Process parameter impacts on adiponitrile current efficiency and cell voltage of an electromembrane reactor using emulsion-type catholyte

Chemical Engineering Journal

Volumn 183, Issue , 2012, Pages 402-407

  Karimi, F ^a   Ashrafizadeh, S N ^a   Mohammadi, F ^b  

^a IRAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Iran)

^b IRAN POLYMER AND PETROCHEMICAL INSTITUTE   (Iran)

Author keywords

Adiponitrile; Electrohydrodimerizaion; Electrosynthesis; Emulsion type catholyte

Indexed keywords

ADIPONITRILE; CELL TEMPERATURE; CELL VOLTAGES; CURRENT EFFICIENCY; ELECTROCHEMICAL REACTOR; ELECTROCHEMICAL SYSTEMS; ELECTROHYDRODIMERIZAION; ELECTROSYNTHESIS; EMULSION-TYPE CATHOLYTE; LABORATORY SCALE; LEAD ELECTRODES; MEMBRANE REACTOR; OPERATING PARAMETERS; P-VALUES; PROCESS PARAMETERS; SUPPORTING ELECTROLYTE; TETRAMETHYLAMMONIUM CHLORIDE;

AMMONIUM COMPOUNDS; BIOREACTORS; CELLS; CHLORINE COMPOUNDS; CURRENT DENSITY; ELECTRIC REACTORS; EMULSIFICATION; FLOW RATE; TAGUCHI METHODS;

ELECTROCHEMICAL ELECTRODES;

TETRA;

EID: 84856515010     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.12.031     Document Type: Article

References (31)

1. (2010). http://www.icis.com/.
2. I.L. Knunyants, N.S. Wjasankin, Report on the 4th Electrom. Congress Moscow, Nauka Moscow (1959) 227.
3. Baizer M.M. Electrolytic reductive coupling. J. Electrochem. Soc. 1964, 111:215.
4. Baizer M.M., Danley D.E. Discovery, develompent and commercialization of the electrochemical adiponitrile process. Chem. Ind. 1979, 435-445.
5. Danly D.E. Development and commercialization of the monsanto electrochemical adiponitrile process. J. Electrochem. Soc. 1984, 13:435C-442C.
6. M. Seko, K. Mihara, Adiponitrile production by the electrolytic hydrodimerization of acrylonitrile, Asahi, US Patent no. 3595764 (1971).
7. HMD by Electrolytic dimerization of acrylonitrile SRI Reports (2009).
8. Scott K., Hayati B. The influence of mass transfer on the electrochemical synthesis of adiponitrile. Chem. Eng. Process. 1993, 32:253-260.
9. K. Mirhara, M. Seko, Electrolytic method of manufacturing hydrodimer of acrylonitrile, Asahi, US Patent no. 3497429 (1970).
10. W.J. Sloan, Electrolytic reduction of adiponitrile, Dupont, US Patent no. 3488267 (1970).
11. Beck F. Electrosynthesis of adiponitrile in undivided cell. J. Appl. Electrochem. 1972, 2:59-69.
12. Kinlen P.J. Mechanistic studies of the electrohydrodimerization of acrylonitrile. J. Electroanal. Chem. 1991, 304:133-151.
13. Piccardi G. Mechanism of electrohydrodimerization of acrylonitrile on mercury from aqueous solutions. J. Electroanal. Chem. 1984, 164:145-166.
14. Costentin C., Saveant J.M. Dimerization of electrochemically generated ion radicals: mechanisms and reactivity factors. J. Electroanal. Chem. 2004, 564:99.
15. Scott K., Hayati B., Hanies A.N., McConvey F. A reaction model for the electrochemical synthesis of adiponitrile. Chem. Eng. Technol. 1990, 13:376-383.
16. Karimi F., Mohammadi F., Ashrafizadeh S.N. An experimental study on the competing cathodic reactions in electro-hydro-dimerization of acrylonitrile to adiponitrile. J. Electrochem. Soc. 2011, 158:E129-E135.
17. Pavia D.L., Kriz G.M.L.G. Introduction to Spectroscopy: A Guide for Students of Organic Chemistry 1996, Saunders Golden Sunburst Series. second ed.
18. + separation from wastewater using electrodialysis. Desalination 2004, 167:379-385.
19. Taguchi G. Introduction to Quality Engineering 1990, McGraw-Hill, New York, USA.
20. Mohammadi T., Moheb A., Sadrzadeh M., Razmi A. Separation of copper ions by electrodialysis using taguchi experimental design. Desalination 2004, 169:21-31.
21. Beck F. Cathodic dimerization. Angew. Chem. Int. Ed. 1972, 11:760-781.
22. Couper A.M. Electrode material for electrosynthesis. Chem. Rev. 1990, 90:837-865.
23. x/Ti binary oxide eectrodes in a sulfuric acid solution. Electrochem. Commun. 2008, 10:668-672.
24. 2 evolution with low Ir content. J. Phys. Chem. 2001, 105:4623-4628.
25. F. Karimi, Synthesis of adiponitrile in membrane electrochemical Cell, MSc Thesis, Department of Chemical Engineering, Iran University of Science and Technology, Tehran, Iran (2011).
26. Danly D.E. The electrochemical route to adiponitrile 2. ChemTech 1980, 302-311.
27. M. Seko, Electrolytic cell for producind adiponitrile by electrolytic hydrodimerization of acrylonitrile, Asahi, US Patent no. 3657099 (1970).
28. Scott K., Hayati B. The multiphase electrochemical synthesis of adiponitrile. Chem. Eng. Sci. 1990, 45:2341-2347.
29. Tae B.S., Lee J., Park Y.W. A study on synthesis of adiponitrile by electrohydrodimerization. J. Korean Ind. Eng. Chem. 1995, 6:834-841.
30. Mohammadi F., Ashrafizadeh S.N., Sattari A. Aqueous HCL electrolysis utilizing an oxygen reducing cathode. Chem. Eng. J 2009, 155:757-762.
31. M.M. Baizer, S. Louis, Mo. Charles, R. Champbell, Adiponitrile Process, Monsanto, Us Patent no. 333647 (1965).