Electrooxidation of CO and methanol on well-characterized carbon supported Pt xSn electrodes. Effect of crystal structure

International Journal of Hydrogen Energy

Volumn 37, Issue 8, 2012, Pages 7109-7118

  Herranz, T ^a   Garcia S ^a   Martinez Huerta M V ^a   Pena M A ^a   Fierro, J L G ^a   Somodi, F ^b   Borbath I ^b   Majrik, K ^b   Tompos, A ^b   Rojas, S ^a  

^a INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

^b CHEMICAL RESEARCH CENTER   (Hungary)

Author keywords

CO; DEMS; EC IRAS; Methanol; Pt 3Sn fcc; PtSn hcp

Indexed keywords

ATOMIC RATIO; CONTROLLED SURFACE REACTIONS; DEMS; DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY; EC-IRAS; ELECTROCATALYTIC PERFORMANCE; ELECTROCATALYTIC PROCESS; ELECTROCHEMICAL TECHNIQUES; FCC PHASE; IN-SITU TECHNIQUES; INFRARED REFLECTION ABSORPTION SPECTROSCOPY; INTERMETALLIC PHASIS; METAL LOADING EFFECT; METAL LOADINGS; NANO-SIZED PARTICLES; PTSN ALLOY; PTSN HCP; SUPPORTED PT; XRD;

CATALYSTS; COBALT; CRYSTAL STRUCTURE; ELECTROOXIDATION; LOADING; MASS SPECTROMETRY; PLATINUM; RATING; SURFACE REACTIONS; TIN;

METHANOL;

EID: 84859217387     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.11.131     Document Type: Conference Paper

References (45)

1. N.M. Markovic, and P.N. Ross New electrocatalysts for fuel cells from model surfaces to commercial catalysts CATTECH 4 2000 110 126
2. C. Lamy Electrocatalytic oxidation of organic compounds on noble metals in aqueous solution Electrochim Acta 29 1984 1581 1588
3. F. Vigier, S. Rousseau, C. Coutanceau, J.M. Leger, and C. Lamy Electrocatalysis for the direct alcohol fuel cell Top Catal 40 2006 111 121
4. S. García-Rodríguez, F. Somodi, I. Borbáth, J. Margitfalvi, M.A. Peña, and J.L.G. Fierro Controlled synthesis of Pt-Sn/C fuel cell catalysts with exclusive Sn-Pt interaction: application in CO and ethanol electrooxidation reactions Appl Catal B Environ 91 2009 83 91
5. J.L. Gómez de la Fuente, M.V. Martínez-Huerta, S. Rojas, P. Hernández-Fernández, P. Terreros, and J.L.G. Fierro Tailoring and structure of PtRu nanoparticles supported on functionalized carbon for DMFC applications: new evidence of the hydrous ruthenium oxide phase Appl Catal B Environ 88 2009 505 514
6. M.V. Martínez-Huerta, S. Rojas, J.L. Gómez de la Fuente, P. Terreros, M.A. Peña, and J.L.G. Fierro Effect of Ni addition over PtRu/C based electrocatalysts for fuel cell applications Appl Catal B Environ 69 2006 75 84
7. x nanoparticles: structural characteristics and performance for methanol electrooxidation Chem Mater 20 2008 4249 4259
8. N. Tsiouvaras, M.V. Martínez-Huerta, O. Paschos, U. Stimming, J.L.G. Fierro, and M.A. Peña PtRuMo/C catalysts for direct methanol fuel cells: effect of the pretreatment on the structural characteristics and methanol electrooxidation Int J Hydrogen Energy 35 2010 11478 11488
9. E.V. Spinacé, M. Linardi, and A.O. Neto Co-catalytic effect of nickel in the electro-oxidation of ethanol on binary Pt-Sn electrocatalysts Electrochem Commun 7 2005 365 369
10. S. García-Rodríguez, S. Rojas, M.A. Peña, J.L.G. Fierro, S. Baranton, and J.M. Léger An FTIR study of Rh-PtSn/C catalysts for ethanol electrooxidation: effect of surface composition Appl Catal B Environ 106 2011 520 528
11. 3Sn by impregnation-reduction and performance on the electrooxidation of CO and ethanol J Power Sources 195 2010 5564 5572
12. 2OH in acid medium Catal Today 160 2011 28 38
13. F. Colmati, E. Antolini, and E.R. González Ethanol oxidation on carbon supported Pt-Sn electrocatalysts prepared by reduction with formic acid J Electrochem Soc 154 2007 B39 B47
14. P. Durussel, R. Massara, and P. Feschotte Le systme binaire PtSn J Alloys Compounds 215 1994 175 179
15. N.M. Markovic, and P.N. Ross Surface science studies of model fuel cell electrocatalysts Surf Sci Rep 45 2002 117 229
16. 25electrocatalyst prepared by reduction with formic acid: effect of thermal treatment Appl Catal B 73 2007 106 115
17. 3) as the source of metal Chem Mater 14 2002 1715 1720
18. E. Antolini, and E.R. Gonzalez The electro-oxidation of carbon monoxide, hydrogen/carbon monoxide and methanol in acid medium on Pt-Sn catalysts for low-temperature fuel cells: a comparative review of the effect of Pt-Sn structural characteristics Electrochim Acta 56 2010 1 14
19. K. Wang, H.A. Gasteiger, N.M. Markovic, and P.N. Ross On the reaction pathway for methanol and carbon monoxide electrooxidation on Pt-Sn alloy versus Pt-Ru alloy surfaces Electrochim Acta 41 1996 2587 2593
20. M.M.P. Janssen, and J. Moolhuysen Platinum - tin catalysts for methanol fuel cells prepared by a novel immersion technique, by electrocodeposition and by alloying Electrochim Acta 21 1976 861 868
21. M.M.P. Janssen, and J. Moolhuysen Binary systems of platinum and a second metal as oxidation catalysts for methanol fuel cells Electrochim Acta 21 1976 869 878
22. S. García-Rodríguez, S. Rojas, M. Vellosillo, M.A. Peña, J.L.G. Fierro, and P. Ocón Role of perfluorosulfonic ionomer as protective agent against strong adsorption of (bi)sulfate anions. Relevance in the determination of the area of Pt/C electrocatalysts Int J Hydrogen Energy 35 2010 11576 11581
23. H. Baltruschat Differential electrochemical mass spectrometry J Am Soc for Mass Spectrom 15 2004 1693 1706
24. H. Wang, L. Alden, F.J. DiSalvo, and H.D. Abruna Electrocatalytic mechanism and kinetics of SOMs oxidation on ordered PtPb and PtBi intermetallic compounds: DEMS and FTIRS study Phys Chem Chem Phys 10 2008 3739 3751
25. P. Hernández-Fernández, M. Montiel, P. Ocón, J.L.G. Fierro, H. Wang, and H.D. Abruña Effect of Co in the efficiency of the methanol electrooxidation reaction on carbon supported Pt J Power Sources 195 2010 7959 7967
26. 2/CO mixtures: Part II: the structure-activity relationship J Catal 232 2005 402 410
27. E.M. Crabb, R. Marshall, and D. Thompsett Carbon monoxide electro-oxidation properties of carbon-supported PtSn catalysts prepared using surface organometallic chemistry J Electrochem Soc 147 2000 4440 4447
28. M. Arenz, K.J.J. Mayhofer, V. Stamenkovic, B.B. Blizanac, T. Tomoyuki, and P.N. Ross The effect of the particle size on the kinetics of CO electrooxidation on high surface area Pt catalysts J Am Chem Soc 127 2005 6819 6829
29. A.E. Bjerke, P.R. Griffiths, and W. Theiss Surface-Enhanced infrared absorption of CO on Platinized platinum Anal Chem 71 1999 1967 1974
30. S. Park, S.A. Wasileski, and M.J. Weaver Some interpretations of surface vibrational spectroscopy pertinent to fuel-cell electrocatalysis Electrochim Acta 47 2002 3611 3620
31. S. Park, S.A. Wasileski, and M.J. Weaver Electrochemical infrared Characterization of carbon-supported platinum nanoparticles: a benchmark structural comparison with single-crystal electrodes and high-nuclearity Carbonyl clusters J Phys Chem B 105 2001 9719 9725
32. T.E. Shubina, and M.T.M. Koper Quantum-chemical calculations of CO and OH interacting with bimetallic surfaces Electrochim Acta 47 2002 3621 3628
33. 3Sn(111) J Am Chem Soc 125 2003 2736 2745
34. S.A. Wasileski, and M.J. Weaver What can we learn about electrode-chemisorbate bonding energetics from vibrational spectroscopy? an assessment from density functional theory Faraday Discuss 121 2002 285 300
35. S.A. Wasileski, M.T.M. Koper, and M.J. Weaver Field-dependent electrode-chemisorbate bonding: sensitivity of vibrational Stark effect and binding energetics to nature of surface coordination J Am Chem Soc 124 2002 2796 2805
36. S.-C. Chang, and M.J. Weaver Coverage-dependent dipole coupling for carbon monoxide adsorbed at ordered platinum(111)-aqueous interfaces: structural and electrochemical implications J Chem Phys 92 1990 4582 4594
37. H. Wang, T. Löffler, and H. Baltruschat Formation of intermediates during methanol oxidation: a quantitative DEMS study J Appl Electrochemistry 31 2001 759 765
38. Z. Jusys, and R.J. Behm Simultaneous oxygen reduction and methanol oxidation on a carbon-supported Pt catalyst and mixed potential formation-revisited Electrochim Acta 49 2004 3891 3900
39. T. Iwasita, and W. Vielstich On line mass-spectroscopy of volatile products during methanol oxidation at Platinum in acid-solutions J Electroanal Chem 201 1986 403 408
40. E.M. Belgsir, H. Huser, J.M. Léger, and C. Lamy A kinetic analysis of the oxidation of methanol at Platinum-based electrodes by quantitative-determination of the reaction-products using liquid-chromatography J Electroanal Chem 225 1987 281 286
41. A. Cuesta, Escudero Ma, B. Lanova, and H. Baltruschat Cyclic voltammetry, FTIRS, and DEMS study of the electrooxidation of carbon monoxide, formic acid, and methanol on cyanide-modified Pt(111) electrodes Langmuir 25 2009 6500 6507
42. E.A. Batista, G.R.P. Malpass, A.J. Motheo, and T. Iwasita New insight into the pathways of methanol oxidation Electrochem Commun 5 2003 843 846
43. E.A. Batista, G.R.P. Malpass, A.J. Motheo, and T. Iwasita New mechanistic aspects of methanol oxidation J Electroanal Chem 571 2004 273 282
44. C. Lamy, A. Lima, V. LeRhun, F. Delime, C. Coutanceau, and J.M. Léger Recent advances in the development of direct alcohol fuel cells (DAFC) J Power Sources 105 2002 283 296
45. H.A. Gasteiger, N. Markovic, P.N. Ross Jr., and E.J. Cairns Electro-oxidation of small organic molecules on well-characterized PtRu alloys Electrochim Acta 39 1994 1825 1832