Bioethanol and ethanol electro-oxidation by amorphous alloys with low amount of platinum

International Journal of Hydrogen Energy

Volumn 37, Issue 7, 2012, Pages 5649-5655

  Barroso, J ^a   Pierna, A R ^a   Blanco, T C ^a   Ruiz, N ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Amorphous alloys; Bioethanol; CO; Ethanol

Indexed keywords

AMORPHOUS CATALYSTS; ANODIC REACTIONS; BIO-ETHANOLS; CATALYTIC RESPONSE; CO CATALYSTS; CO STRIPPING; CO TOLERANCE; DIFFERENTIAL SCANNING CALORIMETRIES (DSC); ELECTRO-OXIDATION REACTION; ELECTROCHEMICAL TECHNIQUES; ETHANOL ELECTRO-OXIDATION; LIGAND EFFECT; ONSET POTENTIAL; PLATINUM ATOMS; SYNERGIC EFFECTS; VOLTAMMOGRAMS;

ADSORPTION; ALDEHYDES; ALLOYS; AMORPHOUS ALLOYS; BIOETHANOL; CATALYSTS; COBALT; CYCLIC VOLTAMMETRY; DIFFERENTIAL SCANNING CALORIMETRY; ETHANOL; FORMIC ACID; MECHANICAL ALLOYING; NIOBIUM; OXIDATION; PLATINUM; RUTHENIUM; RUTHENIUM ALLOYS; TIN; TIN ALLOYS; X RAY DIFFRACTION;

PLATINUM ALLOYS;

EID: 84858293643     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.12.166     Document Type: Article

References (33)

1. M. Gallo A fuel surcharge policy for reducing road traffic greenhouse gas emissions Trans Policy 18 2011 413 424
2. D.J. Wuebbles, and A.K. Jain Concerns about climate change and the role of fossil fuel use Fuel Process Technol 71 2001 99 119
3. A. Le Valant, F. Can, N. Bion, D. Duprez, and F. Epron Hydrogen production from raw bioethanol steam reforming: optimization of catalyst composition with improved stability against various impurities Int J Hydrogen Energy 35 2010 5015 5020
4. J.A. Francesconi, M.C. Mussati, and P.A. Aguirre Effects of PEMFC operating parameters on the performance of an integrated ethanol processor Int J Hydrogen Energy 35 2010 5940 5946
5. D. Hotza, and J.C. Diniz da Costa Fuel cells development and hydrogen production from renewable resources in Brazil Int J Hydrogen Energy 33 2008 4915 4935
6. N.Z. Muradov, and T.N. Veziroglu ''Green'' path from fossil-based to hydrogen economy: an overview of carbon-neutral technologies Int J Hydrogen Energy 33 2008 6804 6839
7. W.E. Mabee, and J.N. Saddler Bioethanol from lignocellulosics: status and perspectives in Canada Bioresour Technol 101 2010 4806 4813
8. M. Balat, H. Balat, and C. Öz Progress in bioethanol processing Prog Energy Combust Sci 34 2008 551 573
9. S. Rousseau, C. Coutanceau, C. Lamy, and J.M. Léger Direct ethanol fuel cell (DEFC): electrical performances and reaction products distribution under operating conditions with different platinum-based anodes J Power Sources 158 2006 8 24
10. F. Vigier, S. Rousseau, C. Coutanceau, J.M. Leger, and C. Lamy Electrocatalysis for the direct alcohol fuel cell Top Catal 40 2006 111 121
11. x alloys and their activation by HF solutions Surf Sci 410 1998 312 320
12. M. Sistiaga, and A.R. Pierna Application of amorphous materials for fuel cells J Non-Cryst Solids 329 2003 184 187
13. A.R. Pierna, M. Sistiaga, C. Navascués, and A. Lorenzo Electrochemical treatment of toxic compounds on the surface of amorphous Ni-Nb-Pt-Sn alloys J Non-Cryst Solids 287 2001 432 436
14. J. Barranco, and A.R. Pierna Kinetics of methanol electro-oxidation on Pt, Pt-Sn and Pt-Ru amorphous metallic alloys J New Mat Electrochem Syst 12 2009 76
15. x (Y = Sn, Ru; x = 0%, 0.4%) modified carbon paste electrodes and their role in the electrochemical methanol deprotonation and CO oxidation process J Non-Crystalline Solids 353 2007 851 854
16. J. Barranco, and A.R. Pierna Bifunctional amorphous alloys more tolerant to carbon monoxide J Power Sources 169 2007 71 76
17. L.G.S. Pereira, V.A. Paganin, and E.A. Ticianelli Investigation of the CO tolerance mechanism at several Pt-based bimetallic anode electrocatalysts in a PEM fuel cell Electrochim Acta 54 2009 1992 1998
18. P.P. Lopes, and E.A. Ticianelli The CO tolerance pathways on the Pt-Ru electrocatalytic system J Electroanal Chem 644 2 2010 110 116
19. C. Lamy, E.M. Belgsir, and J.M. Léger J Appl Electrochem 31 2001 799 809
20. F.C. Simões, D.M. dos Anjos, F. Vigier, J.M. Léger, F. Hahn, and C. Coutanceau Electroactivity of tin modified platinum electrodes for ethanol electrooxidation J Power Sources 167 2007 1 10
21. M. Watanabe, and S. Motoo Electrocatalysis by ad-atoms: part III. Enhancement of the oxidation of carbon monoxide on platinum by ruthenium ad-atoms J Electroanal Chem 60 1975 259 283
22. J. Barroso, A.R. Pierna, T.C. Blanco, E. Morallón, and F. Huerta Homolytic cleavage C-C bond in the electrooxidation of ethanol and bioethanol J Power Sources 196 2011 4193 4199
23. T.C. Blanco, A.R. Pierna, and J. Barroso Ethanol and CO electro-oxidation with amorphous alloys as electrodes J Power Sources 196 2011 4337 4341
24. J. Barroso, A.R. Pierna, T.C. Blanco, E. Morallón, and F. Huerta Acetic acid decarboxylation by amorphous alloys with low loading of platinum Int J Hydrogen Energy 36 2011 12574 12582
25. T.C. Blanco, A.R. Pierna, and J. Barroso Co-catalytic effect of Rh and Ru for the ethanol electro-oxidation in amorphous microparticulated alloys Phys Status Solidi C 8 2011 3187 3190
26. 0.2 alloys Phys Status Solidi A 208 2011 2309 2312
27. R. Gonzaléz-Huerta, I. Guerra-Martinez, J. Santiago Lopez, A.R. Pierna, and O. Solorza-Feria Amorphous metallic alloys for oxygen reduction reaction in a polymer electrolyte membrane fuel cell J New Mater Electrochem Systs 13 2010 171 176
28. F. Vigier, C. Coutanceau, F. Hahn, E.M. Belgsir, and C. Lamy On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies J Electroanal Chem 563 2004 81 89
29. A. Cuesta At least three contiguous atoms are necessary for CO formation during methanol electrooxidation on platinum J Am Chem Soc 128 2006 13332 13333
30. G. García, J.A. Silva-Chong, O. Guillén-Villafuerte, J.L. Rodríguez, E.R. González, and E. Pastor CO tolerant catalysts for PEM fuel cells spectroelectrochemical studies Catal Today 116 2006 415 421
31. T. Vidakovic, M. Christov, and K. Sundmacher The use of CO stripping for in situ fuel cell catalyst characterization Electrochim Acta 52 2007 5606 5613
32. G. Ertl, M. Newmann, and K.M. Strei Chemisorption of carbon monoxide on the platinum(111) surface Surf Sci 64 2 1977 393 410
33. J. Jiang, and A. Kucernak Electrooxidation of small organic molecules on mesoporous precious metal catalysts II: CO and methanol on platinum-ruthenium alloy J Electroanal Chem 543 2003 187 199