Fractionation and characterization of lignin carbohydrate complexes (LCCs) of Eucalyptus globulus in residues left after MWL isolation. Part I: Analyses of hemicellulose-lignin fraction (HC-L)

Holzforschung

Volumn 66, Issue 4, 2012, Pages 459-465

  Miyagawa, Yasuyuki ^a   Takemoto, Ooki ^a   Takano, Toshiyuki ^a   Kamitakahara, Hiroshi ^a   Nakatsubo, Fumiaki ^a,b  

^a KYOTO UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

Eucalyptus globulus; Lignin; Lignin carbohydrate complex (LCC); Lignin carbohydrate linkages; Size exclusion chromatography (SEC); Xylan; Xylan acetate

Indexed keywords

ACETIC ANHYDRIDES; CELLULOSE SOLVENT; DEACETYLATION; EUCALYPTUS GLOBULUS; FORMAMIDES; LICL/DMAC; LIGNIN-CARBOHYDRATE COMPLEX; LITHIUM CHLORIDE; MILLED WOOD LIGNIN; RESIDUAL WOOD MEAL; SOLUBLE FRACTION; XYLAN; XYLAN ACETATE;

ACETYLATION; AMIDES; CARBOHYDRATES; CELLULOSE; CHLORINE COMPOUNDS; LIGNIN; LITHIUM; SOLVENT EXTRACTION; VOLATILE FATTY ACIDS;

WOOD;

ACETATES; ACETYLATION; AMIDES; CHLORINE COMPOUNDS; CHROMATOGRAPHY; EUCALYPTUS GLOBULUS; EXTRACTION; LIGNIN CARBOHYDRATE COMPLEXES; LIGNINS; LITHIUM; SOLVENTS; WOOD; XYLANS;

EUCALYPTUS GLOBULUS;

EID: 84861053686     PISSN: 00183830     EISSN: 1437434X     Source Type: Journal    
DOI: 10.1515/HF.2011.177     Document Type: Article

References (22)

1. Ando, D., Takano, T., Nakatsubo, F. (2012) Multi-steps degradation method for β-O-4 linkage in lignins: . γ-TTSA method. Part 1: Reaction of non-phenolic dimeric β-O-4 model compounds. Holzforschung 66:331-339.
2. Balakshin, M.Y., Capanema, E.A., Chang, H. (2007) MWL fraction with a high concentration of lignin-carbohydrate linkages: isolation and 2D NMR spectroscopic analysis. Holzforschung 61:1-7.
3. Balakshin, M., Capanema, E., Gracz, H., Chang, H., Jameel, H. (2011) Quantification of lignin-carbohydrate linkages with highresolution NMR spectroscopy. Planta 233:1097-1110.
4. Barakat, A., Winter, H., Rondeau-Mouro, C., Saake, B., Chabbert, B., Cathala, B. (2007) Studies of xylan interactions and cross-linking to synthetic lignins formed by bulk and end-wise polymerization: a model study of lignin carbohydrate complex formation. Planta 226:267-281.
5. Borchardt, L.G., Piper, C.V. (1970) A gas chromatographic method for carbohydrates as alditol-acetates. Tappi 53:257-260.
6. Evtuguin, D.V., Tomás, J., Silva, A.M., Neto, C.P. (2003) Characterization of an acetylated hetero xylan from Eucalyptus globulus Labill. Carbohydr. Res. 338:597-604.
7. Furuno, H., Takano, T., Hirosawa, S., Kamitakahara, H., Nakatsubo, F. (2006) Chemical structural elucidation of total lignins in woods. II: analysis of a fraction of residual wood left after MWL isolation and solubilized in lithium chloride/N,N-dimethylacetamide. Holzforschung 60:653-658.
8. Grödahl, M., Teleman, A., Gatenholm, P. (2003) Effect of acetylation on the material properties of glucuronoxylan from aspen wood. Carbohydr. Polymers 52:359-366.
9. Heinze, T., Liebert, T. (2004) Chemical characteristics of cellulose acetate. Macromol. Symp. 208:167-237.
10. Hirosawa, S., Katahira, R., Nakatsubo, F. (2002) Chemical structural elucidation of total lignins in woods I: Fractionation of the lignin in residual wood meal after extraction of milled wood lignin. J. Wood Sci. 48:46-50.
11. Iiyama, K., Wallis, A.F. (1988) An improved acetyl bromide procedures for determining lignin in woods and wood pulps. Wood Sci. Technol. 22:271-280.
12. Karlsson, O., Pettersson, B., Westermark, U. (2001) The use of cellulase and hemicellulase to study lignin-cellulose as well as ligninhemicellulose bonds in kraft pulps. J. Pulp Pap Sci. 27:196-201.
13. Karlsson, O., Ikeda, T., Kishimoto, T., Magara, K., Matsumoto, Y., Hosoya, S. (2004) Isolation of lignin-carbohydrate bonds in wood. Model experiments and preliminary application to pine wood. J Wood Sci. 50:142-150.
14. 1H-NMR spectroscopy using 5-iodovanillin as a new internal standard. J. Wood. Sci. 47:378-382.
15. Katahira, R., Ujihara, M., Nakatsubo, F. (2003) A novel selective cleavage method for β-O-4 substructure in lignins named TIZ method. I. Degradation of guaiacyl and syringyl models. J.Wood Chem. Technol. 23:71-87.
16. Kishimoto, T., Uraki, Y., Ubukata, M. (2008) Synthesis of β-O-4 artificial lignin polymers and their analysis by NMR spectroscopy. Org. Biomol. Chem. 6:2982-2987.
17. Kishimoto, T. (2009) Synthesis of lignin model compounds and their application to wood research. Mokuzai Gakkaishi 55:187-197.
18. Koshijima, T., Timell, T. (1966) Factors affecting number average molecular weights determination of hardwood xylan. Mokuzai Gakkaishi 12:166-172.
19. Koshijima, T., Watanabe, T. Association between lignin and carbohydrates in wood and other plant tissues. Springer, Berlin, 2003.
20. Lawoko, M., Henriksson, G., Gellerstedt, G. (2005) Structural differences between the lignin-carbohydrate complexes present in wood and in chemical pulps. Biomacromolecules 6: 3467-3473.
21. Li, J., Martin-Samperdro, R., Pedrazzi, C., Gellerstedt, G. (2011) Fractionation and characterization of lignin-carbohydrate complexes (LCCs) from eucalyptus fibers. Holzforschung 65:43-50.
22. Lu, F., Ralph, J. (2003) Non-degradative dissolution and acetylation of ball-milled plant cell walls: high-resolution solution-state NMR. The Plant J. 35:535-544.