Carboxylation of toluene by CO 2 generating p-toluic acid: A kinetic look

Industrial and Engineering Chemistry Research

Volumn 51, Issue 14, 2012, Pages 5174-5180

  Sarve, Antaram N ^b   Ganeshpure, Pralhad A ^a   Munshi, Pradip ^a  

^a RELIANCE INDUSTRIES LIMITED   (India)

^b SARDAR VALLABHBHAI NATIONAL INSTITUTE OF TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS CONSTANTS; FIRST ORDER KINETICS; FT-IR SPECTRUM; K-VALUES; KINETIC STUDY; ORDER OF REACTION; RATE LAWS;

ALUMINUM; CARBOXYLATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FRIEDEL-CRAFTS REACTION; KINETICS; RATE CONSTANTS; STOICHIOMETRY; TOLUENE;

CARBON DIOXIDE;

EID: 84859622469     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie300014z     Document Type: Article

References (20)

1. Aresta, M. Carbon Dioxide Recovery and Utilization; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2003.
2. Sakakura, T.; Choi, J. C.; Yasuda, H. Transformation of Carbon Dioxide Chem. Rev. 2007, 107, 2365-2387 (Pubitemid 47029097)
3. 2 as a Chemical Feedstock: Opportunities and Challenges Dalton Trans. 2007, 2975-2992 (Pubitemid 47152307)
4. Simonetta, M.; Carra, S. In The Chemistry of Functional Groups: The Chemistry of Carboxylic Acids and Esters; Patai, S., Ed.; Wiley: Chichester, U.K., 1969; Chapter 1, p 1.
5. Ogliaruso, M.; Wolfe, J. F. The Chemistry of Functional Groups: Synthesis of Carboxylic Acids and Their Derivatives; Patai, S.; Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1991; p 1.
6. Raghavendrachar, P.; Ramachandran, S. Liquid-phase Catalytic Oxidation of p -Xylene Ind. Eng. Chem. Res. 1992, 31, 453-462
7. Ullmann's Encyclopedia of Industrial Chemistry, 5 th ed.; Gerhartz, W.; Yamamoto, Y. S.; Campbell, F. T.; Pferfferkorn, R.; Rounsaville, J. F., Eds.; VCH Publishers: Weinheim, Germany, 1985.
8. Friedel, C.; Crafts, J. M. Fixation directe de l'acide Carbonique, de l'acide Sulfureux, de I'anhydride Phtalique sur la Benzine; Synthese de l'acide Benzoique, de l'hydrure de Sulfophenyle et de l'acide Benzoylbenzoique Compt. Rend. 1878, 86, 1368-1371
9. Friedel, C.; Crafts, J. M. Sur une Nouvelle Methode Generate de Synthese des Combinaisons Aromatiques Ann. Chim. Phys. 1883, 14, 433-472
10. 3 and Al or Zn. U.S. Patent 3,138,626, 1964.
11. 6/Al system J. Am. Chem. Soc. 2002, 124, 11379-11391
12. 2 Ind. Eng. Chem. Res. 2009, 48, 1059-1062
13. Beckman, E. J.; Munshi, P. Carboxylation of Aromatic Hydrocarbon to Produce Aromatic Carboxylic Acids. U.S. Patent 7,271,286, 2007.
14. 2 Ind. Eng. Chem. Res. 2010, 49, 6678-6682
15. Connors, K. A. Chemical Kinetics: The Study of Reaction Rate in Solution; VCH Publishers: New York, 1991.
16. Atkins, P. W. Physical Chemistry, 7 th ed.; Oxford University Press: Oxford, U.K., 2002.
17. Miller, C. D.; Lial, M. L.; Schneider, D. I. Fundamentals of College Algebra, 3 rd ed.; Scott & Foresman/Little & Brown Higher Education: Glenview, IL, 1990.
18. 3SiCl J. Org. Chem. 2010, 75, 7855-7862
19. Eyring, H. The Activated Complex in Chemical Reactions J. Chem. Phys. 1935, 3, 107-115
20. 3OH Mixture and The Order of Reaction Int. J. ChemTech Res. 2011, 3, 975-980