Bioethanol/glycerol mixture steam reforming over Pt and PtNi supported on lanthana or ceria doped alumina catalysts

International Journal of Hydrogen Energy

Volumn 37, Issue 10, 2012, Pages 8298-8309

  El Doukkali, M ^a   Iriondo, A ^a   Arias, P L ^a   Cambra, J F ^a   Gandarias, I ^a   Barrio, V L ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Alumina lanthana ceria; Catalytic steam reforming; Coke formation; Ethanol glycerol mixtures; Hydrogen; Platinum nickel catalysts

Indexed keywords

ACTIVE CATALYST; ACTIVE SITE; ALUMINA-LANTHANA-CERIA; BIMETALLIC CATALYSTS; CATALYTIC STEAM REFORMING; CATALYTIC SYSTEM; COKE FORMATION; DOPED ALUMINA; ETHANOL CONVERSION; FILAMENTOUS CARBON; GASEOUS PRODUCTS; LANTHANA; LIGHT ALKANES; LIQUID PRODUCTS; PT CATALYSTS; PT-NI CATALYSTS; REACTION TEMPERATURE; STEAM REFORMING OF ETHANOL; SURFACE ATOMIC RATIO; THERMODYNAMIC EQUILIBRIA;

ALDEHYDES; ALUMINA; CARBON NANOTUBES; CATALYST ACTIVITY; CERIUM; CERIUM COMPOUNDS; ETHANOL; ETHYLENE; GLYCEROL; HYDROGEN; LANTHANUM OXIDES; MIXTURES; PARAFFINS; PLATINUM; STEAM REFORMING; TEMPERATURE;

CATALYST SUPPORTS;

EID: 84860385725     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.02.154     Document Type: Article

References (47)

1. 3 modified by Mg, Zr, Ce or La Top Catal 49 2008 46 58
2. B. Zhang, X. Tang, Y. Li, Y. Xu, and W. Shen Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts Int J Hydrogen Energy 32 2007 2367 2373
3. 2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts Catal Commun 10 2004 611 615
4. 2 catalysts: the effect of the reaction conditions and reaction mechanism J Catal 233 2005 453 463
5. A.N. Fatsikostas, and E.X. Verykios Reaction network of steam reforming of ethanol over Ni-based catalysts J Catal 225 2004 439 452
6. M. Pagliaro, and M. Rossi The future of glycerol; new usages for versatile raw material 2008 Royal Society of Chemistry Cambridge CB4 0WF, UK
7. A. Iriondo, V.L. Barrio, M. El Doukkali, J.F. Cambra, M.B. Güemez, and J. Requies Biohydrogen production by gas phase reforming of glycerin and ethanol mixtures Int J Hydrogen Energy 37 2012 2028 2036
8. J.H. Sinfelt Specificity in catalytic hydrogenolysis by metals D.D. Eley, Advances in catalysis 1973 Academic Press 91 119
9. D.C. Grenoble, M.M. Estadt, and D.F. Ollis The chemistry and catalysis of the water gas shift reaction: 1. The kinetics over supported metal catalysts J Catal 67 1981 90 102
10. S. Adhikari, S.D. Fernando, and A. Haryanto Hydrogen production from glycerin by steam reforming over nickel catalysts Renewable Energy 33 2008 1097 1100
11. 3 binary oxides prepared by sol-gel Mater Res Bull 42 2007 640 648
12. A.N. Fatsikostas, D.I. Kondarides, and X.E. VeryKios Steam reforming of biomass-derived ethanol for the production of hydrogen for fuel cell applications Chem Commun 9 2001 851 852
13. 3 modified support and Ni and Pt active phases on glycerol steam reforming to produce hydrogen Catal Commun 10 2009 1275 1278
14. A. Iriondo, V.L. Barrio, J.F. Cambra, P.L. Arias, M.B. Güemez, and R.M. Navarro Glycerol steam reforming over Ni catalysts supported on ceria and ceria-promoted alumina Int J Hydrogen Energy 35 2010 11622 11633
15. T. Bunluesin, R.J. Gorte, and G.W. Graham Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen-storage properties Appl Catal B 15 1998 107 114
16. 2- containing materials Catal Rev Sci Eng 38 1996 439 520
17. A. Iriondo, V.L. Barrio, J.F. Cambra, P.L. Arias, M.B. Güemez, and R.M. Navarro Glycerol liquid phase conversion over monometallic and bimetallic catalysts: Effect of metal, support type and reaction temperatures Appl Catal B 106 2011 83 93
18. Sanchez-Sanchez MC. PhD thesis, Institute of Catalysis and Petrochemistry (ICP-CSIC), Madrid, 2008.
19. M. Ni, D.Y.C. Leung, and M.K.H. Leung A review on reforming bio-ethanol for hydrogen production Int J Hydrogen Energy 32 2007 3238 3247
20. R.D. Cortright, R.R. Davda, and J.A. Dumesic Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water Nature 418 2002 964 966
21. A. Corma, G.W. Huber, L. Sauvanaud, and P. O'Connor Biomass to chemicals: catalytic conversion of glycerol/water mixtures into acrolein, reaction network J Catal 257 2008 163 171
22. J.B. Paine III, Y.B. Pithawalla, J.D. Naworal, and C.E. Thomas Jr. Carbohydrate pyrolysis mechanisms from isotopic labeling: Part 1. The pyrolysis of glycerin: discovery of competing fragmentation mechanisms affording acetaldehyde and formaldehyde and the implications for carbohydrate pyrolysis J Anal Appl Pyrolysis 80 2007 297 311
23. A.J. Vizcaíno, P. Arena, G. Baronetti, A. Carrero, J.A. Calles, and M.A. Laborde Ethanol steam reforming on Ni/Al2O3 catalysts: effect of Mg addition Int J Hydrogen Energy 33 2008 3489 3492
24. J.R. Mawdsley, and T.R. Krause Rare earth-first-row transition metal perovskites as catalysts for the autothermal reforming of hydrocarbon fuels to generate hydrogen Appl Catal A Gen 334 2008 311 320
25. 3 (M = Ce, La, Zr and Mg) catalysts: Influence of support on the hydrogen production Int J Hydrogen Energy 32 2007 1462 1471
26. J.P. Breen, R. Burch, and H.M. Coleman Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications Appl Catal B 39 2002 65 74
27. 3 catalysts for fuel-cell application Int J Hydrogen Energy 30 2005 437 445
28. 3 catalysts in propane steam reforming J Catal 234 2005 496 508
29. 3 Stud Surf Sci 6 1980 53 62
30. J.M. Parera, N.S. Figoli, and E.M. Traffano Catalytic action of platinum on coke burning J Catal 79 1983 481 484
31. M.R. Jovanovic, and P.S. Putanov Nature and distribution of coke formed on mono-metallic platinum and bimetallic platinum-rhenium catalysts Appl Catal A Gen 159 1997 1 7
32. 2 reforming of methane to syngas Appl Catal A Gen 244 2003 181 195
33. 2 Int J Hydrogen Energy 34 2009 2224 2234
34. B. Zhang, X. Tang, Y. Li, W. Cai, Y. Xu, and W. Shen Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts Catal Commun 7 2006 367 372
35. 3 catalysts Fuel 87 2008 2502 2511
36. W. Li, H. Zhang, C. Wang, Y. Zhang, L. Xu, and K. Zhu Raman characterization of aligned carbon nanotubes produced by thermal decomposition of hydrocarbon vapor Appl Phys Lett 70 1997 2684 2686
37. P.C. Eklund, J.M. Holden, and R.A. Jishi Vibrational modes of carbon nanotubes: spectroscopy and theory Carbon 33 1995 959 972
38. M.S. Dresselhaus, G. Dresselhaus, A. Jorio, A.G. Souza Filho, and R. Saito Raman spectroscopy on isolated single wall carbon nanotubes Carbon 40 2002 2043 2061
39. C. Pan, and Q. Bao Well-aligned carbon nanotubes from ethanol flames J Mater Sci Lett 21 2002 1927 1929
40. M. García-Diéguez, I.S. Pieta, M.C. Herrera, M.A. Larrubia, and L.J. Alemany Improved Pt-Ni nanocatalysts for dry reforming of methane Appl Catal A Gen 377 2010 191 199
41. 2-reforming of methane J Catal 270 2010 136 145
42. García-Diéguez M. PhD thesis, University of Malaga, Spain, 2010.
43. Y. Liu, C. Pan, and J. Wang Raman spectra of carbon nanotubes and nanofibers prepared by ethanol flames J Mater Sci 39 2004 1091 1094
44. H. Oudghiri-Hassani, S. Rakass, N. Abatzoglou, and P. Rowntree Inhibition of carbon formation during steam reforming of methane using thiol-coated nickel catalysts J Power Sources 171 2007 850 855
45. 2 Appl Catal A Gen 323 2007 188 201
46. 3 in propane dehydrogenation J Ind Eng Chem 17 2011 71 76
47. 2 J Catal 197 2001 34 42