The effects of combining guaiacol and syringol on their pyrolysis

Holzforschung

Volumn 66, Issue 3, 2012, Pages 323-330

  Asmadi, Mohd ^a   Kawamoto, Haruo ^a   Saka, Shiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

aromatic ring; charring; coking; hydrogen donor; lignin; mixture effect; polyaromatization; pyrolysis

Indexed keywords

AROMATIC RINGS; CHARRING; HYDROGEN DONOR; MIXTURE EFFECTS; POLYAROMATIZATION;

ALCOHOLS; COKING; HYDROGEN; LIGNIN; PHENOLS;

PYROLYSIS;

EID: 84860640660     PISSN: 00183830     EISSN: 1437434X     Source Type: Journal    
DOI: 10.1515/hf.2011.165     Document Type: Article

References (47)

1. Afi fi , A.I., Hindermann, J.P., Chornet, E., Overend, R.P. (1989) The cleavage of the aryl-O-CH 3 bond using anisole as a model compound. Fuel 68:498-504.
2. Asmadi, M., Kawamoto, H., Saka, S. (2010) Pyrolysis reactions of Japanese cedar and Japanese beech woods in a closed ampoule reactor. J. Wood Sci. 56:319-330.
3. Asmadi, M., Kawamoto, H., Saka, S. (2011a) Thermal reactions of guaiacol and syringol as lignin model aromatic nuclei. J. Anal. Appl. Pyrol. 92:88-98.
4. Asmadi, M., Kawamoto, H., Saka, S. (2011b) Thermal reactivities of catechols/pyrogallols and cresols/xylenols as lignin pyrolysis intermediates. J. Anal. Appl. Pyrol. 92:76-87.
5. Bre ž n ý , R., Mih á lov, V., Kov á c? ik, V. (1983) Low temperature thermolysis of lignins - I. Reactions of β - O -4 model compounds. Holzforschung 37:199-204.
6. Bridgwater, A.V., Peacocke, G.V.C. (2000) Fast pyrolysis processes for biomass. Renew. Sust. Energ. Rev. 4:1-73.
7. Di Blasi, C., Branca, C., Santoro, A., Perez Bermdez, R.A. (2001a) Weight loss dynamics of wood chips under fast radiative heating. J. Anal. Appl. Pyrol. 57:77-90.
8. Di Blasi, C., Branca, C., Santoro, A., Gonzales Hernandez, E. (2001b) Pyrolytic behavior and products of some wood varieties. Comb. Flame 124:165-177.
9. Dobele, G., Dizhbite, T., Ponomarenko, J., Urbanovich, I., Kreicberga, J., Kampars, V. (2011) Isolation and characterization of the phenolic fractions of wood pyrolytic oil. Holzforschung 65:503-510.
10. Domburg, G.E., Rossinskaya, G., Sergeeva, V. (1974) Study of thermal stability of β -ether bonds in lignin and its models. In: Proceedings of the Fourth International Conference on Thermogravimetric Analysis, Akademia kaido, Budapest, Vol. 2. pp. 211 - 220.
11. Dorrestijn, E., Mulder, P. (1999) The radical-induced decomposition of 2-methoxyphenol. J. Chem. Soc. Perkin Trans. 2:777-780.
12. Evans, R.J., Milne, T.A. (1987) Molecular characterization of the pyrolysis of biomass. 2. Applications. Energ. Fuel. 1:311-319.
13. Evans, R.J., Milne, T.A., Soltys, M.N. (1986) Direct massspectrometric of the pyrolysis of carboneous fuels. III. Primary pyrolysis of lignin. J. Anal. Appl. Pyrol. 9:207-236.
14. Faix, O., Meier, D., Grobe, I. (1987) Studies on isolated lignins and lignins in woody materials by pyrolysis-gas chromatographymass spectrometry and off-line pyrolysis-gas chromatography with fl ame ionization detection. J. Anal. Appl. Pyrol. 11:403-416.
15. Faix, O., Jakab, E., Till, F., Szé kely, T. (1988) Study on low mass thermal degradation products of milled wood lignins by thermogravimetry- mass-spectrometry. Wood Sci. Technol. 22: 323-334.
16. Gardner, D.J., Schultz, T.P., McGinnis, G.D. (1985) The pyrolytic behavior of selected lignin preparations. J. Wood Chem. Technol. 5:85-110.
17. Genuit, W., Boon, J.J., Faix, O. (1987) Characterization of beech milled wood lignin by pyrolysis-gas chromatographyphotoionization mass spectrometry. Anal. Chem. 59:508-513.
18. Greenwood, P.F., van Heemst, J.D.H., Guthrie, E.A., Hatcher, P.G. (2002) Laser micropyrolysis GC-MS of lignin. J. Anal. Appl. Pyrol. 62:365-373.
19. Gr ø nli, M.G., V á rhegyi, G., Di Blasi, C. (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind. Eng. Chem. Res. 41:4201-4208.
20. Hosoya, T., Kawamoto, H., Saka, S. (2007) Pyrolysis behaviors of wood and its constituent polymers at gasifi cation temperature. J. Anal. Appl. Pyrol. 78:328-336.
21. Hosoya, T., Kawamoto, H., Saka, S. (2008a) Pyrolysis gasifi cation reactivities of primary tar and char fractions from cellulose and lignin as studied with a closed ampoule reactor. J. Anal. Appl. Pyrol. 83:71-77.
22. Hosoya, T., Kawamoto, H., Saka, S. (2008b) Secondary reactions of lignin-derived primary tar components. J. Anal. Appl. Pyrol. 83:78-87.
23. Hosoya, T., Kawamoto, H., Saka, S. (2009) Role of methoxyl group in char formation from lignin-related compounds. J. Anal. Appl. Pyrol. 84:79-83.
24. Kawamoto, H., Saka, S. (2007) Role of side-chain hydroxyl groups in pyrolytic reaction of phenolic β -ether type of lignin dimer. J. Wood Chem. Technol. 27:113-120.
25. Kawamoto, H., Horigoshi, S., Saka, S. (2006) Pyrolysis reactions of various lignin model dimers. J. Wood Sci. 53:168-174.
26. Kawamoto, H., Horigoshi, S., Saka, S. (2007) Effects of side-chain hydroxyl groups on pyrolytic β -ether cleavage of phenolic lignin model dimer. J. Wood Sci. 53:268-271.
27. Kawamoto, H., Nakamura, T., Saka, S. (2008a) Pyrolytic cleavage mechanisms of lignin-ether linkages: a study on p -substituted dimers and trimers. Holzforschung 62:50-56.
28. Kawamoto, H., Ryoritani, M., Saka, S. (2008b) Different pyrolytic cleavage mechanisms of β -ether bond depending on the sidechain structure of lignin dimers. J. Anal. Appl. Pyrol. 81:88-94.
29. Li, J., Li, B. Zhang, X. (2002) Comparative studies of thermal degradation between larch lignin and manchurian ash lignin. Polym. Degrad. Stabil. 78:279-285.
30. Liu, Q., Wang, S., Zheng, Y., Luo, Z., Cen, K. (2008) Mechanism study of wood lignin pyrolysis by using TG-FTIR analysis. J. Anal. Appl. Pyrol. 82:170-177.
31. Martin, F., Saiz-Jimenez, C., Gonzalez-Vila, F.J. (1979) Pyrolysis-gaschromatography-mass-spectrometry of lignins. Holzforschung 33:210-212.
32. Meier, D., Faix, O. (1992) Pyrolysis-gas chromatography-mass spectrometry. In: Methods in Lignin Chemistry. Eds. Lin, S.Y., Dence, C.W. Springer-Verlag, Berlin-Heidelberg. pp. 177 - 199.
33. Masuku, C.P. (1991) Thermal reactions of the bonds in lignin IV. Thermolysis of dimethoxyphenols. Holzforschung 45:181-190.
34. Nakamura, T., Kawamoto, H., Saka, S. (2007) Condensation reactions of some lignin related compounds at relatively low pyrolysis temperature. J. Wood Chem. Technol. 27:121-133.
35. Nakamura, T., Kawamoto, H., Saka, S. (2008) Pyrolysis behavior of Japanese cedar wood lignin studied with various model dimers. J. Anal. Appl. Pyrol. 81:173-182.
36. Obst, J.R. (1983) Analytical pyrolysis of hardwood and softwood lignins and its use in lignin-type determination of hardwood vessel element. J. Wood Chem. Technol. 3:377-397.
37. Parsons, A.F. (2000) An Introduction to Free Radical Chemistry. Blackwell Science, Oxford. pp. 87 - 90.
38. Saiz-Jimenez, C., De Leeuw, J.W. (1986) Lignin pyrolysis products: their structures and their signifi cance as biomarkers. Org. Geochem. 10:869-876.
39. Schlosberg, R.H., Szajowski, P.F., Dupre, G.D., Danik, J.A., Kurs, A., Ashe, T.R., Olmstead, W.N. (1983) Pyrolysis studies of organic oxygenates: 3. High temperature rearrangement of aryl alkyl ethers. Fuel 62:690-694.
40. Scott, D.S., Majerski, P., Piskorz, J., Radlein, D. (1999) A second look at fast pyrolysis of biomass - the RTI process. J. Anal. Appl. Pyrol. 51:23-37.
41. Shadkami, F., Helleur, R. (2010) Recent applications in analytical thermochemolysis. J. Anal. Appl. Pyrol. 89:2-16.
42. Vane, C.H., Abbott, G.D. (1999) Proxies for land plant biomass: closed system pyrolysis of some methoxyphenols. Org. Geochem. 30:1535-1541.
43. Vuori, A. (1986) Pyrolysis studies of some simple coal related aromatic methyl ethers. Fuel 65:1575-1583.
44. Vuori, A.I., Bredenberg, J.B. (1985) Thermolysis of substituted anisoles. ACS Div. Fuel Chem. 30:366-378.
45. Vuori, A.I., Bredenberg, J.B. (1987) Thermal chemistry pathways of substituted anisoles. Ind. Eng. Chem. Res. 26:359-365.
46. Watanabe, T., Kawamoto, H., Saka, S. (2009) Radical chain reactions in pyrolytic cleavage of the linkages of lignin model dimers and a trimer. Holzforschung 63:424-430.
47. Windt, M., Meier, D., Lehnen, R. (2011) Quantifi cation of polypropylene (PP) in wood plastic composites (WPCs) by analytical pyrolysis (Py) and differential scanning calorimetry (DSC). Holzforschung 65:199-207.