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Volumn 6, Issue 4, 2012, Pages 3034-3043

Local electronic structure and density of edge and facet atoms at Rh nanoclusters self-assembled on a graphene template

Author keywords

catalysis; core level photoelectron spectroscopy; density functional theory; graphene; nanoclusters; rhodium; scanning tunneling microscopy

Indexed keywords

CORE ELECTRON BINDING ENERGIES; CORE-LEVEL PHOTOELECTRON SPECTROSCOPY; DEGREE OF STRUCTURAL ORDER; FINITE SIZE EFFECT; HIGH-ENERGY RESOLUTION; INTER-ATOMIC DISTANCES; LOCAL ELECTRONIC STRUCTURES; NANOFACETS; SELF-ASSEMBLED; SURFACE ATOMS;

EID: 84860382319     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn300651s     Document Type: Article
Times cited : (52)

References (52)
  • 2
    • 77955319552 scopus 로고    scopus 로고
    • Nanoscale Advances in Catalysis and Energy Applications
    • Li, Y.; Somorjai, G. A. Nanoscale Advances in Catalysis and Energy Applications Nano Lett. 2010, 10, 2289-2295
    • (2010) Nano Lett. , vol.10 , pp. 2289-2295
    • Li, Y.1    Somorjai, G.A.2
  • 3
    • 0009746572 scopus 로고
    • Gold Catalysts Prepared by Coprecipitation for Low-Temperature Oxidation of Hydrogen and of Carbon Monoxide
    • Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. Gold Catalysts Prepared by Coprecipitation for Low-Temperature Oxidation of Hydrogen and of Carbon Monoxide J. Catal. 1989, 115, 301-309
    • (1989) J. Catal. , vol.115 , pp. 301-309
    • Haruta, M.1    Yamada, N.2    Kobayashi, T.3    Iijima, S.4
  • 4
    • 0032508688 scopus 로고    scopus 로고
    • Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties
    • Valden, M.; Lai, X.; Goodman, D. W. Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties Science 1998, 281, 1647-1650
    • (1998) Science , vol.281 , pp. 1647-1650
    • Valden, M.1    Lai, X.2    Goodman, D.W.3
  • 5
    • 5044227264 scopus 로고    scopus 로고
    • The Active Site in Nanoparticle Gold Catalysis
    • Campbell, C. T. The Active Site in Nanoparticle Gold Catalysis Science 2004, 306, 234-235
    • (2004) Science , vol.306 , pp. 234-235
    • Campbell, C.T.1
  • 7
    • 34248196976 scopus 로고    scopus 로고
    • Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-oxidation Activity
    • Tian, N.; Zhou, Z.-Y.; Sun, S.-G.; Ding, Y.; Wang, Z. L. Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-oxidation Activity Science 2007, 316, 732-735
    • (2007) Science , vol.316 , pp. 732-735
    • Tian, N.1    Zhou, Z.-Y.2    Sun, S.-G.3    Ding, Y.4    Wang, Z.L.5
  • 10
    • 0042285085 scopus 로고    scopus 로고
    • The Remarkable Difference between Surface and Step Atoms in the Magnetic Anisotropy of Two-Dimensional Nanostructures
    • Rusponi, S.; Cren, T.; Weiss, N.; Epple, M.; Buluschek, P.; Claude, L.; Brune, H. The Remarkable Difference between Surface and Step Atoms in the Magnetic Anisotropy of Two-Dimensional Nanostructures Nat. Mater. 2003, 2, 546-551
    • (2003) Nat. Mater. , vol.2 , pp. 546-551
    • Rusponi, S.1    Cren, T.2    Weiss, N.3    Epple, M.4    Buluschek, P.5    Claude, L.6    Brune, H.7
  • 11
    • 81855227143 scopus 로고    scopus 로고
    • Ultra-Large-Area Self-Assembled Monolayers of Nanoparticles
    • Wen, T.; Majetich, S. A. Ultra-Large-Area Self-Assembled Monolayers of Nanoparticles ACS Nano 2011, 5, 8868-8876
    • (2011) ACS Nano , vol.5 , pp. 8868-8876
    • Wen, T.1    Majetich, S.A.2
  • 12
    • 33751299299 scopus 로고    scopus 로고
    • Two-Dimensional Ir Cluster Lattice on a Graphene Moiré on Ir(111)
    • NDiaye, A. T.; Bleikamp, S.; Feibelman, P. J.; Michely, T. Two-Dimensional Ir Cluster Lattice on a Graphene Moiré on Ir(111) Phys. Rev. Lett. 2006, 97, 215501
    • (2006) Phys. Rev. Lett. , vol.97 , pp. 215501
    • Ndiaye, A.T.1    Bleikamp, S.2    Feibelman, P.J.3    Michely, T.4
  • 14
    • 77953287273 scopus 로고    scopus 로고
    • Deposition of Metal Clusters on Single-Layer Graphene/Ru(0001): Factors That Govern Cluster Growth
    • Zhou, Z.; Gao, F.; Goodman, D. W. Deposition of Metal Clusters on Single-Layer Graphene/Ru(0001): Factors That Govern Cluster Growth Surf. Sci. 2010, 604, L31-L38
    • (2010) Surf. Sci. , vol.604
    • Zhou, Z.1    Gao, F.2    Goodman, D.W.3
  • 15
    • 78751562551 scopus 로고    scopus 로고
    • Formation of Identical-Size Graphene Nanoclusters on Ru(0001)
    • Cui, Y.; Fu, Q.; Zhang, H.; Bao, X. Formation of Identical-Size Graphene Nanoclusters on Ru(0001) Chem. Commun. 2011, 47, 1470-1472
    • (2011) Chem. Commun. , vol.47 , pp. 1470-1472
    • Cui, Y.1    Fu, Q.2    Zhang, H.3    Bao, X.4
  • 16
    • 79951841992 scopus 로고    scopus 로고
    • Nucleation and Growth of Monodispersed Cobalt Nanoclusters on Graphene Moiré on Ru(0001)
    • Liao, Q.; Zhang, H. J.; Wu, K.; Li, H. Y.; Bao, S. N.; He, P. Nucleation and Growth of Monodispersed Cobalt Nanoclusters on Graphene Moiré on Ru(0001) Nanotechnology 2011, 22, 125303
    • (2011) Nanotechnology , vol.22 , pp. 125303
    • Liao, Q.1    Zhang, H.J.2    Wu, K.3    Li, H.Y.4    Bao, S.N.5    He, P.6
  • 17
    • 69949166116 scopus 로고    scopus 로고
    • Directed Self-Assembly of Monodispersed Platinum Nanoclusters on Graphene Moirè Template
    • Pan, Y.; Gao, M.; Huang, L.; Liu, F.; Gao, H.-J. Directed Self-Assembly of Monodispersed Platinum Nanoclusters on Graphene Moirè Template Appl. Phys. Lett. 2009, 95, 093106
    • (2009) Appl. Phys. Lett. , vol.95 , pp. 093106
    • Pan, Y.1    Gao, M.2    Huang, L.3    Liu, F.4    Gao, H.-J.5
  • 20
    • 70349910449 scopus 로고    scopus 로고
    • Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Using Graphene-Based Moiré Patterns as Templates
    • Mao, J.; Zhang, H.; Jiang, Y.; Pan, Y.; Gao, M.; Xiao, W.; Gao, H.-J. Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Using Graphene-Based Moiré Patterns as Templates J. Am. Chem. Soc. 2009, 131, 14136-14137
    • (2009) J. Am. Chem. Soc. , vol.131 , pp. 14136-14137
    • Mao, J.1    Zhang, H.2    Jiang, Y.3    Pan, Y.4    Gao, M.5    Xiao, W.6    Gao, H.-J.7
  • 21
    • 47749150628 scopus 로고    scopus 로고
    • Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
    • Lee, C.; Wei, X.; Kysar, J. W.; Hone, J. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Science 2008, 321, 385-388
    • (2008) Science , vol.321 , pp. 385-388
    • Lee, C.1    Wei, X.2    Kysar, J.W.3    Hone, J.4
  • 23
    • 67649225738 scopus 로고    scopus 로고
    • Graphene: Status and Prospects
    • Geim, A. K. Graphene: Status and Prospects Science 2009, 324, 1530-1534
    • (2009) Science , vol.324 , pp. 1530-1534
    • Geim, A.K.1
  • 24
    • 77955523549 scopus 로고    scopus 로고
    • Platinum Nanoparticle Ensemble-on-Graphene Hybrid Nanosheet: One-Pot, Rapid Synthesis, and Used as New Electrode Material for Electrochemical Sensing
    • Guo, S.; Wen, D.; Zhai, Y.; Dong, S.; Wang, E. Platinum Nanoparticle Ensemble-on-Graphene Hybrid Nanosheet: One-Pot, Rapid Synthesis, and Used as New Electrode Material for Electrochemical Sensing ACS Nano 2010, 4, 3959-3968
    • (2010) ACS Nano , vol.4 , pp. 3959-3968
    • Guo, S.1    Wen, D.2    Zhai, Y.3    Dong, S.4    Wang, E.5
  • 25
    • 66749106298 scopus 로고    scopus 로고
    • Enhanced Electrocatalytic Activity of Pt Subnanoclusters on Graphene Nanosheet Surface
    • Yoo, E.; Okata, T.; Akita, T.; Kohyama, M.; Nakamura, J.; Honma, I. Enhanced Electrocatalytic Activity of Pt Subnanoclusters on Graphene Nanosheet Surface Nano Lett. 2009, 9, 2255
    • (2009) Nano Lett. , vol.9 , pp. 2255
    • Yoo, E.1    Okata, T.2    Akita, T.3    Kohyama, M.4    Nakamura, J.5    Honma, I.6
  • 26
    • 80455158371 scopus 로고    scopus 로고
    • Graphene-Supported Pt-Au Alloy Nanoparticles: A Highly Efficient Anode for Direct Formic Acid Fuel Cells
    • Venkateswara Rao, C.; Cabrera, C. R.; Ishikawa, Y. Graphene-Supported Pt-Au Alloy Nanoparticles: A Highly Efficient Anode for Direct Formic Acid Fuel Cells J. Phys. Chem. C 2011, 115, 21963-21970
    • (2011) J. Phys. Chem. C , vol.115 , pp. 21963-21970
    • Venkateswara Rao, C.1    Cabrera, C.R.2    Ishikawa, Y.3
  • 27
    • 41149131694 scopus 로고    scopus 로고
    • Coordination-Dependent Surface Atomic Contraction in Nanocrystals Revealed by Coherent Diffraction
    • Huang, W. J.; Sun, R.; Tao, J.; Menard, L. D.; Nuzzo, R. G.; Zuo, J. M. Coordination-Dependent Surface Atomic Contraction in Nanocrystals Revealed by Coherent Diffraction Nat. Mater. 2008, 7, 308-313
    • (2008) Nat. Mater. , vol.7 , pp. 308-313
    • Huang, W.J.1    Sun, R.2    Tao, J.3    Menard, L.D.4    Nuzzo, R.G.5    Zuo, J.M.6
  • 28
    • 4243412584 scopus 로고    scopus 로고
    • Surface Relaxation and Ferromagnetism of Rh(001)
    • Cho, J.-H.; Scheffler, M. Surface Relaxation and Ferromagnetism of Rh(001) Phys. Rev. Lett. 1997, 78, 1299-1302
    • (1997) Phys. Rev. Lett. , vol.78 , pp. 1299-1302
    • Cho, J.-H.1    Scheffler, M.2
  • 30
    • 77954904177 scopus 로고    scopus 로고
    • High-Resolution Fast X-ray Photoelectron Spectroscopy Study of Ethylene Interaction with Ir(111): From Chemisorption to Dissociation and Graphene Formation
    • Lizzit, S.; Baraldi, A. High-Resolution Fast X-ray Photoelectron Spectroscopy Study of Ethylene Interaction with Ir(111): From Chemisorption to Dissociation and Graphene Formation Catal. Today 2010, 154, 68-74
    • (2010) Catal. Today , vol.154 , pp. 68-74
    • Lizzit, S.1    Baraldi, A.2
  • 31
    • 49249104123 scopus 로고    scopus 로고
    • Controlling Graphene Corrugation on Lattice-Mismatched Substrates
    • Preobrajenski, A.; Ng, M.; Vinogradov, A.; Martensson, N. Controlling Graphene Corrugation on Lattice-Mismatched Substrates Phys. Rev. B 2008, 78, 073401
    • (2008) Phys. Rev. B , vol.78 , pp. 073401
    • Preobrajenski, A.1    Ng, M.2    Vinogradov, A.3    Martensson, N.4
  • 32
    • 70349909918 scopus 로고    scopus 로고
    • Growth of Dome-Shaped Carbon Nanoislands on Ir(111): The Intermediate between Carbidic Clusters and Quasi-Free-Standing Graphene
    • Lacovig, P.; Pozzo, M.; Alfè, D.; Vilmercati, P.; Baraldi, A.; Lizzit, S. Growth of Dome-Shaped Carbon Nanoislands on Ir(111): The Intermediate between Carbidic Clusters and Quasi-Free-Standing Graphene Phys. Rev. Lett. 2009, 103, 166101
    • (2009) Phys. Rev. Lett. , vol.103 , pp. 166101
    • Lacovig, P.1    Pozzo, M.2    Alfè, D.3    Vilmercati, P.4    Baraldi, A.5    Lizzit, S.6
  • 33
    • 79961067408 scopus 로고    scopus 로고
    • Strain-Driven Moirè Superstructures of Epitaxial Graphene on Transition Metal Surfaces
    • Merino, P.; Svec, M.; Pinardi, A. L.; Otero, G.; Martìn-Gago, J. A. Strain-Driven Moirè Superstructures of Epitaxial Graphene on Transition Metal Surfaces ACS Nano 2011, 5, 5627-5634
    • (2011) ACS Nano , vol.5 , pp. 5627-5634
    • Merino, P.1    Svec, M.2    Pinardi, A.L.3    Otero, G.4    Martìn-Gago, J.A.5
  • 34
    • 42449143086 scopus 로고    scopus 로고
    • Pinning of Graphene to Ir(111) by Flat Ir Dots
    • Feibelman, P. J. Pinning of Graphene to Ir(111) by Flat Ir Dots Phys. Rev. B 2008, 77, 165419
    • (2008) Phys. Rev. B , vol.77 , pp. 165419
    • Feibelman, P.J.1
  • 36
    • 29244431969 scopus 로고    scopus 로고
    • Morphology of Supported Nanoparticles
    • Henry, C. R. Morphology of Supported Nanoparticles Prog. Surf. Sci. 2005, 80, 92-116
    • (2005) Prog. Surf. Sci. , vol.80 , pp. 92-116
    • Henry, C.R.1
  • 38
    • 0001118009 scopus 로고
    • Surface Core-Level Shifts of Some 4d-Metal Single-Crystal Surfaces: Experiments and Ab Initio Calculations
    • Andersen, J. N.; Hennig, D.; Lundgren, E.; Methfessel, M.; Nyholm, R.; Scheffler, M. Surface Core-Level Shifts of Some 4d-Metal Single-Crystal Surfaces: Experiments and Ab Initio Calculations Phys. Rev. B 1994, 50, 17525-17533
    • (1994) Phys. Rev. B , vol.50 , pp. 17525-17533
    • Andersen, J.N.1    Hennig, D.2    Lundgren, E.3    Methfessel, M.4    Nyholm, R.5    Scheffler, M.6
  • 39
    • 41849147540 scopus 로고    scopus 로고
    • Structure and Chemical Reactivity of Transition Metal Surfaces as Probed by Synchrotron Radiation Core Level Photoelectron Spectroscopy
    • Baraldi, A. Structure and Chemical Reactivity of Transition Metal Surfaces as Probed by Synchrotron Radiation Core Level Photoelectron Spectroscopy J. Phys.: Condens. Matter 2008, 20, 093001
    • (2008) J. Phys.: Condens. Matter , vol.20 , pp. 093001
    • Baraldi, A.1
  • 44
    • 4143079428 scopus 로고
    • Why Gold Is the Noblest of All the Metals
    • Hammer, B.; Nrskov, J. K. Why Gold Is the Noblest of All the Metals Nature 1995, 376, 238-240
    • (1995) Nature , vol.376 , pp. 238-240
    • Hammer, B.1    Nrskov, J.K.2
  • 45
    • 3342922611 scopus 로고    scopus 로고
    • CO Chemisorption at Metal Surfaces and Overlayers
    • Hammer, B.; Morikawa, Y.; Nrskov, J. K. CO Chemisorption at Metal Surfaces and Overlayers Phys. Rev. Lett. 1996, 76, 2141-2144
    • (1996) Phys. Rev. Lett. , vol.76 , pp. 2141-2144
    • Hammer, B.1    Morikawa, Y.2    Nrskov, J.K.3
  • 47
    • 13444280355 scopus 로고    scopus 로고
    • Spontaneous Hierarchical Assembly of Rhodium Nanoparticles into Spherical Aggregates and Superlattices
    • Ewers, T. D.; Sra, A. K.; Norris, B. C.; Cable, R. E.; Cheng, C.-H.; Shantz, D. F.; Schaak, R. E. Spontaneous Hierarchical Assembly of Rhodium Nanoparticles into Spherical Aggregates and Superlattices Chem. Mater. 2005, 17, 514-520
    • (2005) Chem. Mater. , vol.17 , pp. 514-520
    • Ewers, T.D.1    Sra, A.K.2    Norris, B.C.3    Cable, R.E.4    Cheng, C.-H.5    Shantz, D.F.6    Schaak, R.E.7
  • 48
    • 2442537377 scopus 로고    scopus 로고
    • Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set
    • Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set Phys. Rev. B 1996, 54, 11169
    • (1996) Phys. Rev. B , vol.54 , pp. 11169
    • Kresse, G.1    Furthmüller, J.2
  • 49
    • 4243943295 scopus 로고    scopus 로고
    • Generalized Gradient Approximation Made Simple
    • Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized Gradient Approximation Made Simple Phys. Rev. Lett. 1996, 77, 3865
    • (1996) Phys. Rev. Lett. , vol.77 , pp. 3865
    • Perdew, J.P.1    Burke, K.2    Ernzerhof, M.3
  • 50
    • 0033115287 scopus 로고    scopus 로고
    • Ab Initio Molecular Dynamics, a Simple Algorithm for Charge Extrapolation
    • Alfè, D. Ab Initio Molecular Dynamics, a Simple Algorithm for Charge Extrapolation Comput. Phys. Commun. 1999, 118, 31
    • (1999) Comput. Phys. Commun. , vol.118 , pp. 31
    • Alfè, D.1
  • 51
    • 25744460922 scopus 로고
    • Projector Augmented-Wave Method
    • Blöchl, P. E. Projector Augmented-Wave Method Phys. Rev. B 1994, 50, 17953
    • (1994) Phys. Rev. B , vol.50 , pp. 17953
    • Blöchl, P.E.1
  • 52
    • 0011236321 scopus 로고    scopus 로고
    • From Ultrasoft Pseudopotentials to the Projector Augmented-Wave Method
    • Kresse, G.; Joubert, D. From Ultrasoft Pseudopotentials to the Projector Augmented-Wave Method Phys. Rev. B 1999, 59, 1758
    • (1999) Phys. Rev. B , vol.59 , pp. 1758
    • Kresse, G.1    Joubert, D.2


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