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The base peak in all HRMS spectra represents the 1-azadiene, e.g., the product-CS2. This is most likely due to better ionizability of the 1-azadiene combined with the entropic benefit of the formal retro-hetero-Diels-Alder reaction under ESI conditions
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The base peak in all HRMS spectra represents the 1-azadiene, e.g., the product-CS2. This is most likely due to better ionizability of the 1-azadiene combined with the entropic benefit of the formal retro-hetero-Diels-Alder reaction under ESI conditions.
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