Photochemical formation of hydroxyl radical from effluent organic matter

Environmental Science and Technology

Volumn 46, Issue 7, 2012, Pages 3788-3794

  Dong, Mei Mei ^a   Rosario Ortiz, Fernando L ^a  

^a University of Colorado   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EFFLUENT ORGANIC MATTER; FORMATION RATES; HYDROXYL RADICALS; HYDROXYLATION OF BENZENE; NITRATE LEVELS; PRODUCTION RATES; SIMULATED SUNLIGHT; ULTRA-PURE WATER; WASTEWATER EFFLUENTS; WASTEWATER SAMPLES; WAVELENGTH RANGES;

BENZENE; BIOGEOCHEMISTRY; BIOLOGICAL MATERIALS; EFFLUENT TREATMENT; EFFLUENTS; NITRATES; ORGANIC COMPOUNDS; PHENOLS; PHOTOCHEMICAL FORMING; PHOTOLYSIS; QUANTUM YIELD;

CHEMICALS REMOVAL (WATER TREATMENT);

BENZENE; CARBON; HYDROXYL RADICAL; IRON; NITRATE; ORGANIC MATTER; PHENOL;

BENZENE; CONCENTRATION (COMPOSITION); EFFLUENT; HYDROXYL RADICAL; NITRATE; ORGANIC MATTER; PHOTOCHEMISTRY; PHOTOLYSIS; QUANTUM MECHANICS; REACTION RATE; SOLAR RADIATION; WASTEWATER; WATER TREATMENT;

ACTIVATED SLUDGE; ALKALINITY; ARTICLE; DENITRIFICATION; EFFLUENT; FENTON REACTION; HYDROXYLATION; IRRADIATION; NITRIFICATION; PHOTOCHEMISTRY; PHOTOLYSIS; QUANTUM YIELD; SUNLIGHT; WASTE WATER; WASTE WATER MANAGEMENT; WATER QUALITY;

COLORADO; ENVIRONMENT; HYDROXYL RADICAL; NITRATES; ORGANIC CHEMICALS; PHENOLS; PHOTOCHEMICAL PROCESSES; PHOTOLYSIS; PHOTONS; QUANTUM THEORY; WASTE DISPOSAL, FLUID; WATER QUALITY;

EID: 84859334819     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es2043454     Document Type: Article

References (40)

1. Benotti, M.; Trenholm, R. A.; Vanderford, B. J.; Holady, J. C.; Stanford, B. D.; Snyder, S. A. Pharmaceuticals and endocrine disrupting compounds in U.S. drinking water Environ. Sci. Technol. 2009, 43 (3) 597-603
2. Kim, S. D.; Cho, J.; Kim, I. S.; Vanderford, B. J.; Snyder, S. A. Occurrence and removal of pharmaceuticals and endocrine disruptors in South Korean surface, drinking, and waste waters Water Res. 2007, 41 (5) 1013-1021
3. Richardson, S. D. Water Analysis: Emerging Contaminants and Current Issues Anal. Chem. 2007, 79 (12) 4295-4324
4. Kolpin, D. W.; Furlong, E. T.; Meyer, M. T.; Thurman, E. M.; Zaugg, S. D.; Barber, L. B.; Buxton, H. T. Pharmaceuticals, hormones, and other organic wastewater contaminants in US streams, 1999-2000: A national reconnaissance Environ. Sci. Technol. 2002, 36 (6) 1202-1211
5. Kolpin, D. W.; Skopec, M.; Meyer, M. T.; Furlong, E. T.; Zaugg, S. D. Urban contribution of pharmaceuticals and other organic wastewater contaminants to streams during differing flow conditions Sci. Total Environ. 2004, 328 (1-3) 119-130
6. Jobling, S.; Nolan, M.; Tyler, C. R.; Brighty, G.; Sumpter, J. P. Widespread sexual disruption in wild fish Environ. Sci. Technol. 1998, 32, 2498-2506
7. Schwarzenbach, R. P.; Gschwend, P. M.;; Imboden, D. M., Environmental Organic Chemistry; 2 nd ed.; John Wiley &Sons, Inc.: Hoboken, 2003; p 658-666.
8. Boreen, A. L.; Arnold, W. A.; McNeill, K. Photodegradation of pharmaceuticals in the aquatic environment: A review Aquat. Sci. 2003, 65 (4) 320-341
9. Blough, N. V.; Zeep, R. G., Reactive oxygen species in natural waters. In Active Oxygen in Chemistry, Foote, C. S.; Valentine, J. S.; Greenberg, A.; Liebman, J. F., Eds.; Blackie A & P: Glasgow, 1995; pp 280-333.
10. Vermilyea, A. W.; Voelker, B. M. Photo-fenton reaction at near neutral pH Environ. Sci. Technol. 2009, 43 (18) 6927-6933
11. White, E. M.; Vaughan, P. P.; Zepp, R. G. Role of the photo-Fenton reaction in the production of hydroxyl radicals and photobleaching of colored dissolved organic matter in a coastal river of the southeastern United States Aquat. Sci. 2003, 65 (4) 402-414
12. Nakatani, N.; Ueda, M.; Shindo, H.; Takeda, K.; Sakugawa, H., Contribution of the photo-Fenton reaction to hydroxyl radical formation rates in river and rain water samples. Jpn. Soc. Anal. Chem. 2007, 23.
13. Zepp, R. G.; Faust, B. C.; Hoigne, J. Hydroxyl radical formation in aqueous reactions (Ph 3-8) of Iron(Ii) with hydrogen-peroxide-The photo-fenton reaction Environ. Sci. Technol. 1992, 26 (2) 313-319
14. Mack, J.; Bolton, J. R. Photochemistry of nitrite and nitrate in aqueous solution: a review J. Photochem. Photobiol. A 1999, 128, 1-13
15. Pochon, A.; Vaughan, P. P.; Gan, D. Q.; Vath, P.; Blough, N. V.; Falvey, D. E. Photochemical oxidation of water by 2-methyl-1,4-benzoquinone: Evidence against the formation of free hydroxyl radical J. Phys. Chem. A 2002, 106 (12) 2889-2894
16. Page, S. E.; Arnold, W. A.; McNeill, K. Assessing the contribution of free hydroxyl radical in organic matter-sensitized photohydroxylation reactions Environ. Sci. Technol. 2011, 45 (7) 2818-2825
17. Vaughan, P. P.; Blough, N. V. Photochemical formation of hydroxyl radical by constituents of natural waters Environ. Sci. Technol. 1998, 32 (19) 2947-2953
18. Alegria, A. E.; Ferrer, A.; Santiago, G.; Sepulveda, E.; Flores, W. Photochemistry of water-soluble quinones. Production of the hydroxyl radical, singlet oxygen and the superoxide ion J. Photochem. Photobiol., A 1999, 127 (1-3) 57-65
19. Alegria, A. E.; Ferrer, A.; Sepulveda, E. Photochemistry of water-soluble quinones. Production of a water-derived spin adduct Photochem. Photobiol. 1997, 66 (4) 436-442
20. Ononye, A. I.; McIntosh, A. R.; Bolton, J. R. Mechanism of the photochemistry of p-benzoquinone in aqueous solutions. 1. Spin trapping and flash photolysis electron paramagnetic resonance studies J. Phys. Chem. 1986, 90 (23) 6266-6270
21. Vione, D.; Falletti, G.; Maurino, V.; Minero, C.; Pelizzetti, E.; Malandrino, M.; Ajassa, R.; Olariu, R. I.; Arsene, C. Sources and sinks of hydroxyl radicals upon irradiation of natural water samples Environ. Sci. Technol. 2006, 40 (12) 3775-3781
22. Mopper, K.; Zhou, X. L. Hydroxyl radical photoproduction in the sea and its potential impact on marine processes Science 1990, 250 (4981) 661-664
23. Hulstrom, R.; Bird, R.; Riordan, C. Spectral solar irradiance data sets for selected terrestrial conditions Sol. Cells 1985, 15, 365-391
24. Dorfman, L. M.; Taub, I. A.; Buhler, R. E. Pulse radiolysis studies. I Tansient spectra and reaction-rate constants in irradiated aqueous solutions of benzene J. Chem. Phys. 1962, 36, 3051-61
25. -) in Aqueous-Solution J. Phys. Chem. Ref. Data 1988, 17 (2) 513-886
26. Dong, M. M.; Mezyk, S. P.; Rosario-Ortiz, F. L. Reactivity of effluent organic matter (Ef0M) with hydroxyl radical as a function of molecular weight Environ. Sci. Technol. 2010, 44 (15) 5714-5720
27. Rosario-Ortiz, F. L.; Mezyk, S. P.; Doud, D. F. R.; Snyder, S. A. Quantitative correlation of absolute hydroxyl radical rate constants with mon-isolated effluent organic matter bulk properties in water Environ. Sci. Technol. 2008, 42 (16) 5924-5930
28. - Ber Bunsen Phys Chem 1990, 94, 594-599
29. •OH)) photoproduction and consumption in authentic acidic continental cloud waters from Whiteface Mountain, New York: The role of the Fe(r) (r=II, III) photochemical cycle J. Geophys. Res., [Atmos.] 1998, 103 (D3) 3487-3504
30. APHA; AWWA; WEF. Standard Methods for the Examination of Water & Wastewater; American Public Health Association: Washington DC, 2005.
31. McKnight, D. M.; Boyer, E. W.; Westerhoff, P. K.; Doran, P. T.; Kulbe, T.; Andersen, D. T. Spectrofluorometric characterization of dissolved organic matter for indication of precursor organic material and aromaticity Limnol. Oceanogr. 2001, 46 (1) 38-48
32. Brezonik, P. L.; Fulkerson-Brekken, J. Nitrate-induced photolysis in natural waters: controls on concentrations of hydroxyl radical photo-intermediates by natural scavenging agents Environ. Sci. Technol. 1998, 32 (19) 3004-3010
33. Zepp, R. G.; Hoigne, J.; Bader, H. Nitrate-induced photooxidation of trace organic-chemicals in water Environ. Sci. Technol. 1987, 21 (5) 443-450
34. 2 in natural waters exposed to sunlight Environ. Sci. Technol. 1988, 22, 1156-1160
35. - in aqueous solutions J. Phys. Chem. 1988, 92, 6278-6283
36. Grebel, J. E.; Pignatello, J. J.; Mitch, W. A. Sorbic acid as a quantitative probe for the formation, scavenging and steady-state concentrations of the triplet-excited state of organic compounds Water Res. 2011, 45, 6535-6544
37. Zepp, R. G.; Schlotzhauer, P. F.; Sink, R. M. Photosensitized transformations involving electronic-energy transfer in natural-waters-Role of humic substances Environ. Sci. Technol. 1985, 19 (1) 74-81
38. Focazio, M. J.; Kolpin, D. W.; Barnes, K. K.; Furlong, E. T.; Meyer, M. T.; Zaugg, S. D.; Barber, L. B.; Thurman, M. E. A national reconnaissance for pharmaceuticals and other organic wastewater contaminants in the United States-II) Untreated drinking water sources Sci. Total Environ. 2008, 402 (2-3) 201-216
39. Lam, M. W.; Tantuco, K.; Mabury, S. A. PhotoFate: A new approach in accounting for the contribution of indirect photolysis of pesticides and pharmaceuticals in surface waters Environ. Sci. Technol. 2003, 37 (5) 899-907
40. Lam, M. W.; Mabury, S. A. Photodegradation of the pharmaceuticals atorvastatin, carbamazepine, levofloxacin, and sulfamethoxazole in natural waters Aquat. Sci. 2005, 67 (2) 177-188