Reactive and Reversible Ionic Liquids for CO 2 Capture and Acid Gas Removal

Separation Science and Technology

Volumn 47, Issue 2, 2012, Pages 178-188

  Shannon, Matthew S ^a   Bara, Jason E ^a  

^a University of Alabama   (United States)

Author keywords

chemical process engineering; imidazole compounds; post combustion carbon dioxide capture; reactive and reversible ionic liquids; separations for energy applications

Indexed keywords

ACID GAS; ACID GAS REMOVAL; CHEMICAL PROCESS ENGINEERING; COMMERCIAL TECHNOLOGY; GAS SEPARATIONS; IMIDAZOLE COMPOUNDS; INDUSTRIAL PROCESSS; LOWER COST; NATURAL PRODUCTS; NON-VOLATILE; POST-COMBUSTION; PROCESS EQUIPMENTS;

CHEMICAL ENGINEERING; DESULFURIZATION; GASES; INDUSTRIAL RESEARCH; IONIC LIQUIDS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; PLANTS (BOTANY); PROCESS ENGINEERING; SEPARATION; SOLVENTS; SULFUR DIOXIDE;

CARBON DIOXIDE;

EID: 84856841013     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496395.2011.630055     Document Type: Review

References (50)

1. NETL DOE/NETL Advanced Carbon Dioxide Capture R&D Program: Technology Update 9/2010. www.netl.doe.gov/technologies/coalpower/ewr/pubs/CO2%20Capture%20Tech%20Update%20Final.pdf (Accessed 14 June 2011)
2. 2 capture. Science, 325: 1652-1654.
3. Astarita, G.;Savage, D.W.;Bisio, A. (1983) Gas Treating with Chemical Solvents. John Wiley and Sons: New Jersey.
4. Kidnay, A.J.;Parrish, W.R. 2006 Fundamentals of Natural Gas Processing;CRC Press: Taylor and Francis Group: Boca Raton, FL.
5. 2 in a 30-mass-percent monoethanolamine solution. Can. J. Chem. Eng., 73, 140-147.
6. Teng, T.T.;Maham, Y.;Hepler, L.G.;Mather, A.E. (1994) Viscosity of Aqueous-solutions of N-methyldiethanolamine and of diethanolamine. J. Chem. Eng. Data, 39, 290-293.
7. Vrachnos, A.;Kontogeorgis, G.;Voutsas, E. (2006) Thermodynamic modeling of acidic gas solubility in aqueous solutions of MEA, MDEA and MEA-MDEA blends. Ind. Eng. Chem. Res., 45, 5148-5154.
8. Weiland, R.H.;Dingman, J.C.;Cronin, D.B.;Browning, G.J. (1998) Density and viscosity of some partially carbonated aqueous alkanolamine solutions and their blends. J. Chem. Eng. Data, 43, 378-382.
9. Xu, S.;Wang, Y.-W.;Otto, F.D.;Mather, A.E. (1996) Kinetics of the reaction of carbon dioxide with 2-amino-2-methyl-1-propanol solutions. Chem. Eng. Sci., 51, 841-850.
10. 2 separations in imidazolium-based room-temperature ionic liquids. Ind. Eng. Chem. Res., 48, 2739-2751.
11. 2 solubility in ionic liquids. J. Phys. Chem. B, 110, 15059-15062.
12. Shiflett, M.B.;Drew, D.W.;Cantini, R.A.;Yokozeki, A. (2010) Carbon dioxide capture using ionic liquid 1-butyl-3-methylimidazolium Acetate. Energy Fuels, 24, 5781-5789.
13. Shiflett, M.B.;Yokozeki, A. (2010) Chemical absorption of sulfur dioxide in room-temperature ionic liquids. Ind. Eng. Chem. Res., 49, 1370-1377.
14. 2 capture and natural gas sweetening. Energy Fuels, 24: 5817-5828.
15. Holbrey, J.D.;Rogers, R.D.;Mantz, R.A.;Trulove, P.C.;Cocalia, V.A.;Visser, A.E.;Anderson, J.L.;Anthony, J.L.;lsur, J.F.;Maginn, E.J.;Welton, T. (2008) Physicochemical properties. In onic liquids in synthesis, 2nd ed.;Wasserscheid, P.;Welton, T., Eds. Wiley-VCH: Weinheim, Germany.
16. Gardas, R.L.;Coutinho, J.A. P. (2008) A group contribution method for viscosity estimation of ionic liqids. Fluid Phase Equilibr., 266: 195-201.
17. 2. Ind. Eng. Chem. Res., 47, 8496-8498.
18. 2 capture. Acc. Chem. Res., 43, 152-159.
19. 2 capture by a task-specific ionic liquid. J. Am. Chem. Soc., 124, 926-927.
20. 2 from molecular simulation. J. Am. Chem. Soc., 130, 14690-14704.
21. Shiflett, M.B.; Kasprzak, D.J.; Junk, C.P.; Yokozeki, A. (2008) Phase behavior of {carbon dioxide plus bmim Ac} mixtures. J. Chem. Thermodyn.40, 25-31.
22. 2 on acetate and trifluoroacetate imidazolium based ionic liquids at high pressures. J. Phys. Chem. B, 113, 6803-6812.
23. 2 capture. Chemsuschem, 3, 913-918.
24. Freeman, S.A.; Dugas, R.; Van Wagener, D.H.; Nguyen, T.; Rochelle, G.T. (2010) Carbon dioxide capture with concentrated, aqueous piperazine. Int. J. Greenh. Gas Con., 4, 119-124.
25. 2 capture and comparisons to imidazolium-based ionic liquids. Ind. Eng. Chem. Res., 50, 8665-8677.
26. NIST, Ionic Liquids Database (ILThermo)-NIST Standard Reference Database #147. http://ilthermo.boulder.nist.gov/ILThermo/mainmenu.uix (Accessed 14 June 2011).
27. McCabe, W.L.; Smith, J.C.; Harriott, P. (2001) Unit Operations of Chemical Engineering, 6th ed.; McGraw-Hill: New York.
28. Ohno, H.; Fukumoto, K. Amino acid ionic liquids. Acc. Chem. Res.2007, 40, 1122-1129.
29. Fukumoto, K.; Yoshizawa, M.; Ohno, H. (2005) Room temperature ionic liquids from 20 natural amino acids. J. Am. Chem. Soc., 127, 2398-2399.
30. 2 absorption by anion-functionalized ionic liquids. J. Am. Chem. Soc., 132, 2116-2117.
31. Goodrich, B.F.; de la Fuente, J.C.; Gurkan, B.E.; Zadigian, D.J.; Price, E.A.; Huang, Y.; Brennecke, J.F. (2010) Experimental measurements of amine-functionalized anion-tethered ionic liquids with carbon dioxide. Ind. Eng. Chem. Res., 50, 111-118.
32. 2 capture. Angew. Chem. Int. Edit., 50, 4918-4922.
33. 2 capture. J. Phys. Chem. Lett., 1, 3494-3499.
34. McGuinness, D.S.; Cavell, K.J.; Yates, B.F.; Skelton, B.W.; White, A.H. (2001) Oxidative addition of the imidazolium cation to zerovalent Ni, Pd, and Pt: a combined density functional and experimental study. J. Am. Chem. Soc., 123, 8317-8328.
35. 2 capture by imidazolium-based ionic liquids and superbase systems. Green Chem., 12, 2019-2023.
36. Wang, C.M.; Luo, H.M.; Jiang, D.E.; Li, H.R.; Dai, S. (2010) Carbon dioxide capture by superbase-derived protic ionic liquids. Angew. Chem. Int. Edit., 49, 5978-5981.
37. Blasucci, V.; Hart, R.; Mestre, V.L.; Hahne, D.J.; Burlager, M.; Huttenhower, H.; Thio, B.J. R.; Pollet, P.; Liotta, C.L.; Eckert, C.A. (2010) Single component, reversible ionic liquids for energy applications. Fuel, 89, 1315-1319.
38. Blasucci, V.; Dilek, C.; Huttenhower, H.; John, E.; Llopis-Mestre, V.; Pollet, P.; Eckert, C.A.; Liotta, C.L. (2009) One-component, switchable ionic liquids derived from siloxylated amines. Chem. Commun., 116-118.
39. Blasucci, V.M.; Hart, R.; Pollet, P.; Liotta, C.L.; Eckert, C.A. (2010) Reversible ionic liquids designed for facile separations. Fluid Phase Equilibr., 294, 1-6.
40. Hart, R.; Pollet, P.; Hahne, D.J.; John, E.; Llopis-Mestre, V.; Blasucci, V.; Huttenhower, H.; Leitner, W.; Eckert, C.A.; Liotta, C.L. (2010) Benign coupling of reactions and separations with reversible ionic liquids. Tetrahedron, 66, 1082-1090.
41. 2 capture reagents with pressure-swing regeneration. Energ. Environ. Sci., 4, 480-484.
42. 2 -binding organic liquids, an integrated acid gas capture system. Energy Procedia, 4, 216-223.
43. Koech, P.K.; Rainbolt, J.E.; Bearden, M.D.; Zheng, F.; Heldebrant, D.J. (2011) Chemically selective gas sweetening without thermal-swing regeneration. Energ. Environ. Sci., 4, 1385-1390.
44. Jessop, P.G.; Heldebrant, D.J.; Li, X.; Eckert, C.A.; Liotta, C.L. (2005) Green chemistry: Reversible nonpolar-to-polar solvent. Nature, 436, 1102.
45. Yamada, T.; Lukac, P.J.; George, M.; Weiss, R.G. (2007) Reversible, room-temperature ionic liquids. Amidinium carbamates derived from amidines and aliphatic primary amines with carbon dioxide. Chem. Mater., 19, 967-969.
46. Yamada, T.; Lukac, P.J.; Yu, T.; Weiss, R.G. Reversible, room-temperature, chiral ionic liquids. Amidinium carbamates derived from amidines and amino-acid esters with carbon dioxide. Chem. Mater.2007, 19, 4761-4768.
47. Yu, T.; Yamada, T.; Gaviola, G.C.; Weiss, R.G. (2008) Carbon dioxide and molecular nitrogen as switches between ionic and uncharged room-temperature liquids comprised of amidines and chiral amino alcohols. Chem. Mater., 20, 5337-5344.
48. 2 and amidine/amine mixtures. Chem. Mater., 22, 5492-5499.
49. Lenarcik, B.; Ojczenasz, P. (2002) The influence of the size and position of the alkyl groups in alkylimidazole molecules on their acid-base properties. J. Heterocyclic Chem., 39, 287-290.
50. Palleros, D. Heterocycles. www.chemistry.ucsc.edu/courses/palleros/Heterocycles.pdf (Accessed 31 May 2011)