Di-(2-ethylhexyl) dithiophosphoric acid surface protected gold nanoparticles: Micellar synthesis, stabilization, isolation, and properties

Gold Bulletin

Volumn 44, Issue 4, 2011, Pages 207-215

  Tatarchuk, Vladimir V ^a   Sergievskaya, Anastasiya P ^a   Bulavchenko, Alexander I ^a   Zaikovsky, Vladimir I ^b   Druzhinina, Irina A ^a   Korda, Tamara M ^a   Gevko, Pavel N ^a   Alexeyev, Alexey V ^a  

^a NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

^b BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

Author keywords

Di (2 ethylhexyl) dithiophosphoric acid; Gold nanoparticles; Reverse micelles; Triton N 42 surfactant

Indexed keywords

ATOMIC FORCE MICROSCOPY; FIBER OPTIC SENSORS; GOLD COMPOUNDS; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; LIGHT SCATTERING; METAL NANOPARTICLES; MICELLES; MICROCRYSTALS; MOLAR RATIO; PARTICLE SIZE ANALYSIS; POWDERS; SODIUM CHLORIDE; SOLS; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL); ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY POWDER DIFFRACTION;

COLLOIDAL SOLUTIONS; DI(2-ETHYLHEXYL)DITHIOPHOSPHORIC ACID; HYDROPHOBIC POWDER; NARROW SIZE DISTRIBUTIONS; POLAR ORGANIC SOLVENTS; REVERSE MICELLES; THERMO-GRAVIMETRIC; UV-VIS SPECTROSCOPY;

GOLD NANOPARTICLES;

EID: 84856341312     PISSN: 00171557     EISSN: None     Source Type: Journal    
DOI: 10.1007/s13404-011-0031-8     Document Type: Article

References (47)

1. Schmid G (2004) Nanoparticles: from theory to application. Wiley-VCH, Weinheim
2. Grisel R, Weststrate K-J, Gluhoi A, Nieuwenhuys BE (2002) Catalysis by gold nanoparticles. Gold Bulletin 35(2):39-45
3. Bretschneider JC, Reismann M, Plessen GV, Simon U (2009) Photothermal control of the activity of HRP-functionalized gold nanoparticles. Small 22:2549-2553. doi:10.1002/smll.200900544
4. Ofir Y, Samanta B, Rotello VM (2008) Polymer and biopolymer mediated self-assembly of gold nanoparticles. Chem Soc Rev 37:1814-1825. doi:10.1039/B712689C
5. Boisselier E, Astruc D (2009) Gold nanoparticles in nanomedicine: preparations, imaging, diagnostics, therapies and toxicity. Chem Soc Rev 38(6):1759-1782. doi:10.1039/b806051g
6. Ji X, Song X, Li J, Bai Y, Yang W, Peng X (2007) Size control of gold nanocrystals in citrate reduction:the third role of citrate. J Am Chem Soc 129(45):13939-13948. doi:10.1021/ja074447k (Pubitemid 350106084)
7. Ojea-Jiménez I, Romero FM, Bastu's NG, Puntes V (2010) Small gold nanoparticles synthesized with sodium citrate and heavy water: insights into the reaction mechanism. J Phys Chem C 114:1800-1804. doi:10.1021/jp9091305
8. Rao CNR, Kulkarni GU, Thomas PJ, Agrawal VV, Saravanan P (2003) Films of metal nanocrystals formed at aqueous-organic interfaces. J Phys Chem B 107:7391-7395. doi:10.1021/jp0340111
9. Vitale F, Fratoddi I, Battocchio C, Piscopiello E, Tapfer L, Russo MV, Polzonetti G, Giannini C (2011) Mono- and bi-functional arenethiols as surfactants for gold nanoparticles: synthesis and characterization. Nanoscale Res Lett 6:103-111. doi:10.1186/1556-276X-6-103
10. Li Y, Zaluzhna O, Xu B, Gao Y, Modest JM, Tong YJ (2011) Mechanistic insights into the Brust-Schiffrin two-phase synthesis of organo-chalcogenate- protected metal nanoparticles. J Am Chem Soc 133:2092-2095. doi:10.1021/ ja1105078
11. Abecassis B, Testard F, Zemb T (2009) Gold nanoparticle synthesis in worm-like catanionic micelles: microstructure conservation and temperature induced recovery. Soft Matter 5:974-978. doi:10.1039/B816427D
12. Smetana AB, Wang JS, Boeckl J, Brown GJ, Wai CM (2007) Fine-tuning size of gold nanoparticles by cooling during reverse micelle synthesis. Langmuir 23(21):10429-10432. doi:10.1021/la701229q (Pubitemid 47623211)
13. Herrera AP, Resto O, Briano JG, Rinaldi C (2005) Synthesis and agglomeration of gold nanoparticles in reverse micelles. Nanotechnology 6:S618-S625. doi:10.1088/0957-4484/16/7/04 (Pubitemid 40878531)
14. Bulavchenko AI, Pletnev DN (2008) Electrophoretic concentration of nanoparticles of gold in reversed micellar solutions of AOT. J Phys Chem C 112:16365-16369. doi:10.1021/jp805268w
15. Chiang C-L, Hsu M-B, Lai L-B (2004) Control of nucleation and growth of gold nanoparticles in AOT/Span80/isooctane mixed reverse micelles. J Solid State Chem 177(11):3891-3895. doi:10.1016/j.jssc.2004.07.003
16. Tatarchuk VV, Bulavchenko AI (2004) Formation and coagulation kinetics of gold nanoparticles in AOT reverse micelles. Russ J Inorg Chem 49(8):1225-1337
17. Tatarchuk VV, Bulavchenko AI, Druzhinina IA (2006) Formal kinetics of growth of nanosized silver particles upon silver nitrate reduction with sodium citrate in a reverse micellar solution of AOT. Russ J Inorg Chem 51(11):1836-1839. doi:10.1134/S0036023606110222 (Pubitemid 44833255)
18. Tatarchuk VV, Bulavchenko AI, Druzhinina IA (2007) Dissolution kinetics of silver metal nanoparticles in their reaction with nitric acid in a reverse micelle solution of AOT. Russ J Inorg Chem 52(8):1284-1288. doi:10.1134/ S0036023607080207 (Pubitemid 47255704)
19. Tatarchuk VV, Bulavchenko AI, Druzhinina IA (2008) Kinetics of oxidative dissolution of gold nanoparticles in Triton N-42 reversed micelles. Russ J Inorg Chem 53(6):974-979. doi:10.1134/S0036023608060284
20. Tatarchuk VV, Bulavchenko AI, Druzhinina IA (2009) Kinetics of dissolution of silver nanoparticles inside Triton N-42 reversed micelles. Russ J Inorg Chem 54(10):1678-1683. doi:10.1134/S0036023609100295
21. Tatarchuk VV, Bulavchenko AI, Druzhinina IA, Sergievskaya AP (2011) Effect of dioctyl sulfide on the kinetics of oxidative dissolution of gold nanoparticles in Triton N-42 reverse micelles. Russ J Inorg Chem 56(5):808-815. doi :10.1134/S0036023611050251
22. Martin MN, Basham JI, Chando P, Eah S-K (2010) Charged gold nanoparticles in non-polar solvents: 10-min synthesis and 2D selfassembly. Langmuir 26(10):7410-7417. doi:10.1021/la100591h
23. Garg N, Mohanty A, Lazarus N, Schultz L, Rozzi TR, Santhanam S, Weiss L, Snyder JL, Fedder GK, Jin R (2010) Robust gold nanoparticles stabilized by trithiol for application in chemiresistive sensors. Nanotechnology 21:405501-405506. doi:10.1088/0957-4484/21/40/405501
24. Manea F, Bindoli C, Polizzi S, Lay L, Scrimin P (2008) Expeditious synthesis of water-soluble, monolayer-protected gold nanoparticles of controlled size and monolayer composition. Langmuir 24:4120-4124. doi:10.1021/la703558y (Pubitemid 351569018)
25. Zhang S, Leem G, Lee TR (2009) Monolayer-protected gold nanoparticles prepared using long-chain alkanethioacetates. Langmuir 25(24):13855-13860. doi:10.1021/la901847s
26. - by the reduction using aromatic amines. J Nanopart Res 7:209-217. doi:10.1007/s11051-005-0315-0 (Pubitemid 40925069)
27. Sardar R, Bjorge NS, Shumaker-Parry JS (2008) pH-Controlled assemblies of polymeric amine-stabilized gold nanoparticles. Macromolecules 41:4347-4352. doi:10.1021/ma800407s
28. Shem PM, Sardar R, Shumaker-Parry JS (2009) One-step synthesis of phosphine-stabilized gold nanoparticles using the mild reducing agent 9-BBN. Langmuir 25(23):13279-13283. doi:10.1021/la903003n
29. Alimarin IP, Rodionova TV, Ivanov VM (1989) Extraction with thio and dithio phosphorus acids. Russ Chem Rev 58:863. doi:10.1070/ RC1989v058n09ABEH003483
30. Balakireva NA, Novosel'tseva LA, Levin IS (1975) Extraction of gold by di(2-ethylhexyl)dithiophosphorous acid. Zh Anal Khim 30:684, in Russian
31. Tsimbalist VG, Anoshin GN, Mitkin VN, Razvorotneva LI, Golovanova NP (2000) Observations on new approaches for the determination of platinum-group elements, gold and silver in different geochemical samples from Siberia and the Far East. J Geostand Geoanalysis 24(2):171-182. doi:10.1111/j.1751-908X.2000. tb00769.x (Pubitemid 43892083)
32. Yukhin YM, Udalova TA, Tsimbalist VG (1985) Nonflame AAS determination of the noble metals with an extraction preconcentration by mixture of di-2-ethylhexyldithiophosphorous acid and n-oktylanyline. Zh Anal Khim 40:850-854 (in Russian)
33. Puddephatt RJ (1978) The chemistry of gold. Elsevier, Amsterdam
34. Zulauf M, Eicke HF (1979) Inverted micelles and microemulsions in the ternary system water/aerosol-OT/isooctane as studied by photon correlation spectroscopy. J Phys Chem 83(4):480-486. doi:10.1021/j100467a011
35. Bulavchenko AI, Batishcheva EK, Podlipskaya TY, Torgov VG (1998) Colloid-chemical interactions during the process of metal concentration by reverse micelles of ethoxylated surfactants: a geometrical approach. Colloid J Russian Acad Sci 60(2):152-160 (Pubitemid 128696358)
36. Schönfeld N (1967) Surface active ethylene oxide adducts. Pergamon Press, Oxford
37. Bulavchenko AI, Arymbaeva AT, Tatarchuk VV (2008) The kinetics of synthesis and mechanism of coagulation of gold nanoparticles in Triton N-42 reverse micelles. Russ J Phys Chem A 82(5):801-806. doi:10.1134/ S003602440805018X (Pubitemid 351671351)
38. Bulavchenko AI, Popovetsky PS (2010) The electrokinetic potential of nanoparticles in reverse AOT micelles: photometric determination and role in the processes of heterocoagulation, separation, and concentration. Langmuir 26(2):736-742. doi:10.1021/la903583r
39. Bulavchenko AI, Batishcheva EK, Torgov VG (1995) Metal concentration by reversed micelles. Sep Sci Technol 30(2):239-246
40. Bulavchenko AI, Tatarchuk VV, Bulavchenko OA, Arymbaeva AT (2005) Gold concentration by Triton N-42 reversed micelles. Russ J Inorg Chem 50(2):786-790 (Pubitemid 40795029)
41. Lazarides AA, Schatz GC (2000) DNA-linked metal nanosphere materials: structural basis for the optical properties. J Phys Chem B 104(3):460-467. doi:10.1021/jp992179+
42. Vorsina IA, Kolyshev AN, Eremeeva TP (1976) Vibrational spectra of di-2-ethilhehylditiophosphoric acid and spectral characteristics of the P=S bond. J Applied spectroscopy 21(1):926-930. doi:10.1007/BF00606491
43. Eremeeva TP, Vorsina IA (1976) Raman spectra of bis(2-ethylhexyl) hydrogen phosphorodithioate. Bull Acad Sci USSR Div Chem Sci 25(6):1224-1228. doi:10.1007/BF00928056
44. Cote G, Bauer D (1984) Hydrolysis of the O, O-dialkyl phosphorodithioic acids used as extractants in liquid-liquid systems. Anal Chem 56(12):2153-2157. doi:10.1021ac00276a040 (Pubitemid 14643009)
45. Tatarchuk VV, Sergievskaya AP, Druzhinina IA, Zaikovsky VI (2011) Kinetics and mechanism of the growth of gold nanoparticles by reduction of tetrachloroauric acid by hydrazine in Triton N-42 reverse micelles. J Nanopart Res. doi:10.1007/s11051-011-0481-1
46. Arcoleo V, Turco Liveri V (1996) AFM investigation of gold nanoparticles synthesized in water/AOT/n-heptane microemulsions. Chem Phys Lett 258:223-227. doi:10.1016/0009-2614(96)00669-0 (Pubitemid 126161008)
47. Teo BK, Sloane NJA (1985) Magic numbers in polygonal and polyhedral clusters. Inorg Chem 24(26):4545-4558. doi:10.1021/ic00220a025