Methanol oxidation reaction on PtSnO2 obtained by microwave-assisted chemical reduction

International Journal of Hydrogen Energy

Volumn 37, Issue 2, 2012, Pages 1752-1759

  Sandoval Gonzalez A ^a   Borja Arco, E ^a   Escalante, Jaime ^b   Jimenez Sandoval O ^c   Gamboa, S A ^a  

^a INSTITUTO DE ENERGÍAS RENOVABLES   (Mexico)

^b CENTRO DE INVESTIGACIÓN EN QUÍMICA APLICADA   (Mexico)

^c INSTITUTO POLITÉCNICO NACIONAL   (Mexico)

Author keywords

Direct methanol fuel cells; Electrocatalyst; Methanol oxidation; PtSnO 2 C

Indexed keywords

ACIDIC SOLUTIONS; ANODIC ACTIVE MATERIALS; AVERAGE PARTICLE SIZE; CHARGE TRANSFER COEFFICIENT; CHEMICAL REDUCTION; CHRONOAMPEROMETRIC STUDY; CO-EXISTENCE; ELECTROCHEMICAL CHARACTERISTICS; ELECTROCHEMICAL CHARACTERIZATIONS; METHANOL ELECTROOXIDATION; METHANOL OXIDATION; METHANOL OXIDATION REACTIONS; MICROWAVE ASSISTED SYNTHESIS; MICROWAVE-ASSISTED; ONSET POTENTIAL; POTENTIAL APPLICATIONS; PT-BASED ELECTROCATALYST; PTSNO 2/C; TAFEL SLOPES; TEM ANALYSIS; WELL-DISPERSED; XRD , TEM;

CHARGE TRANSFER; CYCLIC VOLTAMMETRY; DIRECT METHANOL FUEL CELLS (DMFC); ELECTROCATALYSTS; METHANOL FUELS; NANOPARTICLES; OXIDATION; PARTICLE SIZE ANALYSIS; PLATINUM; SYNTHESIS (CHEMICAL);

METHANOL;

EID: 84855691955     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.10.049     Document Type: Article

References (33)

1. S.S. Dipti, U.C. Chung, J.P. Kim, and W.S. Chung Different nanostructure cathode catalysts application for direct methanol fuel cell Phys Status Solidi A 204 12 2007 4174 4177
2. C. Jeyabharathi, P. Venkateshkumar, J. Mathiyarasu, and K.L.N. Phani Platinum-tin bimetallic nanoparticles for methanol tolerant oxygen-reduction activity Electrochim Acta 54 2008 448 454
3. J.L. Bronkema, and A.T. Bell Mechanistic studies of methanol oxidation to formaldehyde on isolated vanadate sites supported on high surface area zirconia J Phys Chem C 112 2008 6404 6412
4. R.K. Pandey, and V. Lakshminarayanan Electro-oxidation of formic acid, methanol, and ethanol on electrodeposited Pd-polyaniline nanofiber films in acidic and alkaline medium J Phys Chem C 113 2009 21596 21603
5. L.J. Gojkovic Snezana Mass transfer effect in electrochemical oxidation of methanol at platinum electrocatalysts J Electroanal Chem 573 2004 271 276
6. 2 by a photocatalyst with an energy storage ability Phys Chem Chem Phys 12 2010 5166 5170
7. S. Prakash, W. Mustain, and P.A. Kohl Carbon dioxide vent for direct methanol fuel cells J Power Sources 185 2008 392 400
8. 2 nanoparticles as a catalyst for methanol oxidation Fuel 89 2010 372 377
9. M. Carmo, M. Brandalise, A. Oliveira, E.V. Spinacé, A.D. Taylor, and M. Linardi Enhanced activity observed for sulfuric acid and chlorosulfuric acid functionalized carbon black as PtRu and PtSn electrocatalyst support for DMFC and DEFC applications International Journal of Hydrogen Energy 21 19 2011 1641 1646
10. 2 and PtRu nanoparticles for direct methanol fuel cells Mater Chem Phys 105 2007 222 228 (Pubitemid 47368741)
11. M. Sakthivel, A. Schlange, U. Kunz, and T. Turek Microwave assisted synthesis of surfactant stabilized platinum/carbon nanotube electrocatalysts for direct methanol fuel cell applications J Power Sources 195 2010 7083 7089
12. E. Antolini, T. Lopes, and E.R. Gonzalez An overview of platinum-based catalysts as methanol-resistant oxygen reduction materials for direct methanol fuel cells J Alloys Compd 461 2008 253 262 (Pubitemid 351778477)
13. W. Vogel Size contraction in Pt/C and PtRu/C commercial E-TEK electrocatalysts: an in Situ x-ray diffraction study J Phys Chem C 112 2008 13,475 13,482
14. J.W. Guo, T.S. Zhao, J. Prabhuram, R. Chen, and C.W. Wong Preparation and characterization of a PtRu/C nanocatalyst for direct methanol fuel cell Electrochim Acta 51 2005 754 763 (Pubitemid 41500066)
15. F. Colmati, W.H. Lizcano-Valbuena, G.A. Camara, E.A. Ticianelli, and E.R. Gonzalez Carbon monoxide oxidation on Pt-Ru electrocatalysts supported on high surface area carbon J Braz Chem Soc 13 2002 474 482
16. 2 as an assisting reagent J Phys Chem C 112 2008 12894 12898
17. Z. Liu, B. Guo, L. Hong, and T. Han Lim Microwave heated polyol synthesis of carbon-supported PtSn nanoparticles for methanol electrooxidation Electrochem Commun 8 2006 83 90 (Pubitemid 43008464)
18. D. Chen, and L. Gao Facile synthesis of single-crystal tin oxide nanorods with tunable dimensions via hydrothermal process Chem Phys Lett 398 2004 201 206
19. J.C. Slater Atomic radii in crystals J Chem Phys 41 10 1964 3199 3205
20. Y. Zhu, and C.R. Cabrera Methanol oxidation at the electrochemical codeposited Pt-Os composite electrode Electrochem Solid-State Lett 4 2001 A45 A48
21. P. Vanýsek Electrochemical series CRC Press LLC 2000
22. Z.P. Guo, D.M. Han, D. Wexler, R. Zeng, and H.K. Liu Polyoxometallates- stabilized platinum catalysts on multi-walled carbon nanotubos for fuel cell applications Electrochim Acta 53 2008 6410 6416
23. 2 nanorods J Electrochem Soc 153 2006 A1714 A1718
24. W. Sugimoto, T. Saida, and Y. Takasu Co-catalytic effect of nanostructured ruthenium oxide towards electro-oxidation of methanol and carbon monoxide Electrochem Commun 8 2006 411 415 (Pubitemid 43290468)
25. S. Hadzi-Jordanov, H. Angerstein-Kozlowska, M. Vukovic, and B.E. Conway Reversibility and growth behavior of surface oxide films at ruthenium electrodes J Electrochem Soc 125 1978 1471 1480 (Pubitemid 9386837)
26. D. Michell, D.A.J. Rand, and R. Woods A study of ruthenium electrodes by cyclic voltammetry and X-ray emission spectroscopy J Electroanal Chem Interfacial Electrochem 89 1978 11 27
27. V. Birss, R. Myers, H. Angerstein-Kozlowska, and B.E. Conway Electron microscopy study of formation of thick oxide films on Ir and Ru electrodes J Electrochem Soc 131 1984 1502 1510 (Pubitemid 14605335)
28. P. Piela, C. Eickes, E. Brosha, F. Garzon, and P. Zelenay Ruthenium crossover in direct methanol fuel cell with Pt-Ru black anode J Electrochem Soc 151 2004 A2053 A2059
29. P.J. Ferreira, R. Makharia, S. Kocha, H. Gasteiger, D. Morgan, and O.'G.J. La Instability of Pt/C Electrocatalysts in proton exchange membrane fuel cells: a mechanistic investigation J Electrochem Soc 152 2005 A2256 A2271
30. P. Yu, M. Pemberton, and P. Plasse PtCo/C cathode catalyst for improved durability in PEMFCs J Power Sources 144 2005 11 20
31. W.L. Holstein, and H.D. Rosenfeld In-situ X-ray absorption spectroscopy study of Pt and Ru chemistry during methanol electrooxidation J Phys Chem B 109 2005 2176 2186
32. - J Chem Phys 126 2007 204506
33. N.A. Tapan, W.E. Mustain, B. Gurau, G. Sandi, and J. Prakash Investigation of methanol oxidation electrokinetics on Pt using asymmetric electrode technique J New Mat Electrochem Syst 7 2004 281 286 (Pubitemid 46001036)