Electrochemical performance of membranes based on hydrogenated polynorbornenes functionalized with imide side groups containing sulfonated fluorinated moieties

Journal of Membrane Science

Volumn 403-404, Issue , 2012, Pages 121-128

  Santiago, Arlette A ^a   Vargas, Joel ^b   Tlenkopatchev, Mikhail A ^a   López González, Mar ^c   Riande, Evaristo ^c  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^b UNIVERSIDAD AUTÓNOMA DEL CARMEN   (Mexico)

^c INSTITUTO DE CIENCIA Y TECNOLOGÍA DE POLÍMEROS   (Spain)

Author keywords

Cation exchange membrane; Ring opening metathesis polymerization; Sulfonated fluorinated polynorbornene dicarboximide

Indexed keywords

CATION EXCHANGE MEMBRANES; CONCENTRATION CELLS; ELECTROCHEMICAL CHARACTERISTICS; ELECTROCHEMICAL PERFORMANCE; FUNCTIONALIZED; NAFION MEMBRANE; OSMOTIC FLOW; PERMSELECTIVITIES; POLYMER MEMBRANE; POLYNORBORNENE DICARBOXIMIDE; POLYNORBORNENES; RING OPENING METATHESIS POLYMERIZATION;

ELECTRIC BATTERIES; ELECTROMOTIVE FORCE; FUNCTIONAL POLYMERS; HYDROGENATION; POSITIVE IONS; PROTON CONDUCTIVITY; RING OPENING POLYMERIZATION;

MEMBRANES;

IMIDE; NORBORNENE DERIVATIVE; POLY (N 4-OXYBENZENESULFONIC ACID 2,3,5,6 TETRAFLUOROPHENYL EXO ENDO NORBORNENE 5,6 DICARBOXIMIDE); UNCLASSIFIED DRUG;

ARTICLE; CATION EXCHANGE MEMBRANE; CHEMICAL PARAMETERS; ELECTROCHEMISTRY; MEMBRANE; OSMOSIS; POLYMERIZATION; PRIORITY JOURNAL; PROTON CONDUCTIVITY; SULFONATION; TEMPERATURE;

EID: 84859268623     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2012.02.034     Document Type: Article

References (37)

1. Sata T. Ion-Exchange Membranes 2004, RSC, Cambridge.
2. Xu T. Ion exchange membranes: state of their development and perspective. J. Membr. Sci. 2005, 263:1-29.
3. Cui S., Liu J., Selvan M.E., Keffer D.J., Edwards B.J., Steele W.V. A molecular dynamics study of a Nafion polyelectrolyte membrane and the aqueous phase structure for proton transport. J. Phys. Chem. B 2007, 111:2208-2218.
4. Ennari J., Elomaa M., Sundholm F. Modelling a polyelectrolyte system in water to estimate the ion-conductivity. Polymer 1999, 40:5035-5041.
5. Pozuelo J., Riande E., Saiz E., Compañ V. Molecular dynamics simulations of proton conduction in sulfonated poly (phenyl sulfone)s. Macromolecules 2006, 39:8862-8866.
6. Garrido L., Pozuelo J., López-González M., Fang J., Riande E. Simulation and experimental studies of proton diffusion in polyelectrolytes based on sulfonated naphthalenic copolyimides. Macromolecules 2009, 42:6572-6580.
7. Hickner M.A., Ghassemi H., Kim Y.S., Einsla B.R., McGrath J.E. Alternative polymer systems for proton exchange membranes (PEM)s. Chem. Rev. 2004, 104:4587-4612.
8. Contreras A.P., Tlenkopatchev M.A., López-González M.M., Riande E. Synthesis and gas transport properties of new high glass transition temperature ring-opened polynorbornenes. Macromolecules 2002, 35:4677-4684.
9. Tlenkopatchev M., Vargas J., Almaráz-Girón M.A., López-González M., Riande E. Gas sorption in new fluorine containing polynorbornenes with imide side chain groups. Macromolecules 2005, 38:2696-2703.
10. Vargas J., Santiago A.A., Tlenkopatchev M.A., López-González M., Riande E. Gas transport in membranes based on polynorbornenes with fluorinated dicarboximide side moieties. J. Membr. Sci. 2010, 361:78-88.
11. Vargas J., Santiago A.A., Tlenkopatchev M.A., Gaviño R., Fe Laguna M., López-González M., Riande E. Gas transport and ionic transport in membranes based on polynorbornenes with functionalized imide side groups. Macromolecules 2007, 40:563-570.
12. Santiago A.A., Vargas J., Fomine S., Gaviño R., Tlenkopatchev M.A. Polynorbornene with pentafluorophenyl imide side chain groups: synthesis and sulfonation. J. Polym. Sci. A: Polym. Chem. 2010, 48:2925-2933.
13. O'Hagan D. Understanding organofluorine chemistry. An introduction to the CF bond. Chem. Soc. Rev. 2008, 37:308-319.
14. Yampoĺskii Y.P., Bespalova N.B., Sh Finkeĺshtein E., Bondar V.I., Popov A.V. Synthesis, gas permeability, and gas sorption properties of fluorine-containing norbornene polymers. Macromolecules 1994, 27:2872-2878.
15. Compañ V., Fernández-Carretero F.J., Riande E., Linares A., Acosta J.L. Electrochemical properties of ion-exchange membranes based on sulfonated EPDM-polypropylene blends. J. Electrochem. Soc. 2007, 154:B159-B164.
16. Barsoukov E., Macdonalds J.R. Impedance Spectroscopy: Theory, Experiment and Applications 2005, Wiley, NJ, (Chapter 2). 2nd ed.
17. Nyquist H. Thermal agitation of electric charge in conductors. Phys. Rev. 1928, 32:110-113.
18. Warburg E. About the behaviour of so-called impolarizable electrodes in the presence of alternating current. Ann. Phys. Chem. 1899, 67:493-499.
19. Bard A.J., Faulkner L.R. Electrochemical Methods. Fundamentals and Applications 2001, Wiley, (Section 10.3). 2nd ed.
20. Bode W.W. Network Analysis in Feedback Amplifier Design 1956, Van Nostrand, Princenton, NJ.
21. Wu S. Polymer Interface and Adhesion 1982, Marcel Dekker, New York, (Chapter 5).
22. Ghassemi H., McGrath J.E., Zawodzinsky T.A. Multiblock sulfonated-fluorinated poly(arylene ether)s for a proton exchange membrane fuel cell. Polymer 2006, 47:4132-4139.
23. O'Hayre R., Cha S.-W., Colella W., Prinz F.B. Fuel Cell Fundamentals 2006, Wiley & Sons, New York, (Chapter 4).
24. Guo X., Zhai F., Fang J., Laguna M.F., López-González M., Riande E. Permselectivity and conductivity of membranes based on sulfonated naphthalenic copolyimides. J. Phys. Chem. B 2007, 111:13694-13702.
25. Yuan S., del Rio C., López-González M., Guo X., Fang J., Riande E. Impedance spectroscopy and performance of cross-linked new naphthalenic polyimide acid membranes. J. Phys. Chem. C 2010, 114:22773-22782.
26. Harris K.R., Newit P.J. Self-diffusion of water at low temperatures and high pressure. J. Chem. Eng. Data 1997, 42:346-348.
27. Krynicki K., Green C.D., Sawyer D.W. Pressure and temperature dependence of self-diffusion in water. Faraday Dis. Chem. Soc. 1978, 66:199-208.
28. Harris K.R., Woolf L.A. J. Chem. Soc. Faraday Trans. I 1980, 76:377-385.
29. Cooper K.R. Characterization through-plane and in-plane ionic conductivity of polymer electrolyte membranes. ECS Trans. 2011, 41:1371-1380.
30. Rikukawa M., Sanui K. Proton conducting polymer electrolyte membranes based on hydrocarbon polymers. Prog. Polym. Sci. 2000, 25:1463-1502.
31. Paddison S.J. Proton conduction mechanisms at low degrees of hydration in sulfonic acid-based polymer electrolytes membranes. Annu. Rev. Mater. Res. 2003, 33:289-319.
32. Kreuer K.D., Paddison S.J., Spohr E., Schuster M. Transport in proton conductors for fuel cell applications: simulations, elementary reactions, and phenomenology. Chem. Rev. 2004, 104:4637-4678.
33. Tuckerman M., Laasonen K., Sprik M., Parrinello M. Ab initio molecular dynamics simulation of the solvation and transport of hydronium and hydroxyl ions in water. J. Chem. Phys. 1995, 103:150-161.
34. - ions in water. J. Phys. Chem. 1995, 99:5749-5752.
35. Tuckerman M.E., Marx D., Klein M., Parrinello M. On the quantum nature of the shared proton in hydrogen bonds. Science 1997, 275:817-820.
36. Marx D., Tuckerman M.E., Hutter J., Parrinello M. The nature of the hydrated excess proton in water. Nature 1999, 397:601-604.
37. Marx D., Tuckerman M.E., Parrinello M. Solvated excess protons in water: quantum effects on the hydration structure. J. Phys. Condens. Matter 2000, 12:A153-A159.