-
3
-
-
80052533606
-
-
Williamson, B. R.,;, Krishnaswamay, R.,;, Tonelli, A. E., Polymer 2011, 52, 4517-4527.
-
(2011)
Polymer
, vol.52
, pp. 4517-4527
-
-
Williamson, B.R.1
Krishnaswamay, R.2
Tonelli, A.E.3
-
4
-
-
0025097454
-
-
for a discussion of Vectra, a liquid-crystalline ester/arylate copolymer, that evidences a macroscopically anisotropic melt, much like that suggested above locally for coalesced polymers
-
See, D. E. Beers,;, J. E. Ramirez, J. Text., Inst., 81, 561-574, 1990 for a discussion of Vectra, a liquid-crystalline ester/arylate copolymer, that evidences a macroscopically anisotropic melt, much like that suggested above locally for coalesced polymers.
-
(1990)
J. Text., Inst.
, vol.81
, pp. 561-574
-
-
Beers, D.E.1
Ramirez, J.E.2
-
5
-
-
34047200613
-
-
Vedula, J.,;, Tonelli, A. E., J. Polym. Sci. Part B: Polym. Phys. 2007, 45, 735-746.
-
(2007)
J. Polym. Sci. Part B: Polym. Phys.
, vol.45
, pp. 735-746
-
-
Vedula, J.1
Tonelli, A.E.2
-
6
-
-
79751525965
-
-
Mohan, A.,;, Gurarslan, A.,;, Joyner, X.,;, Child, R.,;, Tonelli, A. E., Polymer 2011, 52, 1055-1062.
-
(2011)
Polymer
, vol.52
, pp. 1055-1062
-
-
Mohan, A.1
Gurarslan, A.2
Joyner, X.3
Child, R.4
Tonelli, A.E.5
-
7
-
-
84860798875
-
-
Joijode, A. S.,;, Gurarslan, A.,;, Tonelli, A. E., in preparation.
-
In Preparation
-
-
Joijode, A.S.1
Gurarslan, A.2
Tonelli, A.E.3
-
8
-
-
84860805287
-
Chap. 11
-
2nd ed. J. E. Mark, Ed. Springer: NY, p
-
Mandelkern, L.,;, Alamo, R. G., Physical Properties of Polymers Handbook, 2nd ed.;, J. E. Mark, Ed.; Springer: NY, 2007, Chap. 11, p. 169-186.
-
(2007)
Physical Properties of Polymers Handbook
, pp. 169-186
-
-
Mandelkern, L.1
Alamo, R.G.2
-
9
-
-
0001032666
-
-
Fischer, E. W., Schmidt, G., Angew. Chem. 1962, 74, 551-562.
-
(1962)
Angew. Chem.
, vol.74
, pp. 551-562
-
-
Fischer, E.W.1
Schmidt, G.2
-
11
-
-
0016994298
-
-
Schelten, J.,;, Ballard, D. G. H.,;, Wignall, G. D.,;, Longman, G.,;, Schmatzl, W., Polymer 1976, 17, 751-757.
-
(1976)
Polymer
, vol.17
, pp. 751-757
-
-
Schelten, J.1
Ballard, D.G.H.2
Wignall, G.D.3
Longman, G.4
Schmatzl, W.5
-
12
-
-
0017493219
-
-
(a)
-
(a), Yoon, D. Y.,;, Flory, P. J., Polymer 1977, 18, 509-513
-
(1977)
Polymer
, vol.18
, pp. 509-513
-
-
Yoon, D.Y.1
Flory, P.J.2
-
13
-
-
0017835737
-
-
(b)
-
(b), Yoon, D. Y., Flory, P. J., Nature, 1978, 272, 226-229.
-
(1978)
Nature
, vol.272
, pp. 226-229
-
-
Yoon, D.Y.1
Flory, P.J.2
-
14
-
-
37049104089
-
-
Yoon, D. Y.,;, Flory, P. J., Faraday Dis. Chem. Soc. 1979, 68, 288-296.
-
(1979)
Faraday Dis. Chem. Soc.
, vol.68
, pp. 288-296
-
-
Yoon, D.Y.1
Flory, P.J.2
-
16
-
-
33947447711
-
-
Baker, W. O.,;, Fuller, C. S.,;, Pape, N. R., J. Am. Chem. Soc. 1942, 64, 776-782.
-
(1942)
J. Am. Chem. Soc.
, vol.64
, pp. 776-782
-
-
Baker, W.O.1
Fuller, C.S.2
Pape, N.R.3
-
18
-
-
0000648930
-
-
Hoffman, J. D.,;, Lauritzen, J. I. Jr., J. Res. Nat. Bur. Stds. 1961, 65A, 297.
-
(1961)
J. Res. Nat. Bur. Stds.
, vol.65 A
, pp. 297
-
-
Hoffman, J.D.1
Lauritzen Jr., J.I.2
-
19
-
-
79960026983
-
-
Gurarslan, A.,;, Tonelli, A. E., Macromolecules 2011, 44, 3856-3861.
-
(2011)
Macromolecules
, vol.44
, pp. 3856-3861
-
-
Gurarslan, A.1
Tonelli, A.E.2
-
20
-
-
0034288622
-
-
Phys. J. E
-
Strobl, G. Eur., Phys. J. E 2000, 3, 165-183.
-
(2000)
, vol.3
, pp. 165-183
-
-
Strobl, G.Eur.1
-
21
-
-
34247256676
-
-
Cho, T. Y.,;, Stille, W.,;, Strobl, G., Macromolecules 2007, 40, 2596-2999.
-
(2007)
Macromolecules
, vol.40
, pp. 2596-2999
-
-
Cho, T.Y.1
Stille, W.2
Strobl, G.3
-
25
-
-
0023997912
-
-
Zachariades, A. E.,;, Kanamoto, T., J. Appl. Polym. Sci. 1988, 35, 1265-1281.
-
(1988)
J. Appl. Polym. Sci.
, vol.35
, pp. 1265-1281
-
-
Zachariades, A.E.1
Kanamoto, T.2
-
26
-
-
23244447284
-
-
Rastogi, S.,;, Lippits, D. R.,;, Peters, G. W. M., Graf, R.,;, Yao, Y.,;, Spiess, H. W.,; Nat. Mater. 2005, 4, 635-641 Quoting Rastogi et al. ".crystals composed of single chains are feasible, where the chains are fully separated from each other. If such separation can be maintained in the melt a new melt state can be formed. Here, we show that through slow and carefully controlled melting such polymer crystals form a heterogeneous melt with more entangled regions, where the chains are mixed, and less entangled ones, composed of individually separated chains. Chain reptation, required for the homogenization of the entanglement distribution, is found to be considerably hindered. The long-lived heterogeneous melt shows decreased melt viscosity and provides enhanced drawability on crystallization." In contrast, the usual morphology of semicrystalline polymers with intimately mixed chains, as illustrated by the central drawing in Figure 5, is rapidly converted on heating into a homogeneous entangled melt of randomly coiling chains. Chain reptation is required to produce homogeneous melts from both semicrystalline morphologies. However, in the case of the slow heating of metallocene-catalyzed UHMW-PE nascent single-chain crystals, the initial rapid entanglements formed between portions of PE chains melting and detaching from the ends of different single-crystals serve to retard the further entanglement of the central portions of the PE chains, leading to a heterogeneous melt whose ultimate homogenization is thus retarded.
-
(2005)
Nat. Mater.
, vol.4
, pp. 635-641
-
-
Rastogi, S.1
Lippits, D.R.2
Peters, G.W.M.3
Graf, R.4
Yao, Y.5
Spiess, H.W.6
-
27
-
-
84860828566
-
-
gs observed for the unincluded portions of amorphous chains "dangling" above the surfaces of their CD-IC crystals are considerably elevated. This supports the observations that in the noncrystalline regions and melts of coalesced polymers the densities of chains are higher and they are likely not significantly entangled
-
gs observed for the unincluded portions of amorphous chains "dangling" above the surfaces of their CD-IC crystals are considerably elevated. This supports the observations that in the noncrystalline regions and melts of coalesced polymers the densities of chains are higher and they are likely not significantly entangled.
-
(2012)
Polymer
, vol.52
-
-
Antony, G.J.1
Tonelli, A.E.2
-
29
-
-
84860817370
-
-
In; Oxford University Press: NY
-
Mark, J. E., In Polymer Data Handbook Ed.; Oxford University Press: NY, 1999, pp. 629-633.
-
(1999)
Polymer Data Handbook Ed.
, pp. 629-633
-
-
Mark, J.E.1
-
30
-
-
0000851859
-
-
Rusa, C. C.,;, Tonelli, A. E., Macromolecules 2000, 33, 5321-5324.
-
(2000)
Macromolecules
, vol.33
, pp. 5321-5324
-
-
Rusa, C.C.1
Tonelli, A.E.2
-
31
-
-
18844428072
-
-
Uyar, T.,;, Rusa, C. C.,;, Hunt, M. A.,;, Aslan, E.,;, Hacaloglu, J.,;, Tonelli, A. E., Polymer 2005, 46, 4762-4775.
-
(2005)
Polymer
, vol.46
, pp. 4762-4775
-
-
Uyar, T.1
Rusa, C.C.2
Hunt, M.A.3
Aslan, E.4
Hacaloglu, J.5
Tonelli, A.E.6
|