The X-ray structure of Fe( fulvene) 2: The missing link in the direct synthesis of ansa- and Cpi-metallocenes (Cpi = C5H4CHMe2)

Journal of Organometallic Chemistry

Volumn 545-546, Issue , 1997, Pages 105-110

  Teuber, Roland ^a   Köppe, Ralf ^a   Linti, Gerald ^a   Tacke, Matthias ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Ab initio calculation; Bis(fulvene)iron; Cocondensation; Fulvenes; Iron; Reaction mechanism

Indexed keywords

EID: 8444251662     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(97)00267-2     Document Type: Article

References (23)

1. [1] K.J. Jens, F. Edelmann, U. Behrens, Chem. Ber. 111 (1978) 2895.
2. [2] A. Christophides, J.A.K. Howard, J.L. Spencer, F.G.A. Stone, J. Organomet. Chem. 232 (1982) 279.
3. [3] F. Edelmann, B. Lubke, U. Behrens, Chem. Ber. 115 (1982) 1325.
4. [4] R.L. Cooper, E.O. Fischer, W. Semmlinger, J. Organomet. Chem., 9 (1967) 333; V.G. Andrianov, Y.T. Struchkov, V.N. Setkina, V.I. Zdanovich, A.'Zh. Zhakaeva, D.N. Kursanov, J. Chem. Soc. Chem. Comm. (1975) 117.
5. [4] R.L. Cooper, E.O. Fischer, W. Semmlinger, J. Organomet. Chem., 9 (1967) 333; V.G. Andrianov, Y.T. Struchkov, V.N. Setkina, V.I. Zdanovich, A.'Zh. Zhakaeva, D.N. Kursanov, J. Chem. Soc. Chem. Comm. (1975) 117.
6. [5] U. Behrens, E. Weiss, J. Organomet. Chem. 96 (1975) 399.
7. [6] E.O. Fischer, B.J. Weimann, Z. Naturforschg. 21b (1966) 84.
8. [7] E.O. Fischer, B.J. Weimann, J. Organomet. Chem. 8 (1967) 535.
9. [8] O. Koch, F. Edelmann, U. Behrens, Chem. Ber. 115 (1982) 1305.
10. [9] T.S. Tan, J.L. Fletcher, M.J. McGlinchey, J. Chem. Soc. Chem. Comm. 19 (1975) 771.
11. [10] U. Zenneck, W. Frank, Angew. Chem. 98 (1986) 806; U. Zenneck, W. Frank, Int. Ed. Engl. 25 (1986) 1129.
12. [10] U. Zenneck, W. Frank, Angew. Chem. 98 (1986) 806; U. Zenneck, W. Frank, Int. Ed. Engl. 25 (1986) 1129.
13. [11] U. Zenneck, L. Suber, H. Pritzkow, W. Seibert, Chem. Ber. 119 (1986) 971.
14. [12] M. Tacke, Organomet. 13 (1994) 4124.
15. [13] Force field calculations were carried out with HyperChem Molecular Modelling System by Hypercube, Inc. and Autodesk, Inc., 1993.
16. [14] N. Norman, B. Post, Acta Cryst. 14 (1961) 503.
17. [15] R. Böhme, H. Burzlaff, Chem. Ber. 107 (1974) 832.
18. [16] Fry, A.J., Synthetic Organic Electrochemistry, Wiley, New York, 1989.
19. [17] K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 242 (1995) 652.
20. [18] The Program System TURBOMOLE, R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Lett. 162 (1989) 165.
21. [19] R. Heinzmann, R. Ahlrichs, Theoret. Chim. Acta 42 (1976) 33.
22. [20] C. Ehrhardt, R. Ahlrichs, Theoret. Chim. Acta 68 (1985) 231.
23. [21] H. McCain, J. Org. Chem 23 (1958) 632.