Effect of isocyanate to hydroxyl index on the properties of clear polyurethane films

Progress in Organic Coatings

Volumn 74, Issue 3, 2012, Pages 572-581

  Levine, Felicia ^a   Escarsega, John ^a   La Scala, John ^a  

^a U S ARMY RESEARCH LABORATORY   (United States)

Author keywords

CARC; Crosslinking; Isocyanate to hydroxyl ratio; Permeability; Polyurethane; Tensile testing

Indexed keywords

ALIPHATIC ISOCYANATES; BARRIER PROPERTIES; CARC; DIMETHYL METHYLPHOSPHONATE; FILM PROPERTIES; HIGHER INDEX; HIGHER T; HYDROXYL GROUPS; ISOCYANATE GROUP; ISOCYANATE TO HYDROXYL RATIO; N-METHYLPYRROLIDONE; POLYURETHANE BINDERS; POLYURETHANE FILMS; RESISTANCE TO PERMEATION; T-BUTYL ACETATES; VOC CONTENT; WATER DISPERSIBLE; WATER-RESISTANCES;

CROSSLINKING; DISPERSIONS; ESTERS; MECHANICAL PERMEABILITY; MOLECULAR WEIGHT; ORGANIC SOLVENTS; POLYURETHANES; TENSILE TESTING; VOLATILE ORGANIC COMPOUNDS;

ALCOHOLS;

EID: 84860735283     PISSN: 03009440     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.porgcoat.2012.02.004     Document Type: Article

References (26)

1. MIL-DTL-64159, Detailed Specification Coating, Water Dispersible Aliphatic Polyurethane, Chemical Agent Resistant, 30 January 2002.
2. D.K. Lee, and H.B. Tsai J. Appl. Polym. Sci. 75 1 2000 167 174
3. Chemistry of Polyurethane Coatings A General Reference Manual 2005 Bayer MaterialScience Pittsburgh, PA August
4. J.A. Escarsega, K. Chesonis, D.M. Crawford, J.L. Duncan, and P. Smith AMPTIAC Quarterly 8 4 2004 96 100
5. D.M. Crawford, and J.A. Escarsega Thermochim. Acta 357-358 2000 161 168
6. Bayhydur 303 Technical Data Sheet, Bayer MaterialScience, Pittsburgh, PA, January 15, 2003.
7. Bayhydrol XP-7110 Product Information Sheet, Bayer MaterialScience, Pittsburgh, PA, October 2003.
8. Case Product Index, Bayer MaterialScience, Pittsburgh, PA, January 2009.
9. ASTM D 882-02 Standard Test Method for Tensile Properties of Thin Plastic Sheeting.
10. FY07 Annual Report For Simulant Selection for Protective Equipment Testing (CA06TAS438) ATEC Project No. 2006-DT-DPG-CBDPX-D1688, WDTC Document No. WDTC-XX-00-000, November 2007, unpublished, limited distribution.
11. E. Napadensky, Y.A. Elabd, Breathability and Selectivity of Selected Materials for Protective Clothing, ARL-TR-3235, July 2004.
12. F. Levine Prog. Org. Coat. 69 2010 63 72
13. ASTM E 96/E 96 M-05 Standard Test Methods for Water Vapor Transmission of Materials.
14. R. David, and Lide CRC Handbook of Chemistry and Physics 75th ed. 1994
15. The Merck Index. An Encyclopedia of Chemicals, Drugs, and Biologicals 13th ed. 2001 Merck and Co., Inc. Whitehouse Station, NJ
16. L.E. Nielsen, and R.F. Landel Mechanical Properties of Polymers and Composites 1994 Marcel Dekker New York pp. 140-142
17. Y. Shi J. Polym. Sci. A 46 2008 2433 2444
18. J.K. Gillham Polym. Eng. Sci. 26 1986 1429
19. J. Gotro, and R.B. Prime J. Kroschwitz, Encyclopedia of Polymer Science & Technology 3rd ed. 2004 John Wiley & Sons NY
20. G.R. Palmese, and R.L. McCullough J. Appl. Polym. Sci. 46 10 1992 1863 1873
21. P.J. Flory Principles of Polymer Chemistry 1953 Cornell University Press Ithica pp. 432-493
22. D.K. Chattopadhyay, and K.V.S.N. Raju Prog. Polym. Sci. 32 2007 355 356
23. M.W. Urban, C.L. Allison, C.C. Finch, and B.A. Tatro J. Coat. Tech. 71 January (888) 1999 75 85
24. J.P. Sheth Polymer 45 2004 6919 6932
25. F.P. Beer, E.R. Johnston Jr., and J.T. DeWolf Mechanics of Materials 3rd ed. 2002 McGraw Hill p. 673
26. W.R. Vieth Diffusion In and Through Polymers 1991 Oxford U. Press