Synthesis of magnesium borohydride from its elements and usage in the hydrogen cycle

Energy Sources, Part A: Recovery, Utilization and Environmental Effects

Volumn 33, Issue 23, 2011, Pages 2157-2170

  Kaya, C ^a   Guru M ^a   Ar, I ^a  

^a GAZI UNIVERSITY   (Turkey)

Author keywords

Catalytic method; Dehydrogenation; Hydrogen storage; Magnesium borohydride; Solid phase reaction

Indexed keywords

BOROHYDRIDES; CATALYTIC METHOD; ELEMENTAL MAGNESIUM; HYDROGEN ABSORPTION; HYDROGEN DESORPTION; HYDROGEN EVALUATION; HYDROGEN STORAGE CAPACITIES; METAL HYDRIDES; SOLID PHASE REACTION; THERMAL METHODS;

BALL MILLING; BORON; BORON COMPOUNDS; DEHYDROGENATION; DESORPTION; HYDRIDES; HYDROGEN; MAGNESIUM; SYNTHESIS (CHEMICAL);

HYDROGEN STORAGE;

EID: 84855864801     PISSN: 15567036     EISSN: 15567230     Source Type: Journal    
DOI: 10.1080/15567030903030625     Document Type: Article

References (27)

1. Akyüz, Y., Biçer, A., and Gürü, M. 2007. Synthesis and processing of Al sheathedMgB2 by powder in tube method and determination of superconducting and mechanical properties. Mater. & Design 28:2500-2504. (Pubitemid 46958948)
2. Cahen, S., Eymery, J.-B., Janot, R., and Tarascon, J.-M. 2009. Improvement of the LiBH4 hydrogen desorption by inclusion into mesoporous carbons. J. Power Sources.DOI: 10.1016/j.jpowsour. 2009.01.002.
3. Çakanyildirim, Ç., and Gürü, M. 2008a. Hydrogen cycle with sodium borohydride. Int. J. Hydrogen Energy 33:4634-4639.
4. Çakanyildirim, Ç., and Gürü, M. 2008b. Processing of LiBH4 from its elements by ball milling method. Renew. Energy 33:2388-2392.
5. Çakanyildirim, Ç., and Gürü, M. 2009. Production of NaBH4 and hydrogen release with catalyst. Renew. Energy (in press).
6. x alloys. J. Alloys & Compounds 359:180-185.
7. 4 hydrolysis on Co-based nanocatalysts studied by differential reaction calorimetry. Int. J. Hydrogen Energy 34:1185-1199.
8. 2. Acta Crystallographica, Sect. B 63:561-568. (Pubitemid 47120535)
9. 2 phase from elements by mechanical milling. Physica C 391:211-216.
10. Hua, D., Hanxi, Y., Xinpin, A., and Chuansin, C. 2003. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. Int. J. HydrogenEnergy 28:1095-1100.
11. 4 by using high-energy ball milling. Int. J. Hydrogen Energy 34:1717-1725.
12. Jemni, A., Nasrallah, S. B., and Lamloumi, J. 1999. Experimental and theoretical study of a metalhydrogen reactor. Int. J. Hydrogen Energy 13:520-533.
13. Jiang, J. J., and Gasik, M. 2000. An electrochemical investigation of mechanical alloying of MgNibased hydrogen storage alloys. J. Power Sources 89:117-124.
14. 2Ni alloy. J. Electrochem. Soc. 143:L198-L199. (Pubitemid 126607976)
15. Li, Z. P., Liu, B. H., Arai, K., and Suda, S. 2005. Development of the direct borohydride fuel cell. J. Alloy. Compd. 404-406:648-652. (Pubitemid 41688695)
16. Liu, B. H., and Li, Z. P. 2009. A review: Hydrogen generation from borohydride hydrolysis reaction. J. Power Sources 187:527-534.
17. Matsurtaga, T., Buchter, F., Miwa, K., Towata, S., Orimo, S., and Züttel, A. 2008. Magnesium borohydride: A new hydrogen storage material. Renew. Energy 33:193-196. (Pubitemid 350180415)
18. 2 alloy. Int. J. Hydrogen Energy 31:867-876.
19. Reiser, A., Bogdanovic, B., and Schlite, K. 2000. The application of Mg-based metal-hydrides as heat energy storage systems. Int. J. Hydrogen Energy 25:425-430. (Pubitemid 30557267)
20. Sarner, S. F. 1966. Propellant Chemistry, 1st Edition. New York: Reinhold Publishing Co.
21. Sivakumar, R., Ramaprabhu, S., Ramo Rao, K. V. S., Anton, H., and Schmidt, P. C. 2000. Kinetics of hydrogen absorption and thermodynamics of dissolved hydrogen in Tb1-xZrxFe3 system. Int. J. Hydrogen Energy 25:453-472.
22. Schlesinger, H. I., Brown, H. C., Finholt, A. E., Gilbreath, J. R., Hoekstra, H. R., and Hyde, E. K. 1952. Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. In: Hydroboration. New York: W. C. Benjamin, Inc.
23. 2. Int. J. Hydrogen Energy 34:2144-2152. DOI: HE-D-08-00531R1.
24. 2. Int. J. Hydrogen Energ. 34:916-928.
25. Veziroǧlu, T. N. 2000. Quarter century of hydrogen movement 1974-2000. Int. J. Hydrogen Energy 25:1143-1150.
26. 2 in air at high temperature. Supercond. Sci. Tech. 16:576-581.
27. Zeng, K., Klassen, T., Oelerich, W., and Borman, R. 1999. Critical assessment and thermodynamic modelling of the Mg-H system. Int. J. Hydrogen Energy 42:989-1004.