil ethyl ester under supercritical ethanol Jounal of Supercritical Fluids 56 2011 271 276
37. M.M. Gui, K.T. Lee, and S. Bhatia Supercritical ethanol technology for the production of biodiesel: process optimization studies Journal of Supercritical Fluids 49 2009 1096 1099
38. E. Li, Z.P. Xu, and V. Rudolph MgCoAl-LDH derived heterogeneous catalyst for the ethanol transesterification of canola oil to biodiesel Applied Catalysis B: Environmental 88 2009 42 49
39. M. Diasakou, A. Louloudi, and N. Papyannakos Kinetics of the non-catalytic transesterification of soybean oil Fuel 77 1998 1297 1302
40. E.S. Song, J. Lim, H. Lee, and Y. Lee Transesterification of RBD palm oil using supercritical methanol Journal of Supercritical Fluids 44 2008 356 363
41. R.C. Reid, J.M. Prausnitz, and B.E. Poling The Properties of Gases and Liquids 4th ed. 1987 McGraw-Hill New York
42. A.C. Caballero, L.N. Hernández, and L.A. Estévez Calculation of interaction parameters for binary solid-SCF equilibria using several EOS and mixing rules Jounal of Supercritical Fluids 5 1992 283 295
43. S.S.T. Ting, S.J. Macnaughtn, D.L. Tomasko, and N.R. Foster Solubility of naproxen in supercritical carbon dioxide with and without cosolvents Industrial and Engineering Chemistry Research 32 1993 1471 1481