Oxidation of chlorophenols in aqueous solution by excess potassium permanganate

Water, Air, and Soil Pollution

Volumn 223, Issue 3, 2012, Pages 1429-1435

  Hossain, S M Ghausul ^a   McLaughlan, Robert G ^a  

^a UNIVERSITY OF TECHNOLOGY SYDNEY   (Australia)

Author keywords

Chlorophenols; Kinetic; Oxidation; Potassium permanganate; Quenching agent

Indexed keywords

2 ,4-DCP; 2 ,4-DICHLOROPHENOL; 2-CHLOROPHENOLS; 3-CHLOROPHENOL (3-CP); 4-CHLOROPHENOL (4-CP); ABSORBANCES; ANALYTICAL METHOD; CALIBRATION CURVES; CHLORINE ATOM; CHLOROPHENOLS; CONCENTRATION RANGES; DETECTION LIMITS; DICHLOROPHENOLS; HYDROXYLAMINE HYDROCHLORIDE; MONOCHLOROPHENOLS; OXIDATION KINETICS; POTASSIUM PERMANGANATE; PSEUDO-FIRST-ORDER RATE CONSTANT; PSEUDO-FIRST-ORDER REACTION; QUENCHING AGENT; QUENCHING AGENTS; SECOND-ORDER RATE CONSTANTS; SODIUM SULFITE; SODIUM THIOSULFATE; SPECTRAL RANGE; SPECTRO-PHOTOMETRIC METHOD;

CHLORINE; GROUNDWATER; KINETICS; OXIDATION; PHENOLS; QUENCHING; RATE CONSTANTS; SODIUM; SOIL POLLUTION; SOLUTIONS;

POTASSIUM;

CHLOROPHENOL; PERMANGANATE POTASSIUM;

ABSORPTION; AQUEOUS SOLUTION; CALIBRATION; CHLOROPHENOL; CONCENTRATION (COMPOSITION); GROUNDWATER POLLUTION; OXIDATION; POTASSIUM; QUANTITATIVE ANALYSIS; REACTION KINETICS; SOIL REMEDIATION; WASTE TREATMENT; WATER TREATMENT;

ANALYTIC METHOD; AQUEOUS SOLUTION; ARTICLE; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; INTERMETHOD COMPARISON; OXIDATION; PH; PROCESS DEVELOPMENT; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; SPECTROPHOTOMETRY;

EID: 84859159283     PISSN: 00496979     EISSN: 15732932     Source Type: Journal    
DOI: 10.1007/s11270-011-0955-x     Document Type: Article

References (22)

1. Ahmed, S., Rasul, M. G., Martens, W. N., Brown, R., & Hasib, M. A. (2011). Advances in heterogeneous photocatalytic degradation of phenols and dyes in waste water: a review. Water, Air, and Soil Pollution, 215, 3-29.
2. Chiavola, A., Baciocchi, R., & Barducci, F. (2010). 3-chlorophenol biodegradation in squenching batch reactor: kinetic study and effect of the filling time. Water, Air, and Soil Pollution, 212, 219-229.
3. Czaplicka, M. (2004). Sources and transformation of chlorophenols in the natural environment. Science of the Total Environment, 322, 21-39.
4. Ermer, J. (2001). Validation in pharmaceutical analysis. Part I: an integrated approach. Journal of Pharmaceutical and Biomedical Analysis, 24, 755-767.
5. Han, J., Deming, R. L., & Tao, F. M. (2004). Theoretical study of molecular structures and properties of the complete series of chlorophenols. The Journal of Physical Chemistry. A, 108, 7736-7743.
6. He, D., Guan, X. H., Ma, J., Yang, X., & Cui, C. W. (2010). Influence of humic acids of different origins on oxidation of phenol and chlorophenols by permanganate. Journal of Hazardous Materials, 182, 681-688.
7. Hood, E. D., Thomson, N. R., Grossi, D., & Farquhar, G. J. (2000). Experimental determination of the kinetic rate law for the oxidation of perchloroethylene by potassium permanganate. Chemosphere, 40, 1383-1388. (Pubitemid 30165656)
8. Huang, K. C., Hoag, G. E., Chheda, P., Woody, B. A., & Dobbs, G. M. (2001). Oxidation of chlorinated ethenes by potassium permanganate: a kinetics study. Journal of Hazardous Materials, 87, 155-169.
9. ITRC. (2005). Technical and regulatory guidance for in situ chemical oxidation of contaminated soil and groundwater. 2nd edn. Interstate Technology and Regulatory Council, In Situ Chemical Oxidation Team, Washington, DC.
10. Khan, A. R., Al-Bahri, T. A., & Al-Haddad, A. (1997). Adsorption of phenol based organic pollutants on activated carbon from multi-component dilute aqueous solutions. Water Research, 31, 2102-2112. (Pubitemid 27312280)
11. Lee, D. G., & Sebastian, C. F. (1981). The oxidation of phenol and chlorophenols by alkaline permanganate. Canadian Journal of Chemistry, 59, 2776-2779.
12. Park, J. S., Her, N. G., & Yoon, Y. (2011). Sonochemical degradation of chlorinated phenolic compounds in water: effects of physicochemical properties of the compounds of degradation. Water, Air, and Soil Pollution, 215, 585-593.
13. Pera-Titus, M., García-Molina, V., Baños, M. A., Giménez, J., & Esplugas, S. (2004). Degradation of chlorophenols by means of advanced oxidation processes: a general review. Applied Catalysis B: Environmental, 47, 219-256. (Pubitemid 38215192)
14. Rodriguez, E., Onstad, G. D., Kull, T. P. J., Metcalf, J. S., Acero, J. L., & von Gunten, U. (2007). Oxidative elimination of cyanotoxins: comparison of ozone, chlorine, chlorine dioxide and permanganate. Water Research, 41, 3381-3393. (Pubitemid 47031262)
15. Smith, J. A., & Novak, J. T. (1987). Biodegradation of chlorinated phenols in subsurface soils. Water, Air, and Soil Pollution, 33, 29-42. (Pubitemid 17035673)
16. Thomas, O., & Burgess, C. (2007). UV-visible spectrophotometry of water and wastewater. Amsterdam: Elsevier.
17. USEPA. (2006). Engineering issue: in-situ chemical oxidation. Washington: Office of Research and Development. EPA/ 600/R-06/072.
18. Waldemer, R. H., & Tratnyek, P. G. (2006). Kinetics of contaminant degradation by permanganate. Environmental Science and Technology, 40, 1055-1061.
19. Yan, Y. E., & Schwartz, F. W. (1999). Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate. Journal of Contaminant Hydrology, 37, 343-365. (Pubitemid 29179559)
20. Yuan, S. H., & Lu, X. H. (2005). Comparison treatment of various chlorophenols by electro-Fenton method: relationship between the chlorine content and degradation. Journal of Hazardous Materials, B, 118, 85-92.
21. Zhai, X. H., Hua, I., Rao, P. S. C., & Lee, L. S. (2006). Cosolvent-enhanced chemical oxidation of perchloroethylene by potassium permanganate. Journal of Contaminant Hydrology, 82, 61-74. (Pubitemid 41811207)
22. Zhang, J., Li, G. B., & Ma, J. (2003). Effects of chlorine content and position of chlorinated phenols on their oxidation kinetics by potassium permanganate. Journal of Environmental Science, 15, 342-345. (Pubitemid 36947274)