Li/MgO with spin sensors as catalyst for the oxidative coupling of methane

Catalysis Communications

Volumn 18, Issue , 2012, Pages 132-136

  Simon, U ^a   Arndt, S ^a   Otremba, T ^a   Schlingmann, T ^a   Gorke O ^a   Dinse, K P ^b   Schomacker R ^a   Schubert, H ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

Cation substitution; EPR; Li MgO; Oxidative coupling of methane; Spin sensor; Transition metal oxides

Indexed keywords

ALIOVALENT IONS; CATION SUBSTITUTIONS; CO-DOPING; EPR SPECTROSCOPY; OXIDATIVE COUPLING OF METHANE; TRANSITION METAL OXIDES;

CATALYSTS; GADOLINIUM; METHANE; PARAMAGNETIC RESONANCE; SENSORS; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

EID: 84855443561     PISSN: 15667367     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.catcom.2011.11.021     Document Type: Article

References (30)

1. S. Arndt. Stability of Lithium doped Magnesium Oxide and Zinc Oxide Catalysts for the Conversion of Natural Gas. PhD thesis, Technical University Berlin, 2010.
2. S. Arndt, U. Simon, S. Heitz, A. Berthold, B. Beck, O. Görke, J.D. Epping, T. Otremba, Y. Aksu, E. Irran, G. Laugel, M. Driess, H. Schubert, and R. Schomäcker Li-doped MgO From Different Preparative Routes For The Oxidative Coupling Of Methane Topics in Catalysis 53 2011 424 514
3. S. Arndt, G. Laugel, S. Levchenko, R. Horn, M. Baerns, M. Scheffler, R. Schlögl, and R. Schomäcker Li/MgO - The Drosophila Catalyst for Methane Oxidative Coupling. A Critical Assessment Catalysis Reviews - Science and Engineering 54 2011 1266 1285
4. A.G. Anderson, and T. Norby Liquid phases in Li:MgO as studied by thermoanalytical methods, electron microscopy, and electrical conductivity measurements Catalysis Today 6 1990 575 586 (Pubitemid 20687400)
5. F.P. Larkins, and M.R. Nordin The effects of transition metal oxides on the methane oxidative coupling activity of doped MgO catalysts I. Zinc and manganese Journal of Catalysis 130 1991 147 160
6. S.J. Korf, J.A. Roos, L.J. Veltman, J.G. van Ommen, and J.R.H. Ross Effect of additives on lithium doped magnesium oxide catalysts used in the oxidative coupling of methane Applied Catalysis 56 1989 119 135 (Pubitemid 20646066)
7. R. Mariscal, J. Soria, M.A. Pena, and J.L.G. Fierro Features of Li-Mn-MgO catalysts and their relevance in the oxidative coupling of methane Journal of Catalysis 147 1994 535 543
8. 2-hydrocarbons over lithium, manganese, cadmium and zinc promoted MgO catalysts I. Catalyst performance in presence of free oxygen Applied Catalysis 62 1990 171 187 (Pubitemid 20731949)
9. 2-hydrocarbons over Li, Mn, Cd and Zn promoted MgO catalysts II: performance of fresh and reoxidised catalysts in the absence of free oxygen Applied Catalysis 69 1991 187 200
10. T. Kanno, and M. Kobayashi The difference in the modification effects of Li on two MgO samples of higher and lower Mn contents Journal of Materials Science Letters 16 1997 126 127 (Pubitemid 127504255)
11. J.J. Zhang, X.G. Yang, Y.L. Bi, and K.J. Zhen Role of Li ion in Li-Mn-MgO catalyst for oxidative coupling of methane Catalysis Today 13 1992 555 558
12. F.P. Larkins, and M.R. Nordin Physico-chemical and catalytic properties of doped MgO catalysts Studies in Surface Science and Catalysis 81 1994 249 251
13. 2 additions on the behavior of Li/MgO and Li/Na/MgO catalysts for the oxidative coupling of methane Canadian Journal of Chemical Engineering 69 1991 883 890 (Pubitemid 21705125)
14. G.C. Hoogendam, K. Seshan, J.G. van Ommen, and J.R.H. Ross Oxidative coupling of methane over doped Li/MgO catalysts Catalysis Today 21 1994 333 340
15. S.J. Korf, J.A. Ross, J.A. Vreeman, J.W.H.C. Derksen, J.G. van Ommen, and J.R.H. Ross A study of the kinetics of the oxidative coupling of methane over a Li/Sn/MgO catalyst Catalysis Today 6 1990 417 426 (Pubitemid 20687381)
16. A.N.J. van Keulen, G.C. Hoogendam, K. Seshan, J.G. van Ommen, and J.R.H. Ross The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methane Journal of the Chemical Society, Chemical Communications 18 1992 1546 1547
17. R.H. Nibbelke, J. Scheerová, M.H.J.M. de Croon, and G.B. Marin The oxidative coupling of methane over MgO-based catalysts: a steady-state isotope transient kinetic analysis Journal of Catalysis 106 1995 106 119
18. E.P.J. Mallens, J.H.B.J. Hoebink, and G.B. Marin An investigation of the oxygen pathways in the oxidative coupling of methane over MgO-based catalysts Journal of Catalysis 160 1996 222 234
19. 2 addition to Li/MgO catalysts for the oxidative coupling of methane Journal of Catalysis 181 1999 160 164 (Pubitemid 129717097)
20. Y.L. Bi, K.J. Zheng, Y.T. Jiang, C.W. Teng, and X.G. Yang Catalytic oxidative coupling of methane over alkali, alkaline earth and rare earth metal oxides Applied Catalysis 39 1988 185 190
21. S. Bartsch, J. Falkowski, and H. Hoffmann Catalyst development for oxidative methane coupling Catalysis Today 4 1989 421 431
22. S. Bartsch, and H. Hoffmann Investigations on a Ce/Li/MgO-catalyst for the oxidative coupling of methane Catalysis Today 6 1990 527 534 (Pubitemid 20687394)
23. A. Santos, C. Finol, J. Coronas, M. Menéndez, and J. Santamaría Reactor engineering studies of methane oxidative coupling on a Li/MgO catalyst Studies in Surface Science and Catalysis 81 1994 171 176
24. A. Santos, M. Menéndez, and J. Santamaría Oxidative coupling of methane over Li/Sn/MgO catalysts. Use of a fluidized bed reactor at low gas velocities Studies in Surface Science and Catalysis 107 1997 373 378 (Pubitemid 127816581)
25. P.J. Gellings, and H.J.M. Bouwmeester Solid state aspects of oxidation catalysis Catalysis Today 58 2000 1 53
26. 3+ in MgO Journal of Chemical Physics 80 1984 574 575
27. 3+ in MgO single crystals Physical Review B 4 1971 2853 2857
28. O. Forlani, and S. Rossini Rare earths as catalysts for the oxidative coupling of methane to ethylene Materials Chemistry and Physics 31 1992 155 158
29. U. Zavyalova, M. Holena, R. Schlögl, and M. Baerns. Statistical Analysis of Past Catalytic Data on Oxidative Methane Coupling for New Insights into the Composition of High-Performance Catalysts. ChemCatChem, DOI. 10.1002/cctc.201100186.
30. M. Baerns, and J.R.H. Ross Perspectives in catalysis, chapter catalytic chemistry of methane conversion 1992 IUPAC International Union of Pure and Applied Chemistry 315 335