Direct synthesis of B-allyl and B-allenyldiisopinocampheylborane reagents using allyl or propargyl halides and indium metal under Barbier-type conditions

Journal of Organic Chemistry

Volumn 77, Issue 9, 2012, Pages 4342-4353

  Hirayama, Lacie C ^a   Haddad, Terra D ^a   Oliver, Allen G ^a   Singaram, Bakthan ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL BROMIDE; ASYMMETRIC ADDITION; BORANE REAGENTS; COUPLING REACTION; DIRECT SYNTHESIS; ENANTIOMERIC EXCESS; HIGH YIELD; HOMOALLYLIC ALCOHOL; INDIUM METAL; ONE POT; ONE POT PROCESS; PROPARGYL; PROPARGYL HALIDES; PROPARGYLATION;

ALDEHYDES; ALLYLATION; BORON; BROMINE COMPOUNDS; CHEMICAL REACTIONS; ENANTIOSELECTIVITY; KETONES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION INTERMEDIATES;

ORGANIC COMPOUNDS;

ALCOHOL; ALDEHYDE; B ALLENYLDIISOPINOCAMPHEYLBORANE; B ALLYLDIISOPINOCAMPHEYLBORANE; BENZALDEHYDE; BORANE DERIVATIVE; BROMIDE; HALIDE; INDIUM; KETONE; REAGENT; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; CHEMICAL REACTION; CONTROLLED STUDY; ENANTIOSELECTIVITY; ONE POT SYNTHESIS; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 84860641907     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300260a     Document Type: Article

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