Process intensification of catalytic hydrogenation of ethylanthraquinone with gas-liquid microdispersion

AIChE Journal

Volumn 58, Issue 5, 2012, Pages 1326-1335

  Tan, J ^a   Zhang, J S ^a   Lu, Y C ^a   Xu, J H ^a   Luo, G S ^a  

^a TSINGHUA UNIVERSITY   (China)

Author keywords

Gas liquid; Hydrogenation; Mass transfer; Microdispersion

Indexed keywords

CATALYTIC HYDROGENATION; DISPERSION MEDIUM; ETHYLANTHRAQUINONES; GAS LIQUIDS; HYDROGENATION REACTORS; MASS TRANSFER PERFORMANCE; MICRO-DISPERSION; MICRO-FILTRATION MEMBRANES; MICROBUBBLES; ORDERS OF MAGNITUDE; OVERALL MASS TRANSFER COEFFICIENT; PACKED BED REACTOR; PROCESS INTENSIFICATION; REACTION SYSTEM; TRICKLE BED REACTOR;

CHEMICAL REACTORS; HYDROGENATION; MASS TRANSFER; MATHEMATICAL MODELS; MICROFILTRATION; PACKED BEDS;

LIQUIDS;

EID: 84859499192     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.12670     Document Type: Article

References (31)

1. Strukul G. Catalytic Oxidations with Hydrogen Peroxide as Oxidant. In: Strukul G, editor. Dordrecht: Kluwer, 1992:1-11.
2. Goor G. Catalytic Oxidations with Hydrogen Peroxide as Oxidant. In: Strukul G, editor. Dordrecht: Kluwer, 1992:13-43.
3. Tundo P, Anastas P, Black DS, Breen J, Collins T, Memoli S, Miyamoto J, Polyakoff M, Tumas W. Synthetic pathways and processes in green chemistry. Introductory overview. Pure Appl Chem. 2000; 72: 1207-1228.
4. Anastas PT, Warner JC. Green Chemistry: Theory and Practice. NewYork: Oxford University Press, 1998.
5. 3: the effect of water and NaOH on the degradation process. Appl A Catal A: Gen. 2005; 284: 59-67.
6. Halder R, Lawal A. Experimental studies on hydrogenation of anthraquinone derivative in a microreactor. Catal Today. 2007; 125: 48-55.
7. Kirk RE, Othmer DF. Encyclopedia of Chemical Technology. New York: Wiley, 971.
8. Santacesaria E, Di Serio M, Russo A, Leone U, Velotte R. Kinetic and catalytic aspects in the hydrogen peroxide production via anthraquinone. Chem Eng Sci. 1999; 54: 2799-2806.
9. Jorgensen K, Jensen AD, Sloth J, Dam-Johansen K, Bach P. Comments to "Analysis of constant rate period of spray drying of slurry." Chem Eng Sci. 2007; 62: 2096-2108.
10. Yue J, Luo LG, Gonthier Y, Chen GW, Yuan Q. An experimental investigation of gas-liquid two-phase flow in single microchannel contactors. Chem Eng Sci. 2008; 63: 4189-4202.
11. Tegrotenhuis WE, Cameron RJ, Viswanathan VV, Wegeng RS. Solvent extraction and gas absorption using microchannel contactors. Presented at the 3rd International Conference on Microreaction Technology, New Orleans, LA, April 18-21 1999: 541-549.
12. Chambers RD, Holling D, Spink RCH, Sandford G. Gas-liquid thin film microreactors for selective direct fluorination. Lab Chip. 2001; 1: 132-137.
13. Hessel V, Ehrfeld W, Golbig K, Haverkamp V, LDw H, Stor M, Wille C, Guber A, Jnhnisch K, Baerns M. Gas/liquid microreactors for direct fluorination of aromatic compounds using elemental fluorine. Presented at the 3rd International Conference on Microreaction Technology, New Orleans, LA, April 18-21 1999: 526-540.
14. Jahnisch K, Baerns M, Hessel V, Ehrfeld W, Haverkamp W, LDwe H, Wille C, Guber A. Direct fluorination of toluene using elemental fluorine in gas/liquid microreactors. J Fluorine Chem. 2000; 105: 117-128.
15. Mas de N, Jackman RJ, Schmidt MA, Jensen KF. Microchemical systems for direct fluorination of aromatics. Presented at the 5th International Conference on Microreaction Technology, Strasbourg, France, May 27-30 2001: 60-67.
16. Antes J, Tuercke T, Marioth E, Lechner F, Scholz M, SchnRrer F, Krause HH, LDbbecke S. Investigation, analysis and optimization of exothermic nitrations in microreactor processes. Presented at the 5th International Conference on Microreaction Technology, Strasbourg, France, May 27-30 2001: 446-454.
17. Tadepalli S, Qian DY, Lawal A. Comparison of performance of microreactor and semi-batch reactor for catalytic hydrogenation of o-nitroanisole. Catal Today. 2007; 125: 64-73.
18. McGovern S, Harish G, Pai CS, Mansfield W, Taylor JA, Pau S, Besser RS. Multiphase flow regimes for hydrogenation in a catalyst-trap microreactor. Chem Eng J. 2008; 135: S229-S236.
19. Trachsel F, Hutter C, von Rohr PR. Transparent silicon/glass microreactor for high-pressure and high-temperature reactions. Chem Eng J. 2008; 135: S309-S316.
20. Yue J, Chen GW, Yuan Q, Luo LA, Gonthier Y. Hydrodynamics and mass transfer characteristics in gas-liquid flow through a rectangular microchannel. Chem Eng Sci. 2007; 62: 2096-2108.
21. Tan J, Xu JH, Wang K, Luo GS. Rapid measurement of gas solubility in liquids using a membrane dispersion micro-contactor. Ind Eng Chem Res. 2010; 49: 10040-10045.
22. Xu JH, Luo GS, Chen GG, Tan B. Mass transfer performance and two-phase flow characteristic in membrane dispersion mini-extractor. J Membrane Sci. 2005; 249: 75-81.
23. Chen GG, Luo GS, Xu JH, Wang JD. Membrane dispersion precipitation method to prepare nanopartials. Powder Technol. 2004; 139: 180-185.
24. 4 particles in a two-liquid phase micro-mixing process. J Cryst Growth. 2005; 279: 501-507.
25. Chen GG, Luo GS, Sun Y, Xu JH, Wang JD. A ceramic microfiltration tube membrane dispersion extractor. AIChE J. 2004; 50: 382-387.
26. Berglint T, Schoon NH. Kinetic and mass-transfer aspects of the hydrogenation stage of the anthraouinone process for hydrogen-peroxide production. Ind Eng Chem Process Des Dev. 1981; 20: 615-621.
27. Tan J, Du L, Xu JH, Wang K, Luo GS. Surfactant free microdispersion process of gas in organic solvents in microfluidic devices. AIChE J. In press.
28. Solvay SA. Making hydrogen peroxide by the anthraquinone process. Patent: GB 2334028A, 1998.
29. AlDahhan MH, Larachi F, Dudukovic MP, Laurent A. High-pressure trickle-bed reactors: a review. Ind Eng Chem Res. 1997; 36: 3292-3314.
30. Ranz WE. Friction and transfer coefficients for single particles and packed beds. Chem Eng Progr. 1952; 48: 247-253.
31. Wakao N, Funazkri T. Effect of fluid dispersion coefficients on particle-to-fluid mass-transfer coefficients in packed-beds-correlation of Sherwood number. Chem Eng Sci. 1978; 33: 1375-1384.