Chemical bond cleavage induced by electron heating Gas emission behavior of titanium-metalloid compounds (titanium nitride and oxide) in a microwave field

Materials Chemistry and Physics

Volumn 131, Issue 1-2, 2011, Pages 178-183

  Fukushima, Jun ^a   Kashimura, Keiichiro ^b   Sato, Motoyasu ^c  

^a NAGOYA UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

^c NATIONAL INSTITUTE FOR FUSION SCIENCE   (Japan)

Author keywords

Density of electron; Microwave H field; Titanium nitrides; Titanium oxides

Indexed keywords

BAND STRUCTURE; CHEMICAL BONDS; CHEMICAL COMPOUNDS; GAS EMISSIONS; MICROWAVE HEATING; MICROWAVES; NITRIDES; QUANTUM CHEMISTRY; TITANIUM; TITANIUM OXIDES;

DENSITY OF ELECTRONS; ELECTRON HEATING; ELECTRONIC ENERGIES; EMISSION BEHAVIOR; HIGH VACUUM SYSTEMS; MICROWAVE FIELD; QUANTUM CHEMICAL; SITU REDUCTION;

TITANIUM NITRIDE;

EID: 84855306425     PISSN: 02540584     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.matchemphys.2011.08.050     Document Type: Article

References (16)

1. N. Yoshikawa, E. Ishizuka, K. ichi Mashiko, S. Taniguchi, Difference in carbothermal reduction reaction kinetics of NiO in microwave E- and H-fields, Mater. Lett. 61 (2007) 2096-2099.
2. S. Sano, S. Takayama, Y. Takao, A. Suzuki, Y. Makino, Microwave absorption behavior of iron-alumina mixed powder at elevated temperature, ISIJ Int. 47 (2007) 588-591.
3. X. Huang, Novel Direct Steelmaking by Combining Microwave, Electric Arc and Exothermal Heating Technologies, Final Technical Report, 2005, pp. 40-48.
4. K. Ishizaki, K. Nagata, T. Hayashi, Localized heating and reduction of magnetite ore with coal in composite pellets using microwave irradiation, ISIJ Int. 47 (6) (2007) 817-822.
5. T. Kimura, H. Takizawa, K. Uheda, T. Endo, Synthesis of metal nitride by microwave irradiation, J. Jpn. Soc. Powder Powder Metall. 46 (1998) 378-382.
6. J.H. Booske, R.F. Cooper, S.A. Freeman, Microwave enhanced reaction kinetics in ceramics, Mater. Res. Innovat. 1 (1997) 77-84.
7. Y.V. Bykov, K.I. Rybakov, V.E. Semenov, High-temperature microwave processing of materials, J. Phys. D: Appl. Phys. 34 (13) (2001) 55.
8. M. Tanaka, H. Kono, K. Maruyama, Selective heating mechanism of magnetic metal oxides by a microwave magnetic field, Phys. Rev. B 79 (2009).
9. M.M. Gunter, C. Korte, G. Brunauer, H. Boysen, M. Lerch, E. Suard, In situ high temperature neutron diffraction study of Sr/Mg-doped lanthanum gallate superionic conductors under microwave irradiation, Z. Anorg. Allg. Chem. 631 (2005) 1277-1284.
10. M. Mizuno, I. Tanaka, H. Adachi, Chemical bonding in titanium-metalloid compounds, Phys. Rev. B 59 (1999).
11. K. Kashimura, J. Fukushima, M. Sato, Oxygen partial pressure change with metal titanium powder nitriding under microwave heating, ISIJ Int. 51 (2011) 181-185.
12. R. Roy, P. Peelamedu, L. Hurtt, J.P. Cheng, D. Agrawal, Definitive experimental evidence for microwave effects: radically new effects of separated E and H fields, such as decrystallization of oxides in seconds, Mater. Res. Innovat. 6 (2002) 128-140.
13. K.I. Rybakov, V.E. Semenov, S.A. Freeman, J.H. Booske, R.F. Cooper, Dynamics of microwave-induced currents in ionic crystals, Phys. Rev. B 55 (6) (1997) 2468-2559.
14. S.A. Freeman, J.H. Booske, R.F. Cooper, Modeling and numerical simulations of microwave-induced ionic transport, Appl. Phys. 83 (11) (1998) 2468-2559.
15. H. Adachi, S. Imoto, Cluster model for electronic structure and bonding mechanism of interstitial hydrogen in iron series transition metals, J. Phys. Soc. Jpn. 46 (1978) 1194-1200.
16. C. Kittel, Introduction to Solid State Physics, 7th ed., John Wiley & Sons, Inc., 1996.