Vibrational and elastic properties of ferromagnesite across the electronic spin-pairing transition of iron

American Mineralogist

Volumn 97, Issue 4, 2012, Pages 583-591

  Lin, Jung Fu ^a   Liu, Jin ^a   Jacobs, Caleb ^a   Prakapenka, Vitali B ^b  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b UNIVERSITY OF CHICAGO   (United States)

Author keywords

Diamond anvil cell; Ferromagnesite; Raman spectroscopy; Spin transition; X ray diffraction

Indexed keywords

BOND LENGTH; IRON; IRON ORES; MAGNESIA; RAMAN SPECTROSCOPY; SPIN DYNAMICS; THERMODYNAMIC PROPERTIES; X RAY DIFFRACTION;

COMPOSITIONAL EFFECTS; DIAMOND-ANVIL CELL; FERROMAGNESITE; PHYSICAL AND CHEMICAL PROPERTIES; SPIN TRANSITION; SYMMETRIC STRETCHING; TRANSITION PRESSURE; X-RAY DIFFRACTION SPECTROSCOPY;

ELASTICITY;

DIAMOND ANVIL CELL; ELASTIC PROPERTY; HIGH PRESSURE; IRON; RAMAN SPECTROSCOPY; SIDERITE; THERMODYNAMIC PROPERTY; X-RAY DIFFRACTION;

EID: 84860316579     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2012.3961     Document Type: Article

References (64)

1. Anderson, O.L. (2000) The Grüneisen ratio for the last 30 years. Geophysical Journal International, 143, 279-294.
2. Biellmann, C., Gillet, P., Guyot, F., Peyronneau, J., and Reynard, B. (1993) Experimental evidence for carbonate stability in the Earth's lower mantle. Earth and Planetary Science Letters, 118, 31-41. (Pubitemid 24418294)
3. Birch, F. (1978) Finite strain isotherm and velocities for single crystal and polycrystalline NaCl at high pressure and 300 K. Journal of Geophysical Research, 83, 1257-1268.
4. Bischoff, W.D., Sharma, S.K., and Mackenzie, F.T. (1985) Carbonate ion disorder in synthetic and biogenic magnesian calcites: A Raman spectral study. American Mineralogist, 70, 581-589.
5. Born, M. and Huang, K. (1954) Dynamical theory of crystal lattices. Oxford University Press, U.K.
6. Boulard, E., Gloter, A., Corgne, A., Antonangeli, D., Auzende, A.L., Perrillat, J.P., Guyot, F., and Fiquet, G. (2011) New host for carbon in the deep Earth. Proceedings of the National Academy of Sciences, 108, 5184-5187.
7. Brenker, F.E., Vollmer, C., Vincze, L., Vekemans, B., Szymanski, A., Janssens, K., Szaloki, I., Nasdala, L., Joswig, W., and Kaminsky, F. (2007) Carbonates from the lower part of transition zone or even the lower mantle. Earth and Planetary Science Letters, 260, 1-9. (Pubitemid 47040581)
8. Buzgar, N. and Apopei, A. (2009) The Raman study of certain carbonates. Geologie. Tomul LV, 2, 97-112.
9. Clark, S.J., Jouanna, P., Haines, J., and Mainprice, D. (2011) Calculation of infrared and Raman vibration modes of magnesite at high pressure by density-functional perturbation theory and comparison with experiments. Physics and Chemistry of Minerals, 38, 193-202.
10. Crowhurst, J.C., Brown, J.M., Goncharov, A.F., and Jacobsen, S.D. (2008) Elasticity of (Mg,Fe)O through the spin transition of iron in the lower mantle. Science, 319, 451-453. (Pubitemid 351160575)
11. Dasgupta, R. and Hirschmann, M.M. (2010) The deep carbon cycle and melting in Earth's interior. Earth and Planetary Science Letters, 298, 1-13.
12. Edwards, H.G.M., Jorge Villar, S.E., Jehlicka, J., and Munshi, T. (2005) FT-Raman spectroscopic study of calcium-rich and magnesium-rich carbonate minerals. Spectrochimica Acta Part A, 61, 2273-2280. (Pubitemid 41000349)
13. Fei, Y., Zhang, L., Corgne, A., Watson, H., Ricolleau, Meng, Y., and Prakapenka, V. (2007a) Spin transition and equations of state of (Mg,Fe)O solid solutions. Geophysical Research Letters, 34, L17307.
14. Fei, Y., Ricolleau, A., Frank, M., Mibe, K., Shen, G., and Prakapenka, V. (2007b) Towards an internally consistent pressure scale. Proceedings of the National Academy of Sciences, 104, 9182-9186. (Pubitemid 47185754)
15. Fiquet, G. and Reynard, B. (1999) High-pressure equation of state of magnesite: New data and a reappraisal. American Mineralogist, 84, 856-860. (Pubitemid 29497009)
16. 3. American Mineralogist, 79, 15-23. (Pubitemid 24425564)
17. Fiquet, G., Guyot, F., Kunz, M., Matas, J., Andrault, D., and Hanfland, M. (2002) Structural refinements of magnesite at very high pressure. American Mineralogist, 87, 1261-1265. (Pubitemid 35151385)
18. Ghosh, S., Ohtani, E., Litasov, K.D., and Terasaki, H. (2009) Solidus of carbonated peridotite from 10 to 20 GPa and origin of magnesiocarbonatite melt in the Earth's deep mantle. Chemical Geolology, 262, 17-28.
19. Gillet, P., Biellmann, C., Reynard, B., and McMillan, P. (1993) Raman spectroscopic studies of carbonates Part I: High-pressure and high-temperature behaviour of calcite, magnesite, dolomite and aragonite. Physics and Chemistry of Minerals, 20, 1-18. (Pubitemid 23393542)
20. Gunasekaran, S., Anbalagan, G., and Pandi, S. (2006) Raman and infrared spectra of carbonates of calcite structure. Journal of Raman Spectroscopy, 37, 892-899.
21. Isshiki, M., Irifune, T., Hirose, K., Ono, S., Ohishi, Y., Watanuki, T., Nishibori, E., Takata, M., and Sakata, M. (2004) Stability of magnesite and its high-pressure form in the lowermost mantle. Nature, 427, 60-63. (Pubitemid 38094819)
22. Javoy, M. (1997) The major volatile elements of the Earth: Their origin, behaviour, and fate. Geophysical Research Letters, 24, 177-180.
23. Kaabar, W., Botta, S., and Devonshire, R. (2011) Raman spectroscopic study of mixed carbonate materials. Spectrochimica Acta Part A, 78, 136-141.
24. 3 system at high-pressures: Implications to evolution of the Earth's atmosphere. Earth and Planetary Science Letters, 99, 110-117.
25. Kaminsky, F.V. and Wirth, R. (2011) Iron carbide inclusions in lower-mantle diamond from Juina, Brazil. The Canadian Mineralogist, 49, 555-572.
26. Komabayashi, T., Hirose, K., Nagaya, Y., Sugimura, E., and Ohishi, Y. (2010) High temperature compression of ferropericlase and the effect of temperature on iron spin transition. Earth and Planetary Science Letters, 297, 691-699.
27. Lavina, B., Dera, P., Downs, R.T., Prakapenka, V., Rivers, M., Sutton, S., and Nicol, M. (2009) Siderite at lower mantle conditions and the effects of the pressure-induced spin-pairing transition. Geophysical Research Letters, 36, L23306.
28. 3 to 56 GPa and hysteresis of its spin-pairing transition. Physical Review B, 82, 064110.
29. Lavina, B., Dera, P., Downs, R.T., Tschauner, O.T., Yang, W., Shebanova, O., and Shen, G. (2010b) Effect of dilution on the spin pairing transition in rhombohedral carbonates. High Pressure Research, 30, 224-229.
30. Li, L. and Fei, Y. (2003) Experimental constraints on core composition. In R.W. Carlson, Ed., The Mantle and Core, 2nd edition, Volume 2, p. 521-546. Treatise on Geochemistry, Elsevier, Amsterdam.
31. Lin, J.F., Struzhkin, V., Jacobsen, S.D., Hu, M., Chow, P., Kung, J., Liu, H., Mao, H.K., and Hemley, R.J. (2005) Spin transition of iron in magnesiowüstite in Earth's lower mantle. Nature, 436, 377-380. (Pubitemid 41059045)
32. Lin, J.F., Gavriliuk, A.G., Struzhkin, V.V., Jacobsen, S.D., Sturhahn, W., Hu, M.Y., Chow, P., and Yoo, C.S. (2006) Pressure-induced electronic spin transition of iron in magnesiowüstite-(Mg,Fe)O. Physical Review B, 73, 113107.
33. Lin, J.F., Weir, S.T., Jackson, D.D., Evans, W.J., and Yoo, C.S. (2007) Electrical conductivity of the low-spin ferropericlase in the Earth's lower mantle. Geophysical Research Letters, 34, L16305, 2007.
34. Lin, J.F. and Tsuchiya, T. (2008) Spin transition of iron in the Earth's lower mantle. Physics of the Earth and Planetary Interiors, 170, 248-259.
35. Lin, J.F., Wenk, H.R., Voltolini, M., Speziale, S., Shu, J., and Duffy, T.S. (2009) Deformation of lower-mantle ferropericlase (Mg,Fe)O across the electric spin transition. Physics and Chemistry of Minerals, 36, 585-592.
36. Litasov, K.D., Fei, Y., Ohtani, E., Kuribayashi, T., and Funakoshi, K. (2008) Thermal equation of state of magnesite to 32 GPa and 2073 K. Physics of the Earth and Planetary Interiors, 168, 191-203.
37. 3: Linear incompressibility of lattice parameters and high-pressure transformations. Physics and Chemistry of Minerals, 30, 582-588. (Pubitemid 37471053)
38. Mao, H.K., Bell, P.M., Shaner, J.W., and Steinberg, D.J. (1978) Specific volume measurements of Cu, Mo, Pd, and Ag and calibration of the ruby R1 fluorescence pressure gauge from 0.06 to 1 Mbar. Journal of Applied Physics, 49, 3276-3283. (Pubitemid 8620372)
39. Marquardt, H., Speziale, S., Reichmann, H.J., Frost, D.J., Schilling, F.R., and Garnero, E.J. (2009) Elastic shear anisotropy of ferropericlase in Earth's lower mantle. Science, 324, 224-226.
40. 3 studied by X-ray emission spectroscopy. Journal of Physics: Condensed Matter, 19, 386206.
41. McDonough, W.F. and Sun, S.-s. (1995) The composition of the Earth. Chemical Geology, 120, 223-253.
42. Meade, C. and Jeanloz, R. (1990) Static compression of Ca(OH)2 at room temperature: Observations of amorphization and equation of state measurements to 10.7 GPa. Geophysical Research Letters, 17, 1157-1160.
43. 3-siderite studied by X-ray diffraction measurements. Journal of Physics: Conference Series, 215, 012002.
44. 2 and their role in Earth's lower mantle. Earth and Planetary Science Letters, 273, 38-47.
45. Pal'yanov, Y.N., Sokol, A.G., Borzdov, Y.M., Khokhryakov, A.F., and Sobolev, N.V. (1999) Diamond formation from mantle carbonate fluids. Nature, 400, 417-418. (Pubitemid 29361787)
46. Rividi, N., van Zuilen, M., Philippot, P., Menez, B., Godard, G., and Poidatz, E. (2010) Calibration of carbonate composition using micro-Raman analysis: Application to planetary surface exploration. Astrobiology, 10, 293-309.
47. 3) between 5 and 600 K. American Mineralogist, 69, 349-357.
48. Rohrbach, A. and Schmidt, M.W. (2011) Redox freezing and melting in the Earth's deep mantle resulting from carbon-iron redox coupling. Nature, 472, 209-212.
49. Rutt, H.N. and Nicola, J.H. (1974) Raman spectra of carbonates of calcite structure. Journal of Physics C: Solid State Physics, 7, 4522-4528.
50. 3)2-dolomite. Physics of the Earth and Planetary Interiors, 143-144, 291-304. (Pubitemid 38653438)
51. Santillan, J., Catalli, K., and Williams, Q. (2005) An infrared study of carbon-oxygen bonding in magnesite to 60 GPa. American Mineralogist, 90, 1669-1673. (Pubitemid 41555959)
52. Seto, Y., Hamane, D., Nagai, T., and Fujino, F. (2008) Fate of carbonates within oceanic plates subducted to the lower mantle, and a possible mechanism of diamond formation. Physics and Chemistry of Minerals, 35, 223-229.
53. Shannon, R.D. and Prewitt, C.T. (1969) Effective ionic radii in oxides and fluorides. Acta Crystallography, B25, 925-945.
54. Shcheka, S., Wiedenbeck, M., Frost, D., and Keppler, H. (2006) Carbon solubility in mantle minerals. Earth and Planetary Science Letters, 245, 730-742. (Pubitemid 44255095)
55. 3. Physical Review B, 78, 155119.
56. Speziale, S., Milner, A., Lee, V.E., Clark, S.M., Pasternak, M., and Jeanloz, R. (2005) Iron spin transition in Earth's mantle. Proceedings of the National Academy of Sciences, 102, 17918-17922. (Pubitemid 41798477)
57. Speziale, S., Lee, V.E., Clark, S.M., Lin, J.F., Pasternak, M.P., and Jeanloz, R. (2007) Effects of Fe spin transition on the elasticity of (Mg,Fe)O magnesiowüstites and implications for the seismological properties of the Earth's lower mantle. Journal of Geophysical Research, 112, B10212.
58. Stachel, T., Harris, J.W., Brey, G.P., and Joswig, W. (2000) Kankan diamonds (Guinea) II: Lower mantle inclusion parageneses. Contributions to Mineralogy and Petrology, 140, 16-27.
59. Stagno, V. and Frost, D.J. (2010) Carbon speciation in the asthenosphere: Experimental measurements of the redox conditions at, which carbonate-bearing melts coexist with graphite or diamond in peridotite assemblages. Earth and Planetary Science Letters, 300, 72-84.
60. Wagner, J.-M. (2000) On the inadequacy of linear pressure dependence of vibrational frequency. Solid State Communications, 116, 355-356.
61. Wells, A.F. (1984) Structural Inorganic Chemistry, 5th edition, 1382 p. Clarendon, Oxford, U.K.
62. Wentzcovitch, R.M., Justo, J.F., Wu, Z., da Silva, C.R.S., Yuen, D.A., and Kohlstedt, D. (2009) Anomalous compressibility of ferropericlase throughout the iron spin cross-over. Proceedings of the National Academy of Sciences, 106, 8447-8452.
63. White, W.B. (1974) Order-disorder effects. In V.C. Farmer, Ed., Infrared Spectra of Minerals, p. 87-110. Mineralogical Society Monograph 4, London.
64. 2+ substitution in calcite-structure carbonates: Thermoelastic properties. American Mineralogist, 83, 280-287.