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Volumn 638, Issue 3-4, 2012, Pages 526-533

Elusive fluoro sulfinyl nitrite, FS(O)NO, produced by photolysis of matrix-isolated FS(O) 2N

Author keywords

EPR spectroscopy; IR spectroscopy; Matrix isolation; Reactive intermediates; UV Vis spectroscopy

Indexed keywords


EID: 84858788995     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.201100396     Document Type: Review
Times cited : (22)

References (43)
  • 23
    • 36048959496 scopus 로고    scopus 로고
    • 2P(O)N (calculated Mulliken spin densities are 1.82, 1.84, and 1.88, respectively), the similarity of their D values also suggest similar contributions caused by spin-orbit coupling. This latter conclusion is reasonable, since the spin-orbit coupling term for these nitrenes was reported to be dominated by spin-flip transitions between the nearly degenerate n- and p SOMO's. See
    • 2P(O)N (calculated Mulliken spin densities are 1.82, 1.84, and 1.88, respectively), the similarity of their D values also suggest similar contributions caused by spin-orbit coupling. This latter conclusion is reasonable, since the spin-orbit coupling term for these nitrenes was reported to be dominated by spin-flip transitions between the nearly degenerate n- and p SOMO's. See:, F. Neese, J. Chem. Phys. 2007, 127, 164112/1-9.
    • (2007) J. Chem. Phys. , vol.127
    • Neese, F.1
  • 25
    • 0001252080 scopus 로고
    • -1) lies outside the working range of our X-band spectrometer. See
    • -1) lies outside the working range of our X-band spectrometer. See:, A. E. Douglas, W. E. Jones, Can. J. Phys. 1966, 44, 2251-2258.
    • (1966) Can. J. Phys. , vol.44 , pp. 2251-2258
    • Douglas, A.E.1    Jones, W.E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.