Monoatomically dispersed Pd/TiO 2 catalyst effective for epoxidation of propylene at ambient temperature in the presence of H 2 and O 2

Journal of Molecular Catalysis A: Chemical

Volumn 358, Issue , 2012, Pages 89-98

  Hikazudani, Susumu ^a   Mochida, Tatsuya ^b   Matsuo, Naofumi ^b   Nagaoka, Katsutoshi ^b   Ishihara, Tatsumi ^c   Kobayashi, Hisayoshi ^d   Takita, Yusaku ^b  

^a HITACHI ZOSEN CORPORATION   (Japan)

^b OITA UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

^d KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Monoatomically supported Pd; Oxidation in the presence of H 2; Pd TiO 2; Propylene epoxidation; Reaction mechanism

Indexed keywords

CHLORIDE COMPLEXES; EPOXIDATION OF PROPYLENE; FORMATION MECHANISM; ISOBUTANES; ISOTOPE EXCHANGE; LOW RATES; LOW SURFACE CONCENTRATIONS; PRODUCT DISTRIBUTIONS; PROPYLENE EPOXIDATION; PROPYLENE OXIDE; REACTION MECHANISM; SUPPORTED PD; SURFACE AREA; SURFACE CONCENTRATION; TIO;

BUTANE; BUTENES; CATALYST ACTIVITY; CHLORINE COMPOUNDS; ISOTOPES; PALLADIUM COMPOUNDS; PRECIOUS METALS; PROPANE; TEMPERATURE; TITANIUM DIOXIDE;

PROPYLENE;

EID: 84860275441     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2012.03.001     Document Type: Article

References (32)

1. S.B. Cavitt, USP 4,102,820 (1975).
2. M. McCoy Chem. Eng. News 2001 19
3. Z. Song, N. Mimura, J.J. Bravo-Suárez, T. Akita, S. Tsubota, and S.T. Oyama Appl. Catal. A: Gen. 316 2007 142 151
4. Y. Liu, K. Murata, M. Inaba, and N. Mimura Appl. Catal. A: Gen. 309 2006 91 105
5. A. Takahashi, N. Hamakawa, I. Nakamura, and T. Fujitani Appl. Catal. A: Gen. 294 2005 34 39
6. T. Miyaji, P. Wu, and T. Tatsumi Catal. Today 71 2001 169 176
7. Q. Zhang, Q. Guo, X. Wang, T. Shishido, and Y. Wang J. Catal. 239 2006 105 116
8. B. Moens, H. De Winne, S. Corthals, H. Poelman, R. De Gryse, V. Meynen, P. Cool, B.F. Sels, and P.A. Jacobs J. Catal. 247 2007 86 100 N2O
9. V.N. Parmon, G.I. Panov, A. Uriarte, and A.S. Noskov Catal. Today 100 2005 115 131 N2O
10. V. Arca, A.B. Boscoletto, N. Fracasso, L. Meda, and G. Ranghino J. Mol. Catal. A: Chem. 243 2006 264 277
11. L.Y. Chen, G.K. Chuah, and S. Jaenicke J. Mol. Catal. A: Chem. 132 1998 281 292
12. J. Kaur, and I.V. Kozhevnikov Catal. Commun. 5 2004 709 713
13. P. Wu, and T. Tatsumi J. Phys. Chem. B 106 4 2002 748 753
14. T. Tatsumi, P. Peng Wu, and W. Weibin Fan Stud. Surf. Sci. Catal. 170 2007 1051 1058
15. D.H. Wells Jr., W.N. Delgass, and K.T. Thomson J. Catal. 225 2004 69 77
16. T. Honma, M. Nakajo, T. Mizugaki, K. Ebitani, and K. Kaneda Tetrahedron Lett. 43 2002 6229 6232
17. T. Hayashi, K. Tanaka, and M. Haruta J. Catal. 178 1998 566 575
18. M. Haruta, B.S. Uphade, S. Tsubota, and A. Miyamoto Res. Chem. Intermed. 24 1998 329 336
19. M. Haruta, and M. Daté Appl. Catal. A: Gen. 222 2001 427 437
20. A.K. Sinha, T. Akita, S. Tsubota, and M. Haruta Stud. Surf. Sci. Catal. 142 2002 611 618
21. B.S. Uphade, Y. Yamada, T. Akita, T. Nakamura, and M. Haruta Appl. Catal. A: Gen. 215 2001 137 148
22. C. Qi, T. Akita, M. Okumura, and M. Haruta Appl. Catal. A: Gen. 218 2001 81 89
23. C. Qi, T. Akita, M. Okumura, K. Kuraoka, and M. Haruta Appl. Catal. A: Gen. 253 2003 75 89
24. C. Qi, M. Okumura, T. Akita, and M. Haruta Appl. Catal. A: Gen. 263 2004 19 26
25. N. Yap, R.P. Andres, and W.N. Delgass J. Catal. 226 2004 156 170
26. B. Taylor, J. Lauterbach, and W.N. Delgass Catal. Today 123 2007 50 58
27. B. Taylor, J. Lauterbach, G.E. Blau, and W.N. Delgass J. Catal. 242 2006 142 152
28. B. Taylor, J. Lauterbach, and W.N. Delgass Appl. Catal. A: Gen. 291 2005 188 198
29. S.T. Oyama, X. Zhang, J. Lu, Y. Gu, and T. Fujitani J. Catal. 257 2008 1 4
30. Y. Takita, S. Yoshida, K. Usami, T. Sato, Y. Obana, M. Ito, M. Ogura, H. Nishiguchi, and T. Ishihara Appl. Catal. A: Gen. 225 2002 215 221
31. S. Hikazudani, T. Mochida, K. Yano, K. Nagaoka, T. Ishihara, and Y. Takita Catal. Commun. 12 2011 1396 1400
32. C. Sivadinarayana, T.V. Choudhary, L.L. Daemen, J. Eckert, and D.W. Goodman J. Am. Chem. Soc. 126 2004 38 39