Role of organic diluents on Am(III) extraction and transport behaviour using N,N,N',N'-tetraoctyl-3-oxapentanediamide as the extractant

Journal of Membrane Science

Volumn 403-404, Issue , 2012, Pages 71-77

  Panja, S ^a   Mohapatra, P K ^a   Tripathi, S C ^a   Gandhi, P M ^a   Janardan, P ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Americium; Diffusion coefficient; Diluent; Supported liquid membrane; TODGA

Indexed keywords

1 ,2-DICHLOROETHANES; 1-OCTANOL; DILUENT; DILUENT EFFECT; DISTRIBUTION RATIO; EXTRACTANTS; MEMBRANE DIFFUSION; MEMBRANE PORE SIZE; N-DODECANE; ORGANIC DILUENTS; SUPPORTED LIQUID MEMBRANE; TODGA; TRANSPORT BEHAVIOUR;

AMERICIUM; BENZENE; CHLORINE COMPOUNDS; DIFFUSION; KEROSENE; SOLVENT EXTRACTION; TOLUENE; TRANSPORT PROPERTIES;

LIQUID MEMBRANES;

1,2 DICHLOROETHANE; AMERICIUM; BENZENE DERIVATIVE; CARBON TETRACHLORIDE; CHLOROFORM; DILUENT; DODECANE; KEROSENE; N,N,N',N' TETRAOCTYL 3 OXAPENTANEDIAMIDE; NITROBENZENE; OCTANOL; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; DIFFUSION COEFFICIENT; LIQUID MEMBRANE; PRIORITY JOURNAL; SOLVENT EXTRACTION;

EID: 84859265977     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2012.02.022     Document Type: Article

References (38)

1. Boyadzhiev L., Lazarova Z. Membrane Separations Technology: Principles and Applications 1995, 283-300. Elsevier Science B.V. R.D. Noble, S.A. Stern (Eds.).
2. Mohapatra P.K., Manchanda V.K. Liquid membrane based separations of actinides and fission products. Indian J. Chem. 2003, 42A:2925-2939.
3. Bartsch R.A., Way J.D., Chrisstoffels L.A.J., de Jong F., Reinhouldt D.N. Chemical Separations with Liquid Membranes. ACS Symposium Series Number 642 1996, 1-10. ACS, Washington, DC. R.A. Bartsch, J.D. Way (Eds.).
4. Kocherginsky N.M., Yang Q., Seelam L. Recent advances in supported liquid membrane technology. Sep. Purif. Technol. 2007, 53:171-177.
5. Ansari S.A., Pathak P.N., Mohapatra P.K., Manchanda V.K. Aqueous partitioning of minor actinides by different processes. Sep. Purif. Rev. 2011, 40:43-76.
6. Mathur J.N., Murali M.S., Nash K.L. Actinide partitioning - a review. Solv. Extr. Ion Exch. 2001, 19:357.
7. Paiva A.P., Malik P. Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes. J. Radioanal. Nucl. Chem. 2004, 261:485-496.
8. Zhu Y., Jiao R. Chinese experience in the removal of actinides from high active waste by tri alkyl phosphine oxide extraction. Nucl. Technol. 1994, 108:361-369.
9. Morita Y., Glatz J.P., Kubota M., Koch L., Pagliosa G., Roemer K., Nicholl A. Actinide partitioning from HLW in a continuous DIDPA extraction process by means of centrifugal extractors. Solv. Extr. Ion Exch. 1996, 14:385-400.
10. Serrano-Purroy D., Christiansen B., Malmbeck R., Glatz J.P., Baron P. Partitioning of minor actinides from HLW using DIAMEX process. Proceedings Global 2003 2003.
11. Sasaki Y., Choppin G.R. Solvent extraction of Eu, Th, U, Np and Am with N,N'-dimethyl-N,N'-dihexyl-3-oxapentanediamide and its analogous compounds. Anal. Sci. 1998, 12:225.
12. Sasaki Y., Zhu Z.X., Sugo Y., Kimura T. Extraction of various metal ions from nitric acid to n-dodecane by diglycolamide (DGA) compounds. J. Nucl. Sci. Technol. 2007, 44:405.
13. 3-n-dodecane system. Solv. Extr. Ion Exch. 2001, 19:91.
14. Modolo G., Hanna A., Schreinemachers C., Vijgen H. Development of a TODGA based process for partitioning of actinides from a PUREX raffinate. Part I. Batch extraction optimization studies and stability tests. Solv. Extr. Ion Exch. 2007, 25:703.
15. Modolo G., Asp H., Vijgen H., Malmbeck R., Magnusson D., Sorel C. Demonstration of a TODGA-based continuous counter-current extraction process for the partitioning of actinides from a simulated PUREX raffinate. Part II. Centrifugal contactor runs. Solv. Extr. Ion Exch. 2008, 26:62-76.
16. Magnusson D., Christiansen B., Glatz J., Malmbeck R., Modolo G., Purroy D., Sorel C. Demonstration of a TODGA based extraction process for the partitioning of minor actinides from a PUREX raffinate. Part III. Centrifugal contactor run using genuine fuel solution. Solv. Extr. Ion Exch. 2009, 27:26-35.
17. Ansari S.A., Mohapatra P.K., Prabhu D.R., Manchanda V.K. Transport of Americium(III) through a supported liquid membrane containing N,N,N',N'-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier. J. Membr. Sci. 2006, 282:133-141.
18. Ansari S.A., Mohapatra P.K., Prabhu D.R., Manchanda V.K. Evaluation of N,N,N',N'-tetraoctyl-3-oxapentane-diamide (TODGA) as a mobile carrier in remediation of nuclear waste using supported liquid membrane. J. Membr. Sci. 2007, 298:169-174.
19. Panja S., Mohapatra P.K., Tripathi S.C., Manchanda V.K. Studies on uranium(VI) pertraction across a N,N,N',N'-tetraoctyldiglycolamide (TODGA) supported liquid membrane. J. Membr. Sci. 2009, 337:274-281.
20. Panja S., Mohapatra P.K., Kandwal P., S.C.Tripathi, Manchanda V.K. Pertraction of plutonium in the +4 oxidation state through a supported liquid membrane containing TODGA as the carrier. Desalination 2010, 262:57-63.
21. Ansari S.A., Mohapatra P.K., Manchanda V.K. Recovery of actinides and lanthanides from high-level waste using hollow-fiber supported liquid membrane with TODGA as the carrier. Ind. Eng. Chem. Res. 2009, 48:8605-8612.
22. Marcus Y. Diluent effects in solvent extraction. Solv. Extr. Ion Exch. 1989, 7:567-575.
23. Ansari S.A., Pathak P.N., Hussain M., Prasad A.K., Parmar V.S., Manchanda V.K. N,N,N',N' tetraoctyl diglycolamide (TODGA): a promising extractant for actinide-partitioning from high-level waste (HLW). Solv. Extr. Ion Exch. 2005, 23:463.
24. Sriram S., Manchanda V.K. Transport of metal ions across a supported liquid membrane (SLM) using dimethyldibutyltetradecyl-1,3-malonamide (DMDBTDMA) as the carrier. Solv. Extr. Ion Exch. 2002, 20:97-114.
25. Mohapatra P.K., Lakshmi D.S., Manchanda V.K. Diluent effect on Sr(II) extraction using di-tert-butyl cyclohexano 18 crown 6 as the extractant and its correlation with transport data obtained from supported liquid membrane studies. Desalination 2006, 198:166-172.
26. Bartsch R.A., Jeona E-G., Walkowiaka W., Apostoluk W. Effect of solvent in competitive alkali metal cation transport across bulk liquid membranes by a lipophilic lariat ether carboxylic acid carrier. J. Membr. Sci. 1999, 159:123-131.
27. P.K. Mohapatra, Ph.D. Thesis, University of Bombay, 1993.
28. Sriram S., Mohapatra P.K., Pandey A.K., Manchanda V.K., Badheka L.P. Facilitated transport of americium(III) from nitric acid media using dimethyldibutyl-tetradecyl-1,3-malonamide. J. Membr. Sci. 2000, 177:163-175.
29. D.L. Hofman, W.M. Craig, E.M. Buchalter, R.S. Birkill, J.J. Smit, Supported liquid membrane technology applied to the recovery of useful isotopes from reactor pool water, I. Chem. E. Symposium Series No. 103, Extraction'87, EFCE Publication Series No. 347 (1987) pp. 180-182.
30. Barton A.F.M. CRC Handbook of Solubility Parameters and Other Cohesion Parameters 1991, CRC, Press, Boca Raton, p. 95.
31. Roy Chowdhury M., Sanyal S.K. Diluent effect on extraction of tellurium (IV) and selenium (IV) by tri-n-butyl phosphate. Hydrometallurgy 1994, 34:319-330.
32. Jensen M.P., Yaita T., Chiarizia R. Reverse-micelle formation in the partitioning of trivalent f-element cations by biphasic systems containing a tetraalkyl diglycolamide. Langmuir 2007, 23:4765-4774.
33. Handbook of Chemistry and Physics 1992, CRC Press. W.M. Haynes (Ed.).
34. Jackson R. Transport in Porous Catalysts 1977, Elsevier, New York.
35. Rodgers V.G.J., Oppenheim S.F., Datta R. Correlation of permeability and solute uptake in membranes of arbitrary pore morphology. AIChE J. 1995, 41:1826-1829.
36. Wilke C.R., Chang P. Correlation of diffusion coefficients in dilute solutions. AIChE J. 1955, 1:264-270.
37. Panja S., Mohapatra P.K., Dakshinamoorthy A., Manchanda V.K. transport of thorium(IV) across a supported liquid membrane containing TODGA as the carrier. Sep. Sci. Technol. 2011, 46:94-104.
38. Crank J. The Mathematics of Diffusion 1975, Oxford University Press Inc, New York, p. 414. 2nd ed.