메뉴 건너뛰기




Volumn 335, Issue 6072, 2012, Pages 1075-1078

No straight path: Roaming in both ground- and excited-state photolytic channels of NO3→NO + 02

Author keywords

[No Author keywords available]

Indexed keywords

ION CHANNEL; NITRATE; NITROUS OXIDE;

EID: 84857672106     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1216911     Document Type: Article
Times cited : (111)

References (23)
  • 3
    • 38149133091 scopus 로고    scopus 로고
    • J. Mikosch et al., Science 319, 183 (2008).
    • (2008) Science , vol.319 , pp. 183
    • Mikosch, J.1
  • 5
    • 8444221247 scopus 로고    scopus 로고
    • D. Townsend et al., Science 306, 1158 (2004).
    • (2004) Science , vol.306 , pp. 1158
    • Townsend, D.1
  • 18
    • 2142803437 scopus 로고    scopus 로고
    • Materials and methods are detailed in the supporting online material at
    • Materials and methods are detailed in the supporting online material at Science Online.
    • Science Online
  • 19
    • 84922746033 scopus 로고    scopus 로고
    • note
    • Recent vector correlation measurements of the NO fragment show strong perpendicular correlations between the NO velocity and its rotation, consistent with in-plane dissociation.
  • 20
    • 84922741353 scopus 로고    scopus 로고
    • note
    • Although the predicted in-plane abstraction of the oxygen atom may at first seem at odds with the geometrically unconstrained abstraction observed in previous roaming systems, we contend that forces acting as the products separate are governed by the exit channel of the corresponding bimolecular abstraction reaction. Any constraints on the bimolecular reaction should therefore also apply to roaming and will vary for different molecular systems.
  • 23
    • 84922711159 scopus 로고    scopus 로고
    • note
    • The two translational distributions have been area normalized for comparison purposes. Absolute propensities are difficult to obtain from our experiment, but maximum propensity calculations necessitate that these normalizations are coincidently approximately correct.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.