Titanium(IV)-promoted regioselective nucleophilic ring-opening reaction of chiral epoxyallyl alcohols with acids as a tool for ready access to chiral 1,2,3-triol monoesters: Application to stereoselective total synthesis of macrolides

Journal of Organic Chemistry

Volumn 77, Issue 1, 2012, Pages 674-679

  Radha Krishna, Palakodety ^a   Ramana, D Venkata ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

MACROLIDES; MONOESTERS; NATURAL PRODUCTS; NUCLEOPHILIC RING-OPENING REACTION; REGIO-SELECTIVE; RING OPENING REACTION; STEREO-SELECTIVE; STEREOSELECTIVE SYNTHESIS; SYNTHETIC UTILITY; TOTAL SYNTHESIS;

REGIOSELECTIVITY; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL); TITANIUM;

STEREOSELECTIVITY;

ACID; ALCOHOL DERIVATIVE; ANTIBIOTIC AGENT; ESTER DERIVATIVE; HERBARUMIN I; HERBARUMIN II; LETHALOXIN; MACROLIDE; NUCLEOPHILE; STAGONOLIDE A; TITANIUM; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHIRALITY; CRYSTAL STRUCTURE; DRUG SYNTHESIS; ENANTIOMER; EPOXIDATION; NUCLEOPHILICITY; PROTON NUCLEAR MAGNETIC RESONANCE; RING OPENING; STEREOCHEMISTRY;

ACIDS; EPOXY COMPOUNDS; ESTERS; MACROLIDES; MOLECULAR STRUCTURE; PROPANOLS; STEREOISOMERISM; TITANIUM;

EID: 84855543490     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo202199g     Document Type: Article

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