Stable, Two-Coordinate, Open Shell (d°-d9) Transition Metal Complexes

Comments on Inorganic Chemistry

Volumn 8, Issue 5, 1989, Pages 177-202

  Power, Philip P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

bonds; borylamides; metal alkoxides; metal amides; metal nitrogen; silylamides; steric crowding; three coordination; two coordination

Indexed keywords

EID: 84858640849     PISSN: 02603594     EISSN: 15489574     Source Type: Journal    
DOI: 10.1080/02603598908035794     Document Type: Article

References (77)

1. B. Nowitzki and R. Hoppe, Croat. Chem. Acta 57, 537 (1984); M. A. Hitchman, II. Stratemier and R. Hoppe, Inorg. Chem. 27, 2506 (1988).
2. G. Wilkinson, R. D. Gil and J. A. McCleverty (Eds.), Comprehensive Coordination Chemistry, Vol. 1 (Pergamon, Oxford, 1987).
3. P. G. Eller, D. C. Bradley, M. B. Hursthouse and D. W. Meek, Coord. Chem. Rcvs. 24, 1 (1977).
4. D. C. Bradley Adv. in Chem. Ser. ISO, 266 (1976); D. C. Bradley, Chem. Br. 11 393 (1975).
5. J. Tremmel, A. A. Ivanov, J. Schultz, I. Hargittai, S. J. Cyvin and A. Erikson. Chem. Phys. Lett. 23, 533 (1973);
6. I. Hargittai. J. Hargittai and J. Schultz, J. Mol. Struct. 26, 116 (1975);
7. E. Vajda, J. Tremmel and I. Hargittai, J. Mol. Struct. 44, 101 (1978);
8. M. Hargittai, I. Hargittai and J. Tremmel, Chen-L Phys. Lett. 83, 207 (1986);
9. M. Hargittai, O. V. Dorofeeva and J. Tremmel, Inorg. Chem. 24, 245 (1985);
10. M. Hargittai, O. V. Dorofeeva and J. Tremmel, Inorg. Chem. 24, 3963 (1985).
11. For example, C. W. De Kock and D. M. Gruen, J. Chem. Phys. 44, 437 (1966).
12. M. E. Jacox and D. E. Milligan, J. Chem. Phys. 51, 4143 (1969);
13. I. Berkowitz, D. G. Streets and A. Garritz, J. Chem. Phys. 70, 1305 (1970).
14. M. Hargittai and A. R. Rossi, Inorg. Chem. 24, 4758 (1985).
15. D. C. Bradley, R. C. Mehrotra and W. Wardlaw, J. Chem. Soc. 2027, 4204, 5020 (1952);
16. R. C. Mehrotra and J. Indian, Chem. Soc. 31. 904 (1954). See also D. C. Bradley, R. C. Mehrotra and D. P. Gaur, Metal Alkoxides (Aca-demic Press, New York, 1978); R. C:. Mehrotra, Adv. in Inorg. Chem Ra-diochem. 26, 269 (1983).
17. H. Bürger and U. Wannagat, Monatsh. 94, 1007 (1963).
18. H. Bürger and U. Wannagat, Monatsh. 95, 1099 (1964).
19. D. H. Harris and M. F. Lappert, J. Organomet. Chem. Libr. 2, 13 (1976).
20. E. C. Alyea, D. C. Bradley and R. G. Copperthwaite, J. Chem. Soc. Dalton. Trans. 1580(1972);
21. J. S. Ghotra, M. B. Hursthouse and A. J. Welch J. Chem. Soc. Chem. Commun. 669, (1973).
22. R. A. Andersen, D. H. Templeton and A. Zalkin, Inorg. Chem. 17, 2317 (1978);
23. T. D. Tilley, R. A. Andersen and A. Zalkin, lnorg. Chem. 23, 2271 (1984).
24. R. A. Andersen, J. Boncella and I. D. Tilley. unpublished results.
25. D. E. Goldberg, D. H. Harris, M. F. Lappert and K. M. Thomas, J. Chem. Soc. Chem. Commun. 261 (1976);
26. P. J. Davidson, D. H. Harris and M. F. Lappert, Lappert„I. Chem. Soc. Dalton. Trans. 2268 (1976);
27. G. K. Barker, M. F. Lappert and J. A. K. Howard, J. Chem. Soc. Dalton. Trans. 734 (1978);
28. P.B. Hitchcock, M. F. Lappert, R. G. Smith, R. A. Bartlett and P. P. Power, J. Chem. Soc. Chem. Commun. in press (1988).
29. M. Bochmann, G. Wilkinson, G. B. Young, M. B. Hursthouse and K. M. Malik, J. Chem. Soc. Dalton. Trans. 1863 (1980) idem, ibid901 (1980); M. Bochmann, G. Wilkinson and G. B. Young, ibid. 1879 (1980).
30. J. Hvoslef, H. Hope, B. D. Murray and P. P. Power, J. Chem. Soc. Chem. Commun. 1439 (1983);
31. T. V. Lubben, P. T. Wolczanski and G. D. Van Duyne, Organometallics 3, 977 (1984);
32. B. D. Murray and P. P. Power, J. Am. Chem. Soc. 166, 7011 (1984);
33. T. V. Lubben and P. T. Wolczanski, J. Am. Chem. Soc. 107, 701 (1985).
34. G. A. Sigel, R. A. Bartlett, D. Decker, M. M. Olmstead and P. P. Power, Inorg. Chem. 26, 1773 (1987).
35. R. E. La Pointe, P. T. Wolczanski and G. Van Duyne, Organometallics 4, 1810 (1985).
36. I. P. Rothwell, Acc. Chem. Res. 21, 153 (1988).
37. M. Yoshifuji, I. Shima and N. Inamoto, Tetrahedron Len. 3963 (1979).
38. M. A. Cook, C. Eaborn, A. E. Jukes and D. R. M. Walton, J. Organometallic Chem. 24, 4529 (1970);
39. C. Eaborn, J. Organometallic Chem. 299, 93 (1982).
40. D. C. Bradley and K. J. Fisher, J. Am. Chem. Soc. 93, 2058 (1971).
41. D. C. Bradley, M. B. Hursthouse, K. M. A. Malik and R. Moseler, Transition Met. Chem. (Weinheim, Ger.) 3, 253 (1978).
42. B. D. Murray and P. P. Power, Inorg. Chem. 23, 4584 (1984).
43. R. A. Bartlett, M. M. Olmstead, P. P. Power and S. Shoner, unpublished results. We thank Professor R. A. Andersen for a synthesis of Fe{N(SiMe3)2}2, see also Ref. 27. The structure of the Mn analogue of Fe(THF){N(SiMe3)2}2has been given in Ref. 3. See also Ref. 53 for further synthetic details.
44. H. Hope, M. M. Olmstead, B. D. Murray and P. P. Power, J. Am. Chem. Soc. 107, 712 (1985).
45. R. A. Andersen, K. Faegri, Jr., J. C. Green, A. Haaland, M. F. Lappert, W.-P. Leung and K. Rypdal, Inorg. Chem. 27, 1782 (1988).
46. A. Haaland, K. Hedberg and P. P. Power, Inorg. Chem. 23, 1972 (1984).
47. N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith and A. C. Sullivan, J. Chem. Soc. Chem. Commun. 1380 (1985).
48. R. A. Andersen, A. Haaland, K. Rypdal and H. V. Volden, J. Chem. Soc. Chem. Commun. 1807 (1985).
49. R. A. Andersen, A. Haaland, M. F. Lappert and co-workers, unpublished results.
50. M. F. Lappert, P. P. Power, A. R. Sanger and R. C. Srivastava Metal and Metalloid Amides (Ellis-Horwood, Chichester, 1980).
51. M. F. Lappert, D. S. Patil and J. B. Pedley, J. Chem. Soc. Chem. Commun. 830 (1975).
52. K. A. Andrianov, A. M. Kononov and N. N. Makanova, Zh. Obshch. Khim. 36, 895 (1986).
53. R. A. Bartlett, H. Chen and P. P. Power, unpublished results.
54. R. A. Bartlett and P. P. Power, J. Am. Chem. Soc. 109, 7563 (1987).
55. R. Dias and P. P. Power, unpublished results.
56. M. M. Olmstead, P. P. Power and G. Sigel, Inorg. Chem. 25, 1027 (1986).
57. J. C. Green, M. Payne, E. A. Seddon and R. A. Andersen, J. Chem. Soc. Dalton. Trans. 887 (1982);
58. M. F. Lappert, J. B. Pedley, G. J. Sharp and D. C. Bradley, J. Chem. Soc. Dalton. Trans. 1737 (1976).
59. D. C. Bradley, M. B. Hursthouse, C. W. Newing and A. J. Welch, J. Chem. Soc. Chem. Coinmun. 567 (1972).
60. E. C. Alyea, J. S. Basi, D. C. Bradley and M. H. Chisholm, J. Chem. Soc. Chetn. Commun. 4495 (1968). See also D. C. Bradley and M. H. Chisholm, Acc. Chcm. Res. 9, 273 (1976).
61. H. Fusstetter, G. Kopietz and H. Noth, Chem. Ber. 113, 728 (1980);
62. H. Nöth H. Prigge and A. Rotsch, Chem. Ber. 119, 1361 (1986).
63. H. Fusstetter and H. With Chem. Ber. 112, 3672 (1979);
64. H. Fusstetter and H. Noth, Chem. Ber. 113, 791 (1980).
65. J. W. Wilson, J. Organomet. Chem. 186 297 (1980);
66. N. M. D. Brown, F. Davidson and J. W. Wilson, J. Organomet. Chem. 185, 277 (1980);
67. A. Pelter, B. Singaram, L. Williams and J. W. Wilson, Tetrahedron Lett. 24, 623 (1983);
68. A. Pelter, G. Bradley and R. Roesser, Tetrahedron Lett. 26, 5097 (1985).
69. R. A. Bartlett, X. Feng, M. M. Olmstead, P. P. Power and K. J. Weese, J. Am. Chem. Soc. 109, 4851 (1987).
70. M. F. Lappert, M. J. Slade, A. Singh, J. L. Atw'ood, R. D. Rogers and R. Shakir, J. Am. Chem. Soc. 105, 302 (1983); L. M. Engelhardt, A. S. Max'. C. L. Raston and A. L. White, J. Chem. Soc. Dalton. Trans. 671 (1983).
71. R. A. Bartlett, H. Hope, P. P. Power and G. A. Sigel, unpublished results.
72. R. A. Bartlett, H. Chen and P. P. Power, Angew?. Chem. Int. Ed. Engl. (in press).
73. R. A. Bartlett, H. Chen, M. M. Olmstead and P. P. Power, unpublished results.
74. K. J. Weese, R. A. Bartlett, B. D. Murray, M. M. Olmstead and P. P. Power. Inorg. Chem. 26, 2049 (1987).
75. R. R. Schrock, Acc, Chem. Res. 11, 342 (1986);J. Organomet. Chem. 300 249 (1986).
76. R. Lingnau and J. Strahle, Angew. Chem. 100, 409 (1988).
77. Hetcrolcptic silylamide derivatives of both cobalC and manganese have already been reported: B. Horvath R. Mdseler and E. G. Horvath, Z. Anors. Al Chem. 450, 165 (1979).