Octahydriodo diborane (B2H8) and its protonated cations containing five-, six-, and seven-coordinate boron atoms

Proceedings of the National Academy of Sciences of the United States of America

Volumn 109, Issue 18, 2012, Pages 6825-6828

  Olah, George A ^a   Prakash, G K Surya ^a   Rasul, Golam ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

Ab initio; Boronium; Cations; Hypercoordinate; Polycations

Indexed keywords

BORON DERIVATIVE; OCTAHYDRIODO DIBORANE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; CHEMICAL STRUCTURE; ELECTRON; ENERGY; HYDROGEN BOND; PRIORITY JOURNAL; PROTON TRANSPORT;

EID: 84860833040     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1204184109     Document Type: Article

References (22)

1. Olah GA, Prakash GKS, Wade K, Molnar A, Williams RE (2011) Hypercarbon Chemistry (Wiley, New York).
2. Haberlen OD, Schmidbaur H, Rosch N, Notker R (1994) Stability of main-group element-centered gold cluster cations. J Am Chem Soc 116:8241-8248. (Pubitemid 24981532)
3. Schreiner PR, Schaefer HF, Schleyer PvR (1996) Alkyl Cation-Dihydrogen Complexes; Silonium and Germonium Cations: Theoretical Considerations. Advances in Gas Phase Ion Chemistry, (JAI Press Inc., Greenwich, CT), 2, pp 125-160.
4. n+. J AmChem Soc 105:484-491.
5. Schmidbaur H (1995) Ludwig Mond lecture: High-carat gold compounds. Chem Soc Rev 24:391-400.
6. 2+. Angew Chem Int Ed Engl 27:1544-1546.
7. Grohmann A, Riede J, Schmidbaur H (1990) Electron-deficient bonding at pentacoordinate nitrogen. Nature 345:140-142. (Pubitemid 120028827)
8. Schmidbaur H, Beruda H, Zeller E (1994) Hyper-coordinate phosphorus atoms in a golden hour-glass. Phosphorus, Sulfur Silicon Relat Elem 87:245-255.
9. 3. Inorg Chem 32:3203-3204.
10. Schmidbaur H, Hofreiter S, Paul M (1995) Synthesis of the gold analog of the elusive doubly protonated water molecule. Nature 377:503-504.
11. Blumenthal A, Beruda H, Schmidbaur H (1993) Tetrakis[(triphenylphosphine) gold(I)] (tricyclohexylphosphine)boronium tetrafluoroborate, a novel boron-centered gold cluster. J Chem Soc Chem Commun 1005-1006.
12. 3+. Inorg Chem 36:1278-1281.
13. +. Nature 375:216-218.
14. +: The story goes on An explicitly correlated coupled-cluster study. J Chem Phys 106:1863-1869.
15. 2+. J Am Chem Soc 104:6851-6852.
16. Lammertsma K, et al. (1983) Carbodications 7. Structure and stability of diprotonated methane, CH62+. J Am Chem Soc 105:5258-5263. (Pubitemid 13587343)
17. 3+: The parent heptacoordinate carbonium ion. J Am Chem Soc 118:8503-8504.
18. Frisch MJ, et al. (2009) Gaussian 09 (Gaussian, Inc, Wallingford, CT) Revision A.02.
19. Foresman JB, Frisch A (1996) Exploring Chemistry with Electronic Structure Methods (Gaussian, Inc, Pittsburgh) p 64.
20. Martin JML, Oliveira GD (1999) Towards standard methods for benchmark quality ab initio thermochemistry-W1 and W2 theory. J Chem Phys 111:1843-1856. (Pubitemid 129576258)
21. Parthiban S, Martin JML (2001) Assessment of W1 and W2 theories for the computation of electron affinities, ionization potentials, heats of formation, and proton affinities. J Chem Phys 114:6014-6029. (Pubitemid 32419579)
22. Reed AE, Curtiss LA, Weinhold F (1988) Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint. Chem Rev 88:899-926.