Coordination structures and supramolecular architectures in a cerium(III)-malonamide solvent extraction system

Langmuir

Volumn 28, Issue 14, 2012, Pages 5987-5998

  Ellis, Ross J ^a   Antonio, Mark R ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADVANCED ANALYSIS; AGGREGATION PHENOMENA; AQUEOUS MEDIA; COORDINATION CHEMISTRY; COORDINATION ENVIRONMENT; COORDINATION STRUCTURES; FOURIER TRANSFORM METHOD; LIQUID-LIQUID EXTRACTION; MALONAMIDES; METAL EXTRACTIONS; MICELLAR ASSEMBLIES; N-DODECANE; ORGANIC PHASIS; PROCESS CHEMISTRY; PROCESS PROPERTIES; REAL-SPACE; REVERSE MICELLES; SEPARATION SCIENCE; SMALL ANGLE X-RAY SCATTERING; SOFT MATTER; SOLUTION STRUCTURES; SOLVENT EXTRACTION SYSTEM; STRUCTURED FLUIDS; SUPRAMOLECULAR ARCHITECTURES; SUPRAMOLECULAR STRUCTURE; THIRD PHASE; TRANSITION PHENOMENON; TRIVALENT CERIUM;

ARCHITECTURE; CERIUM; COAGULATION; COORDINATION REACTIONS; HYDRATES; MICELLES; PHASE TRANSITIONS; SOLVENTS;

SOLVENT EXTRACTION;

EID: 84859609437     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3002916     Document Type: Article

References (83)

1. Bernardis, F. L.; Grant, R. A.; Sherrington, D. C. A review of methods of separation of the platinum-group metals through their chloro-complexes React. Funct. Polym. 2005, 65, 205-217
2. Bautista, R. G. Separation chemistry. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr.; Eyring, L., Eds.; North-Holland: Amsterdam, 1995; Vol. 21; pp 1-27.
3. Handbook of Extractive Metallurgy; Habashi, F., Ed.; Wiley: New York, 1997, 2500 pp.
4. Musikas, C.; Schulz, W. W.; Liljenzin, J.-O. Solvent extraction in nuclear science and technology. In Solvent Extraction Principles and Practice; 2 nd ed.; Rydberg, J., Ed.; Marcel Dekker, Inc.: New York, 2004; pp 507-557.
5. Cuillerdier, C.; Musikas, C.; Hoel, P. New extractants for the treatment of nuclear waste solutions Inst. Chem. Eng. Symp. Ser. 1990, 119, 47-59
6. Musikas, C.; Hoel, P.; Thiollet, G.; Lafosse, L. Method for the recovery of actinides and/or lanthanides using novel extraction agents, and novel propanediamides, and the preparation thereof. U.S. Patent 4938871, 1990.
7. Musikas, C.; Morisseau, J. C.; Hoel, P.; Guillaume, B. Actinide extractants for the nuclear industry of the future Inst. Chem. Eng. Symp. Ser. 1987, 103, 51-65
8. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallogr., Sect. A 1976, A32, 751-67
9. Musikas, C.; Hubert, H. Extraction by N, N'-tetraalkylmalonamides. II. Extraction of metallic ions Solvent Extr. Ion Exch. 1987, 5, 877-93
10. Tasker, P. A.; Plieger, P. G.; West, L. C. Metal complexes for hydrometallurgy and extraction. In Comprehensive Coordination Chemistry II; Ward, M. D., Ed.; Elsevier Ltd.: New York, 2004; Vol. 9; pp 759-808.
11. Charbonnel, M. C.; Flandin, J. L.; Giroux, S.; Presson, M. T.; Madic, C.; Morel, J. P. Extraction of Ln(III) and Am(III) from nitrate media by malonamides and polydentate N-bearing ligands. In Proceedings of the International Solvent Extraction Conference; Sole, K. C.; Cole, P. M.; Preston, J. S.; Robinson, D. J., Eds.; South African Institute of Mining and Metallurgy: Marshalltown, South Africa, 2002; Vol. 2; pp 1154-1160.
12. Osseo-Asare, K. Aggregation, reversed micelles, and microemulsions in liquid-liquid extraction: The tri- n -butyl phosphate-diluent-water-electrolyte system Adv. Colloid Interface Sci. 1991, 37, 123-73
13. Erlinger, C.; Belloni, L.; Zemb, T.; Madic, C. Attractive interactions between reverse aggregates and phase separation in concentrated malonamide extractant solutions Langmuir 1999, 15, 2290-2300
14. Erlinger, C.; Gazeau, D.; Zemb, T.; Madic, C.; Lefrancois, L.; Hebrant, M.; Tondre, C. Effect of nitric acid extraction on phase behavior, microstructure and interactions between primary aggregates in the system dimethyldibutyltetradecylmalonamide (DMDBTDMA)/ n -dodecane/water: A phase analysis and small angle X-ray scattering (SAXS) characterization study Solvent Extr. Ion Exch. 1998, 16, 707-738
15. Chiarizia, R.; Briand, A.; Jensen, M. P.; Thiyagarajan, P. SANS study of reverse micelles formed upon the extraction of inorganic acids by TBP in n -octane Solvent Extr. Ion Exch. 2008, 26, 333-359
16. 3-TBP, n -dodecane system Solvent Extr. Ion Exch. 2003, 21, 1-27
17. 3, TBP- n -octane system with Baxter's "sticky spheres" model Solvent Extr. Ion Exch. 2004, 22, 325-351
18. Chiarizia, R.; Jensen, M. P.; Rickert, P. G.; Kolarik, Z.; Borkowski, M.; Thiyagarajan, P. Extraction of zirconium nitrate by TBP in n -octane: Influence of cation type on third phase formation according to the "sticky spheres" model Langmuir 2004, 20, 10798-10808
19. 3, TBP- n -dodecane system Langmuir 2003, 19, 9592-9599
20. Chiarizia, R.; Stepinski, D.; Antonio, M. R. SANS study of HCl extraction by selected neutral organophosphorus compounds in n -octane Sep. Sci. Technol. 2010, 45, 1668-1678
21. Chiarizia, R.; Thiyagarajan, P.; Jensen, M. P.; Borkowski, M.; Littrell, K. C. Third phase formation in TBP solvent extraction systems as a result of interaction between reverse micelles. In Hydrometallurgy 2003, 5th Proceedings of the International Symposium honoring Professor Ian M. Ritchie, Vancouver, BC, Canada, Aug. 24-27, 2003; Young, C., Ed.; Minerals, Metals & Materials Society: Warrendale, PA, 2003; Vol. 1; pp 917-928.
22. Baxter, R. J. Percus-Yevick equation of hard spheres with surface adhesion J. Chem. Phys. 1968, 49, 2770-4
23. Menon, S. V. G.; Kelkar, V. K.; Manohar, C. Application of Baxter's model to the theory of cloud points of nonionic surfactant solutions Phys. Rev. A 1991, 43, 1130-3
24. Plaue, J.; Gelis, A.; Czerwinski, K. Actinide third phase formation in 1.1 M TBP/nitric acid/alkane diluent systems Sep. Sci. Technol. 2006, 41, 2065-2074
25. Nave, S.; Mandin, C.; Martinet, L.; Berthon, L.; Testard, F.; Madic, C.; Zemb, T. Supramolecular organisation of tri- n -butyl phosphate in organic diluent on approaching third phase transition Phys. Chem. Chem. Phys. 2004, 6, 799-808
26. Nave, S.; Modolo, G.; Madic, C.; Testard, F. Aggregation properties of N, N, N', N'-tetraoctyl-3-oxapentanediamide (TODGA) in n -dodecane Solvent Extr. Ion Exch. 2004, 22, 527-551
27. Antonio, M. R.; Chiarizia, R.; Gannaz, B.; Berthon, L.; Zorz, N.; Hill, C.; Cote, G. Aggregation in solvent extraction systems containing a malonamide, a dialkylphosphoric acid and their mixtures Sep. Sci. Technol. 2008, 43, 2572-2605
28. Hiemenz, P. C.; Rajagopalan, R. Principles of Colloid and Surface Chemistry, Third Edition, Revised and Expanded; Marcel Dekker: New York, 1997.
29. Sharma, S. C.; Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. Viscoelastic wormlike micelles in mixed nonionic fluorocarbon surfactants and structural transition induced by oils J. Phys. Chem. B 2009, 113, 1615-1622
30. Shrestha, L. K.; Shrestha, R. G.; Aramaki, K. Intrinsic parameters for the structure control of nonionic reverse micelles in styrene: SAXS and rheometry studies Langmuir 2011, 27, 5862-5873
31. Shrestha, L. K.; Yamamoto, M.; Arima, S.; Aramaki, K. Charge-free reverse wormlike micelles in nonaqueous media Langmuir 2011, 27, 2340-2348
32. Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. Rheology of wormlike micelles in aqueous systems of a mixed amino acid-based anionic surfactant and cationic surfactant Colloid Polym. Sci. 2009, 287, 1305-1315
33. Shrestha, L. K.; Sato, T.-A.; Shrestha, R. G.; Hill, J.; Ariga, K.; Aramaki, K. Structure and rheology of reverse micelles in dipentaerythrityl tri-(12-hydroxystearate)/oil systems Phys. Chem. Chem. Phys. 2011, 13, 4911-4918
34. 5 mixtures and microemulsions with n -octane J. Chem. Phys. 1999, 110, 10623-10632
35. Fritz, G.; Bergmann, A.; Glatter, O. Evaluation of small-angle scattering data of charged particles using the generalized indirect Fourier transformation technique J. Chem. Phys. 2000, 113, 9733-9740
36. Glatter, O.; Fritz, G.; Lindner, H.; Brunner-Popela, J.; Mittelbach, R.; Strey, R.; Egelhaaf, S. U. Nonionic micelles near the critical point: Micellar growth and attractive interaction Langmuir 2000, 16, 8692-8701
37. George, G. N. In EXAFSPAK: A suite of computer programs for analysis of X-ray absorption spectra; SSRL: Stanford; http://www-ssrl.slac.stanford.edu/ exafspak.html.
38. Rehr, J. J.; Albers, R. C. Theoretical approaches to X-ray absorption fine structure Rev. Mod. Phys. 2000, 72, 621-654
39. Keiderling, U.; Gilles, R.; Wiedenmann, A. Application of silver behenate powder for wavelength calibration of a SANS instrument-A comprehensive study of experimental setup variations and data processing techniques J. Appl. Crystallogr. 1999, 32, 456-463
40. Guinier, A.; Fournet, G. Small-Angle Scattering of X-rays; John Wiley & Sons: New York, 1955.
41. Percus, J. K.; Yevick, G. J. Analysis of classical statistical mechanics by means of collective coordinates Phys. Rev. 1958, 110, 1-13
42. Shrestha, L. K.; Sato, T.; Dulle, M.; Glatter, O.; Aramaki, K. Effect of lipophilic tail architecture and solvent engineering on the structure of trehalose-based nonionic surfactant reverse micelles J. Phys. Chem. B 2010, 114, 12008-12017
43. Shrestha, L. K.; Shrestha, R. G.; Oyama, K.; Matsuzawa, M.; Aramaki, K. Structure of diglycerol polyisostearate nonionic surfactant micelles in nonpolar oil hexadecane: A SAXS study J. Oleo Sci. 2010, 59, 339-350
44. Campbell, A. N.; Debus, G. H.; Kartzmark, E. M. Conductances of aqueous lithium nitrate solutions at 25.0 and 110.0 °C Can. J. Chem. 1955, 33, 1508-14
45. Meridiano, Y.; Berthon, L.; Crozes, X.; Sorel, C.; Dannus, P.; Antonio, M. R.; Chiarizia, R.; Zemb, T. Aggregation in organic solutions of malonamides: Consequences for water extraction Solvent Extr. Ion Exch. 2009, 27, 607-637
46. Lefrancois, L.; Delpuech, J.-J.; Hebrant, M.; Chrisment, J.; Tondre, C. Aggregation and protonation phenomena in third phase formation: An NMR study of the quaternary malonamide/dodecane/nitric acid/water system J. Phys. Chem. B 2001, 105, 2551-2564
47. Ellis, R. J.; Antonio, M. R. Redox chemistry of third phases formed in the cerium/nitric acid/malonamide- n -dodecane solvent extraction system ChemPlusChem 2012, 77, 41-47
48. Ellis, R. J.; D'Amico, L.; Chiarizia, R.; Antonio, M. R. Solvent extraction of cerium(III) using an aliphatic malonamide: The role of acid in organic phase behaviors. Sep. Sci. Technol. 2012, in press.
49. Gannaz, B.; Antonio, M. R.; Chiarizia, R.; Hill, C.; Cote, G. Structural study of trivalent lanthanide and actinide complexes formed upon solvent extraction Dalton Trans. 2006, 4553-4562
50. 3-edge XANES spectroscopy Chem.-Eur. J. 2010, 16, 684-692
51. Persson, I.; D'Angelo, P.; De Panfilis, S.; Sandstrom, M.; Eriksson, L. Hydration of lanthanoid(III) ions in aqueous solution and crystalline hydrates studied by EXAFS spectroscopy and crystallography: The myth of the "gadolinium break" Chem.-Eur. J. 2008, 14, 3056-3066
52. Yaita, T.; Narita, H.; Suzuki, S.; Tachimori, S.; Motohashi, H.; Shiwaku, H. Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS J. Radioanal. Nucl. Chem. 1999, 239, 371-375
53. Antonio, M. R.; Soderholm, L. X-ray absorption spectroscopy of the actinides. In The Chemistry of the Actinide and Transactinide Elements; Morss, L. R.; Edelstein, N. M.; Fuger, J., Eds.; Springer: Dordrecht, 2006; Vol. 5; pp 3086-3198.
54. D'Angelo, P.; Zitolo, A.; Migliorati, V.; Chillemi, G.; Duvail, M.; Vitorge, P.; Abadie, S.; Spezia, R. Revised ionic radii of lanthanoid(III) ions in aqueous solution Inorg. Chem. 2011, 50, 4572-4579
55. Marcus, Y. Principles of solubility and solutions. In Solvent Extraction Principles and Practice, 2 nd ed.; Rydberg, J., Ed.; Marcel Dekker, Inc.: New York, 2004; pp 27-80.
56. Chatterjee, A.; Maslen, E. N.; Watson, K. J. The effect of the lanthanoid contraction on the nonaaqualanthanoid(III) tris(trifluoromethanesulfonates) Acta Crystallogr. Sect. B 1988, 44, 381-386
57. Dong, Y.-B.; Wang, P.; Ma, J.-P.; Zhao, X.-X.; Wang, H.-Y.; Tang, B.; Huang, R.-Q. Coordination-driven nanosized lanthanide "molecular lantern" with tunable luminescent properties J. Am. Chem. Soc. 2007, 129, 4872-4873
58. Faithfull, D. L.; Harrowfield, J. M.; Ogden, M. I.; Skelton, B. W.; Third, K.; White, A. H. Synthetic and structural studies in the lanthanide toluene-4-sulfonate hydrates Aust. J. Chem. 1992, 45, 583-594
59. 2O [M = La-Lu (except Pm)], at 171 K Acta Crystallogr Sect. C 1984, 40, 781-786
60. Trzesowska-Kruszynska, A.; Kruszynski, R.; Zalewicz, M.; Bartczak, T. J. Coordination sphere geometry changes of lanthanoid(III) nitrate complexes with hexamethylenetetramine J. Coord. Chem. 2010, 63, 1013-1028
61. Rapko, B. M.; McNamara, B. K.; Rogers, R. D.; Lumetta, G. J.; Hay, B. P. Coordination of lanthanide nitrates with N, N, N', N'-tetramethylsuccinamide Inorg. Chem. 1999, 38, 4585-4592
62. Dobler, M.; Guilbaud, P.; Dedieu, A.; Wipff, G. Interaction of trivalent lanthanide cations with nitrate anions: A quantum chemical investigation of monodentate/bidentate binding modes New J. Chem. 2001, 25, 1458-1465
63. Dahaoui-Gindrey, V.; Lecomte, C.; Barbette, F.; Pullumbi, P.; Gros, C. P.; Guilard, R.; Dahaoui, S. Confirmation by an X-ray crystallography study of a molecular modeling prediction about the coordination scheme of a new (1,4,8,11-(tetra-2-carboxyethyl)-1,4,8,11-tetraazacyclotetradecane)cerium(III) complex Z. Kristallogr. 2000, 215, 293-298
64. Li, L.; Jin, X.; Li, G.; Wang, Y.; Liao, F.; Yao, G.; Lin, J. Novel rare earth polyborates. 2. Syntheses and structures Chem. Mater. 2003, 15, 2253-2260
65. III derivative Inorg. Chem. 2011, 50, 5890-5898
66. Zucchi, G.; Maury, O.; Thuery, P.; Gumy, F.; Bunzli, J. C. G.; Ephritikhine, M. 2,2′-bipyrimidine as efficient sensitizer of the solid-state luminescence of lanthanide and uranyl ions from visible to near-infrared Chem.-Eur. J. 2009, 15, 9686-9696
67. Sun, Q.; Zheng, F.; Sun, X.; Wang, W. Bis{4-[(4 H -1,2,4-triazol-4-yl) iminomethyl]pyridinium} diaquapentanitratocerate(III) Acta Crystallogr., Sect. E 2009, 65, m124
68. Drew, M. G. B.; Hill, C.; Hudson, M. J.; Iveson, P. B.; Madic, C.; Youngs, T. G. A. Solvent extraction and lanthanide complexation studies with new terdentate ligands containing two 1,3,5-triazine moieties Dalton Trans. 2004, 244-251
69. 4 Solvent Extr. Ion Exch. 1994, 12, 261-96
70. Chatt, J.; Duncanson, L. A.; Gatehouse, B. M.; Lewis, J.; Nyholm, R. S.; Tobe, M. L.; Todd, P. F.; Venanzi, L. M. Infrared spectra and structure of some simple and bridged nitro complexes of platinum, palladium, and cobalt J. Chem. Soc. 1959, 4073-80
71. Curtis, N. F.; Hay, R. W.; Curtis, Y. M. Some complexes of dipropylenetriamine with nickel(II), copper(II), zinc(II) and cobalt(III) J. Chem. Soc. A 1968, 182-187
72. Gatehouse, B. M.; Livingstone, S. E.; Nyholm, R. S. Infrared spectra of some nitrato and other oxyanion coordination complexes J. Inorg. Nucl. Chem. 1958, 8, 75-8
73. Nelson, D. L.; Irish, D. E. Interactions in lanthanide systems. 2. Raman study of aqueous cerium(III) nitrate J. Chem. Soc., Faraday Trans. 1 1973, 69, 156-60
74. Ferraro, J. R.; Borkowski, M.; Chiarizia, R.; McAlister, D. R. FT-IR spectroscopy of nitric acid in TBP/octane solution Solvent Extr. Ion Exch. 2001, 19, 981-992
75. Berthon, L.; Martinet, L.; Testard, F.; Madic, C.; Zemb, T. Solvent penetration and sterical stabilization of reverse aggregates based on the DIAMEX process extracting molecules: Consequences for the third phase formation Solvent Extr. Ion Exch. 2007, 25, 545-576
76. Motokawa, R.; Suzuki, S.; Ogawa, H.; Antonio, M. R.; Yaita, T. Microscopic structures of tri- n -butyl phosphate/ n -octane mixtures by X-ray and neutron scattering in a wide q range J. Phys. Chem. B 2012, 116, 1319-27
77. Fritz, G.; Glatter, O. Structure and interaction in dense colloidal systems: Evaluation of scattering data by the generalized indirect Fourier transformation method J. Phys.: Condens. Matter 2006, 18, S2403-S2419
78. 5 mixtures and microemulsions with n -octane: Direct analysis by Fourier transformation J. Chem. Phys. 1996, 105, 1175-1188
79. Glatter, O. The interpretation of real-space information from small-angle scattering experiments J. Appl. Crystallogr. 1979, 12, 166-75
80. Spalla, O. General theorems in small-angle scattering. In Neutrons, X-Rays and Light; Lindner, P.; Zemb, T., Eds.; Elsevier Science B.V.: Amsterdam, 2002; pp 49-71.
81. Guilbaud, J.-B.; Saiani, A. Using small angle scattering (SAS) to structurally characterise peptide and protein self-assembled materials Chem. Soc. Rev. 2011, 40, 1200-1210
82. Shrestha, L. K.; Sharma, S. C.; Sato, T.; Glatter, O.; Aramaki, K. Small-angle X-ray scattering (SAXS) study on nonionic fluorinated micelles in aqueous system J. Colloid Interface Sci. 2007, 316, 815-24
83. Glatter, O. The inverse scattering problem in small-angle scattering. In Neutrons, X-rays and Light; Lindner, P.; Zemb, T., Eds.; Elsevier Science B.V.: Amsterdam, 2002; pp 73-102.