Carbon nanotubes coated on silica gels as a support of Cu-Co catalyst for the synthesis of higher alcohols from syngas

Industrial and Engineering Chemistry Research

Volumn 50, Issue 19, 2011, Pages 11067-11072

  Feng, Wei ^a   Wang, Qingwei ^a   Jiang, Biao ^a   Ji, Peijun ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

HIGHER ALCOHOLS; METHANOL SELECTIVITY; SYN-GAS;

ETHANOL; METHANOL; MULTIWALLED CARBON NANOTUBES (MWCN); SILICA GEL; SYNTHESIS GAS;

CATALYST SELECTIVITY;

EID: 84860112689     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie2014907     Document Type: Article

References (34)

1. Subramani, V.; Gangwal, S. K. A Review of Recent Literature to Search for an Efficient Catalytic Process for the Conversion of Syngas to Ethanol. Energy Fuels 2008, 22, 814.
2. Spivey, J. J.; Egbebi, A. Heterogeneous Catalytic Synthesis of Ethanol from Biomass-Derived Syngas. Chem. Soc. Rev. 2007, 36, 1514.
3. Zhang, Y.; Sun, Y.; Zhong, B. Synthesis of Higher Alcohols from Syngas over Ultrafine Mo-Co-K Catalysts. Catal. Lett. 2010, 76, 3.
4. Xu, R.; Wei, W.; Li, W. H.; Hu, T. D.; Sun, Y. H. Fe Modified CuMnZrO2 Catalysts for Higher Alcohols Synthesis from Syngas: Effect of Calcination Temperature. J. Mol. Catal. A: Chem. 2005, 234, 75.
5. Dong, X.; Liang, X. L.; Li, H. Y.; Lin, G. D.; Zhang, P.; Zhang, H. B. Preparation and Characterization of Carbon Nanotube-Promoted Co-Cu Catalyst for Higher Alcohol Synthesis from Syngas. Catal. Today 2009, 147, 158.
6. Wu, X, M.; Guo, Y. Y.; Zhou, J. M.; Lin, G. D.; Dong, X.; Zhang, H. B. Co Decorated Carbon Nanotubes as a Promoter of Co-Mo-K Oxide Catalyst for Synthesis of Higher Alcohols from Syngas. Appl. Catal., A 2008, 340, 87.
7. Surisetty, V. R.; Dalai, A. K.; Kozinski, J. Effect of Rh Promoter on MWCNT Supported Alkali Modified Mos2 Catalysts for Higher Alcohols Synthesis from CO Hydrogenation. Appl. Catal., A 2010, 381, 282.
8. Thao, N. T.; Zahedi-Niaki, M. H.; Alamdari, H.; Kaliaguine, S. Effect of Alkali Additives over Nanocrystalline Co-Cu-Based Perovskites as Catalysts for Higher Alcohol Synthesis. J. Catal. 2007, 245, 348.
9. Subramanian, N. D.; Balaji, G.; Kumar, C. S.S.R.; Spivey, J. J. Development of Cobalt-Copper Nanoparticles as Catalysts for Higher Alcohol Synthesis from Syngas. Catal. Today 2009, 147, 100.
10. Xiang, M.; Li, D.; Li, W.; Zhong, B.; Sun, Y. Synthesis of Higher Alcohols from Syngas over K/Co/B-Mo2C Catalysts. Catal. Commun. 2007, 8, 503.
11. Xiang, M.; Li, D.; Xiao, H.; Zhang, J.; Qi, H.; Li, W.; Zhong, B.; Sun, Y. Synthesis of Higher Alcohols from Syngas over Fischer-Tropsch Elements Modified K/B-Mo2C Catalysts. Fuel 2008, 87, 599.
12. Fan, Z.; Chen, W.; Pan, X.; Bao, X. Catalytic Conversion of Syngas into C2 Oxygenates over Rh-Based Catalysts-Effect of Carbon Supports. Catal. Today 2009, 147, 86.
13. Ma, C. H.; Li, H. Y.; Lin, G. D.; Zhang, H. B. Ni Decorated Carbon Nanotube-Promoted Ni-Mo-K Catalyst for Highly Efficient Synthesis of Higher Alcohols from Syngas. Appl. Catal., B 2010, 100, 245.
14. Liu, J.; Rinzler, A. G.; Dai, H.; Hafner, J. H.; Bradley, R. K.; Boul, P. J.; Lu, A.; Iverson, T.; Shelimov, K.; Huffman, C. B.; Rodriguez-Macias, F.; Shon, Y. S.; Lee, T. R.; Colbert, D. T.; Smalley, R. E. Fullerene Pipes. Science 1998, 280, 1253.
15. Sano, M.; Kamino, A.; Okamura, J.; Shinkai, S. Noncovalent Self-Assembly of Carbon Nanotubes for Construction of Cages. Nano Lett. 2002, 2, 531.
16. Huang, X, J.; Ryu, S. W.; Im, H. S. Wet Chemical Needlelike Assemblies of Single-Walled Carbon Nanotubes on a Silicon Surface. Langmuir 2007, 23, 991.
17. Balasubramanian, K.; Burghard, M. Electrochemically Functionalized Carbon Nanotubes for Device Applications. J. Mater. Chem. 2008, 18, 3071.
18. Mawhinney, D. B.; Naumenko, V.; Kuznetsova, A.; Yates, J. T., Jr.; Liu, J.; Smalley, R. E. Infrared Spectral Evidence for the Etching of Carbon Nanotubes: Ozone Oxidation at 298 K. J. Am. Chem. Soc. 2000, 122, 2383.
19. Kovtyukhova, N. I.; Mallouk, T. E.; Pan, L.; Dickey, E. C. Individual Single-Walled Nanotubes and Hydrogels Made by Oxidative Exfoliation of Carbon Nanotube Ropes. J. Am. Chem. Soc. 2003, 125, 9761.
20. Eswaramoorthi, I.; Sundaramurthy, V.; Das, N.; Dalai, A. K.; Adjaye, J. Application of Multi-Walled Carbon Nanotubes as Efficient Support to Nimo Hydrotreating Catalyst. Appl. Catal., A 2008, 339, 187.
21. 2. Appl. Catal., A 1998, 172, 217.
22. Unger, E.; Duesberg, G. S.; Liebau, M.; Graham, A. P.; Seidel, R.; Kreupl, F.; Hoenlein, W. Decoration of Multi-Walled Carbon Nanotubes with Noble and Transition Metal Clusters and Formation of CNT-CNT Networks. Appl. Phys. A: Mater. Sci. Process. 2003, 77, 735.
23. Ernst, B.; Bensaddik, A.; Hilaire, L.; Chaumette, P.; Kiennemann, A. Study on a Cobalt Silica Catalyst during Reduction and Fischer-Tropsch Reaction: In Situ EXAFS Compared to XPS and XRD. Catal. Today 1998, 39, 329.
24. Janas, J.; Machej, T.; Gurgul, J.; Socha, R. P.; Che, M.; Dzwigaj, S. Effect of Co Content on the Catalytic Activity of Cosibea Zeolite in the Selective Catalytic Reduction of NO with Ethanol: Nature of the Cobalt Species. Appl. Catal., B: Environ. 2007, 75, 239.
25. Ikonomov, J.; Stoychev, D.; Marinova, T. S. XPS and SEM Characterization of Electrodeposited Transition Metals on Zirconia. Appl. Surf. Sci. 2000, 161, 94.
26. Contarin, S.; Kevan, L. X-ray Photoelectron Spectroscopic Study of Copper-Exchanged X- and Y-Type Sodium Zeolites: Resolution of Two Cupric Ion Components and Dependence on Dehydration and X-Irradiation. J. Phys. Chem. 1986, 90, 1630.
27. Janas, J.; Gurgul, J.; Socha, R. P.; Dzwigaj, S. Effect of Cu Content on the Catalytic Activity of Cusibea Zeolite in the SCR of NO by Ethanol: Nature of the Copper Species. Appl. Catal., B: Environ. 2009, 91, 217.
28. Pyrzynska, K.; Bystrzejewski, M. Comparative Study of Heavy Metal Ions Sorption onto Activated Carbon,Carbon Nanotubes, and Carbon-Encapsulated Magnetic Nanoparticles. Colloids Surf., A 2010, 362, 102.
29. Lin, D.; Xing, B. Adsorption of Phenolic Compounds by Carbon Nanotubes: Role of Aromaticity and Substitution of Hydroxyl Groups. Environ. Sci. Technol. 2008, 42, 7254.
30. Cletus White, S. M.; Bard, A. J. Polarography of Metal Pyrogallol Complexes. Anal. Chem. 1996, 38, 61.
31. Mitic, S. S.; Miletic, G. Z.; Obradovic, M. V. Catalytic Determination of Nanogram Amount from Iron (III) Using its Catalytic Effect on the Oxidation of Sodium Pyrogallol-5-Sulphonate by Hydrogenperoxide. Talanta 1995, 42, 1273.
32. Safavi, A.; Shams, E. Determination of Trace Amounts of Copper (II) by Adsorptive Stripping Voltammetry of its Complex with Pyrogallol Red. Anal. Chim. Acta 1999, 385, 265.
33. Courty, P.; Durand, D.; Freund, E.; Surgier, A. Production of a Mixture of Alcohols from Synthesis Gas. UK Patent 2118061, 1983.
34. Courty, P.; Durand, D.; Surgier, A.; Freund, R. Process for Manufacturing a Mixture of Methanol and Higher Alcohols from Synthesis Gas. U.S. Patent 4659742, 1987.