An investigation of the kinetics and mechanism of Fischer-Tropsch synthesis on Fe-Co-Mn supported catalyst

Fuel Processing Technology

Volumn 96, Issue , 2012, Pages 150-159

  Arsalanfar, M ^a   Mirzaei, A A ^a   Atashi, H ^a   Bozorgzadeh, H R ^b   Vahid, S ^a   Zare, A ^a  

^a UNIVERSITY OF SISTAN AND BALUCHESTAN   (Iran)

^b RESEARCH INSTITUTE OF PETROLEUM INDUSTRY RIPI   (Iran)

Author keywords

Co precipitation; Fe Co Mn catalyst; Fischer Tropsch synthesis; Kinetic model

Indexed keywords

BRUNAUER-EMMETT-TELLER SURFACE AREAS; CATALYST CHARACTERIZATION; EXPERIMENTAL CONDITIONS; FEED RATIOS; FIXED BED MICRO-REACTOR; KINETIC EXPRESSION; KINETIC MODEL; KINETIC MODELS; KINETICS AND MECHANISM; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; NON-LINEAR REGRESSION METHOD; POWDER X RAY DIFFRACTION; RATE EQUATIONS; REACTION MECHANISM; REACTION PRESSURE; SPACE VELOCITIES; TEMPERATURE RANGE;

ACTIVATION ENERGY; CATALYSTS; FISCHER-TROPSCH SYNTHESIS; KINETIC THEORY; LINEAR REGRESSION; MANGANESE; PRECIPITATION (CHEMICAL); REACTION RATES; X RAY DIFFRACTION;

KINETICS;

EID: 84855883049     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2011.12.018     Document Type: Article

References (48)

1. 3Fischer-Tropsch catalyst Industrial and Engineering Chemistry Research 48 2009 10439 10447
2. Y. Liu, B.T. Teng, X.H. Guo, Y. Li, J. Chang, L. Tian, X. Hao, Y. Wang, H.Y. Xiang, Y.Y. Xu, and Y.W. Li Effect of reaction conditions on the catalytic performance of Fe-Mn catalyst for Fischer-Tropsch synthesis Journal of Molecular Catalysis A: Chemical 272 2007 182 190 (Pubitemid 46809604)
3. X. Li, M. Luo, and K. Asami Direct synthesis of middle iso-paraffins from synthesis gas on hybrid catalysts Catalysis Today 89 2004 439 446
4. 2 (CO) over supported iron catalysts Reaction Kinetics and Catalysis Letters 17 1981 373 378
5. J. Barrault, C. Forquy, and V. Perrichon Effects of manganese oxide and sulphate on olefin selectivity of iron supported catalysts in the Fischer-Tropsch reaction Applied Catalysis A: General 5 1983 119 125 (Pubitemid 13490627)
6. 2 Fischer-Tropsch catalysts: relationships between preparation method, molecular structure, and catalyst performance The Journal of Physical Chemistry. B 110 2006 8626 8639 (Pubitemid 43798569)
7. A.A. Mirzaei, M. Faizi, and R. Habibpour Effect of preparation conditions on the catalytic performance of cobalt manganese oxide catalysts for conversion of synthesis gas to light olefins Applied Catalysis A: General 306 2006 98 107 (Pubitemid 44262081)
8. Y. Yang, H.W. Xiang, R.L. Zhang, B. Zhang, and Y.W. Li A highly active and stable Fe-Mn catalyst for slurry Fischer-Tropsch synthesis Catalysis Today 106 2005 170 175
9. 2 Applied Catalysis A: General 284 2005 105 122
10. T. Herranz, S. Rojas, F.J. Perez-Alonso, M. Ojeda, P. Terreros, and J.L.G. Fierro Hydrogenation of carbon oxides over promoted Fe-Mn catalysts prepared by the microemulsion methodology Applied Catalysis A: General 311 2006 66 75 (Pubitemid 44224023)
11. C.H. Zhang, Y. Yang, B.T. Teng, T.Z. Li, H.Y. Zheng, H.W. Xiang, and Y.W. Li Study of an iron-manganese Fischer-Tropsch synthesis catalyst promoted with copper Journal of Catalysis 237 2006 405 415 (Pubitemid 43052905)
12. A. Tavasoli, M. Trepanier, R.M.M. Abbaslou, A.K. Dalai, and N. Abatzoglou Fischer-Tropsch synthesis on mono- and bimetallic Co and Fe catalysts supported on carbon nanotubes Fuel Processing Technology 90 2009 1486 1494
13. A.A. Mirzaei, R. Habibpour, M. Faizi, and E. Kashi Characterization of iron-cobalt oxide catalysts: effect of different supports and promoters upon the structure and morphology of precursors and catalysts Applied Catalysis A: General 301 2006 272 283 (Pubitemid 43199584)
14. 2 catalysts Catalysis Letters 104 2005 129 133 (Pubitemid 41456191)
15. 2 bimetallic catalysts for the Fischer-Tropsch reaction: part 3: the effect of Fe:Co ratio, mixing and loading on FT product selectivity Applied Catalysis A: General 289 2005 231 239
16. A.A. Mirzaei, R. Habibpour, and E. Kashi Preparation and optimization of mixed iron cobalt oxide catalysts for conversion of synthesis gas to light olefins Applied Catalysis A: General 296 2005 222 231
17. V.A. Peña O'Shea, M.C. Álvarez-Galvána, J.M. Campos-Martín, and J.L.G. Fierro Fischer-Tropsch synthesis on mono- and bimetallic Co and Fe catalysts in fixed-bed and slurry reactors Applied Catalysis A: General 326 2007 65 73 (Pubitemid 46818956)
18. 2 catalysts Fuel 90 2011 756 765
19. M.J. Keyser, R.C. Everson, and R.L. Espinoza Fischer-Tropsch kinetic studies with cobalt-manganese oxide catalysts Industrial and Engineering Chemistry Research 39 2000 48 54 (Pubitemid 30048738)
20. G.P. Van der Laan, and A.A.C.M. Beenackers Intrinsic kinetics of the gas-solid Fischer-Tropsch and water gas shift reactions over a precipitated iron catalyst Applied Catalysis A: General 193 2000 39 53
21. 2/CO mixtures over the group VIII metals: II. The kinetics of the methanation reaction over supported metals Journal of Catalysis 37 1975 462 473
22. E. Van Steen, and H. Schulz Polymerisation kinetics of the Fischer-Tropsch CO hydrogenation using iron and cobalt based catalysts Applied Catalysis A: General 186 1999 309 320 (Pubitemid 129532968)
23. H. Atashi, F. Siami, A.A. Mirzaei, and M. Sarkari Kinetic study of Fischer-Tropsch process on titania-supported cobalt-manganese catalyst Journal of Industrial and Engineering Chemistry 16 2010 952 961
24. M.J. Keyser, R.C. Everson, and R.L. Espinoza Fischer-Tropsch studies with cobalt-manganese oxide catalysts: synthesis performance in a fixed bed reactor Applied Catalysis A: General 171 1998 99 107 (Pubitemid 128414149)
25. B.-T. Teng, C.-H. Zhang, J. Yang, D.-B. Cao, J. Chang, H.-W. Xiang, and Y.-W. Li Oxygenate kinetics in Fischer-Tropsch synthesis overran industrial Fe-Mn catalyst Fuel 84 2005 791 800
26. A. Nakhaei Pure, M.R. Housaindokht, S.F. Tayyari, and J. Zarkesh Kinetics of water-gas shift reaction in Fischer-Tropsch synthesis over a nano-structured iron catalyst Journal of Natural Gas Chemistry 19 2010 362 368
27. Y.-N. Wang, W.-P. Ma, Y.-J. Lu, J. Yang, Y.-Y. Xu, H.-W. Xiang, Y.-W. Li, Y.-L. Zhao, and B.-J. Zhang Kinetics modeling of Fischer-Tropsch synthesis over an industrial Fe-Cu-K catalyst Fuel 82 2003 195 213
28. B.-T. Teng, J. Chang, J. Yang, G. Wang, C.-H. Zhag, Y.-Y. Xu, H.-W. Xiang, and Y.-W. Li Water gas shift reaction kinetics in Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst Fuel 84 2005 917 926
29. X.H. Guo, Y. Liu, J. Chang, L. Bia, Y.Y. Xu, H.W. Xiang, and Y.W. Li Isothermal kinetics modelling of the Fischer-Tropsch synthesis over the spray-dried Fe-Cu-K catalyst Journal of Natural Gas Chemistry 15 2006 105 114 (Pubitemid 44089188)
30. G.P. Van der Laan, and A.A.C.M. Beenackers Kinetics and selectivity of the Fischer-Tropsch synthesis: a literature review Catalysis Reviews - Science and Engineering 41 1999 255 318 (Pubitemid 129605307)
31. X. An, B. Wu, W. Hou, H. Wan, Z. Tao, T. Li, Z. Zhang, H. Xiang, Y. Li, B. Xu, and F. Yi The negative effect of residual sodium on iron-based catalyst for Fischer-Tropsch synthesis Journal of Molecular Catalysis A: Chemical 263 2007 266 272 (Pubitemid 46186140)
32. R.C. Everson, H. Mulder, and M.J. Keyser The Fischer-Tropsch reaction with supported ruthenium catalysts: modelling and evaluation of the reaction rate equation for a fixed bed reactor Applied Catalysis A: General 142 1996 223 241 (Pubitemid 126387551)
33. G.F. Forment, and K.B. Bischoff Chemical Reactor Analysis and Design 2nd ed. 1990 Wiley New York
34. R.F. Blanks Fischer-Tropsch synthesis gas conversion reactor Chemical Engineering Science 47 1992 959 966
35. D.E. Mears The role of liquid holdup and effective wetting in the performance of trickle-bed reactors ACS Monographs 133 1974 218 228
36. M. Mollavali, F. Yaripour, H. Atashi, and S. Sahebdelfar Intrinsic kinetics study of dimethyl ether synthesis from methanol Industrial and Engineering Chemistry Research 47 2008 3265 3273
37. J. Yang, Y. Liu, J. Chang, Y.N. Wang, L. Bai, Y.Y. Xu, H.W. Xiang, Y.W. Li, and B. Zhang Detailed kinetics of Fischer-Tropsch synthesis on an industrial Fe-Mn catalyst Industrial and Engineering Chemistry Research 42 2003 5066 5090 (Pubitemid 37266416)
38. 3 catalysts Chemical Engineering Science 62 2007 5338 5343 (Pubitemid 47268354)
39. B.H. Davis Fischer-Tropsch synthesis: current mechanism and futuristic needs Fuel Processing Technology 71 2001 157 166
40. P.M. Maitlis A new view of the Fischer-Tropsch polymerization reaction Pure and Applied Chemistry 61 1989 1747 1754
41. H.H. Storch, N. Golumbic, and R.B. Aderson The Fischer-Tropsch and Related Synthesis 1951 Wily New York
42. R.C. Brady, and R. Pettit Reaction of diazomethane on transition-metal surfaces and their relationship to the mechanism of the Fischer-Tropsch reaction Journal of the American Chemical Society 102 1980 6181 6182
43. 3 catalyst in slurry phase reactor Fuel Processing Technology 90 2009 1305 1313
44. 2 catalyst in slurry phase reactor Chemical Engineering Science 62 2007 4983 4991 (Pubitemid 47268339)
45. A.Y. Khodakov, W. Chu, and P. Fongarland Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels Chemical Reviews 107 2007 1692 1744 (Pubitemid 46876278)
46. F.M. Dautzenberg, J.N. Helle, R.A. Van Santen, and H. Verbeek Pulse-technique analysis of the kinetics of the Fischer-Tropsch reaction Journal of Catalysis 50 1977 8 14
47. H.B. Zhang, and G.L. Schrader Characterization of a fused iron catalyst for Fischer-Tropsch synthesis by in situ laser Raman spectroscopy Journal of Catalysis 95 1985 325 332
48. M.D. Shroff, D.S. Kalakkad, K.E. Coulter, S.D. Kohler, M.S. Harrington, N.B. Jackson, A.G. Sault, and A.K. Datye Activation of precipitated Iron Fischer-Tropsch synthesis catalysts Journal of Catalysis 156 1995 185 207