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Volumn 12, Issue 2, 2012, Pages 577-582

Structural rationalization of the phase transition behavior in a solid organic inclusion compound: Bromocyclohexane/thiourea

Author keywords

[No Author keywords available]

Indexed keywords

FIRST-ORDER PHASE TRANSITIONS; INCLUSION COMPOUNDS; LOW TEMPERATURE PHASE; MOLECULAR GEOMETRIES; ORGANIC INCLUSION; SINGLE-CRYSTAL AND POWDER; TRANSITION BEHAVIOR;

EID: 84858017746     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg201656y     Document Type: Article
Times cited : (16)

References (47)
  • 1
    • 0002833875 scopus 로고
    • Mandelcorn L. Ed.; Academic Press: New York
    • Fetterly, L. C. Non-Stoichiometric Compounds; Mandelcorn, L., Ed.; Academic Press: New York, 1964; p 491.
    • (1964) Non-Stoichiometric Compounds , pp. 491
    • Fetterly, L.C.1
  • 21
    • 0000288679 scopus 로고
    • The structural relationship between the periodicity (denoted ch) of the host structure along the tunnel and the periodicity (denoted cg) of the guest molecules along the tunnel is incommensurate if no small integers p and q satisfy the relationship pcg = qch. Thus, cg/ch is not equal to a rational number with a small denominator. In contrast, if small integers p and q satisfy the relationship pcg = qch, then the structure is commensurate and the host and guest substructures share a common periodicity cs = pcg = qch along the tunnel (if p > 1 and/or q > 1, then the common periodicity cs is typically called a "superstructure"). General aspects concerning the nature of incommensurate versus commensurate behavior in tunnel inclusion compounds are discussed in the following papers
    • The structural relationship between the periodicity (denoted ch) of the host structure along the tunnel and the periodicity (denoted cg) of the guest molecules along the tunnel is incommensurate if no small integers p and q satisfy the relationship pcg = qch. Thus, cg/ch is not equal to a rational number with a small denominator. In contrast, if small integers p and q satisfy the relationship pcg = qch, then the structure is commensurate and the host and guest substructures share a common periodicity cs = pcg = qch along the tunnel (if p > 1 and/or q > 1, then the common periodicity cs is typically called a "superstructure"). General aspects concerning the nature of incommensurate versus commensurate behavior in tunnel inclusion compounds are discussed in the following papers: Rennie, A. J. O.; Harris, K. D. M. Proc. R. Soc. A 1990, 430, 615.
    • (1990) Proc. R. Soc. A , vol.430 , pp. 615
    • Rennie, A.J.O.1    Harris, K.D.M.2
  • 46
    • 0344545210 scopus 로고
    • Los Alamos Laboratory Report No. LA-UR-86-748; Los Alamos National Laboratory: Los Alamos NM
    • Larson, A. C.; Von Dreele, R. B. GSAS; Los Alamos Laboratory Report No. LA-UR-86-748; Los Alamos National Laboratory: Los Alamos, NM, 1987.
    • (1987) GSAS
    • Larson, A.C.1    Von Dreele, R.B.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.