A new application of high-viscosity kinetics. An attempt to identify a site of solvent reorganizations around a reactant

Bulletin of the Chemical Society of Japan

Volumn 77, Issue 10, 2004, Pages 1803-1806

  Sugita, Keijiro ^a   Goto, Yoshitaka ^a   Ono, Mikiko ^a   Yamashita, Kazumi ^a   Hayase, Kayoko ^a   Takahashi, Toru ^a   Ohga, Yasushi ^a   Asano, Tsutomu ^a  

^a OITA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; PHOTOCHEMICAL REACTIONS; SOLVENTS; VISCOSITY;

CHROMENES; THERMAL FADING; VISCOUS MEDIA;

KINETIC THEORY;

1 (3 METHYLBUT 2 ENYLIDENE)NAPHTHALEN 2 ONE; 1 (3,3 DIPHENYLPROP 2 ENYLIDENE)NAPHTHALEN 2 ONE; 10 (3,3 DIPHENYLPROP 2 ENYLIDENE)PHENANTHREN 9 ONE; 2 METHYLPENTANE 2,4 DIOL; NAPHTHALENE DERIVATIVE; SOLVENT; TRIACETIN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CYCLIZATION; ENTHALPY; ENTROPY; KINETICS; PHOTOCHEMISTRY; TEMPERATURE; VISCOSITY;

EID: 8444240133     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.77.1803     Document Type: Article

References (23)

1. C. Reichardt, "Solvents and Solvents Effects in Organic Chemistry, 3rd ed," Wiley-VCH, Weinheim (2003).
2. A. Drljaca, C. D. Hubbard, R. van Eldik, T. Asano, M. V. Basilevsky, and W. J. le Noble, Chem. Rev., 98, 2167 (1998), and earlier reviews cited therein.
3. For examples see Ref. 2.
4. T. Asano, H. Furuta, and H. Sumi, J. Am. Chem. Soc., 116, 5545 (1994).
5. N. Agmon and J. J. Hopfield, J. Chem. Phys., 78, 6947 (1983).
6. N. Agmon and J. J. Hopfield, J. Chem. Phys., 79, 2042 (1983).
7. H. Sumi and R. A. Marcus, J. Chem. Phys., 84, 4894 (1986).
8. H. Sumi, J. Phys. Chem., 95, 3334 (1991).
9. A. M. Berezhkovskii and V. Yu. Zitserman, Chem. Phys. Lett., 158, 369 (1989).
10. A. M. Berezhkovskii, Yu. A. D'yakov, and V. Yu. Zitserman, J. Chem. Phys., 109, 4182 (1998).
11. A. M. Berezhkovskii, V. Yu. Zitserman, D.-Y. Yang, J. Kuo, and S. H. Lin, Physica A, 251, 399 (1998).
12. M. V. Basilevsky, V. M. Ryaboy, and N. N. Weinberg, J. Phys. Chem., 94, 8734 (1990).
13. M. V. Basilevsky, V. M. Ryaboy, and N. N. Weinberg, J. Phys. Chem., 95, 5533 (1991).
14. T. Asano, K. Cosstick, H. Furuta, K. Matsuo, and H. Sumi, Bull. Chem. Soc. Jpn., 69, 551 (1996).
15. T. Asano, K. Matsuo, and H. Sumi, Bull. Chem. Soc. Jpn., 70, 239 (1997).
16. J. C. Kim, Y. Ohga, T. Asano, N. N. Weinberg, and A. V. George, Bull. Chem. Soc. Jpn., 74, 103 (2001).
17. Y. Goto, T. Takahashi, Y. Ohga, T. Asano, M. Hildebrand, and N. N. Weinberg, Phys. Chem. Chem. Phys., 5, 1825 (2003).
18. H. Kono, H. Osako, M. Sasaki, T. Takahashi, Y. Ohga, T. Asano, M. Hildebrand, and N. N. Weinberg, Phys. Chem. Chem. Phys., 6, 2260 (2004).
19. J.-L. Pozzo, A. Samat, R. Guglielmetti, R. Dubest, and J. Aubard, Helv. Chim. Acta, 80, 725 (1997).
20. T. Asano, Pure Appl. Chem., 71, 1691 (1999).
21. T. Asano and T. Okada, J. Phys. Chem., 88, 238 (1984).
22. 23 of the reactants were, 2.71 D (1a), 0.76 D (1b), 2.66 D (2a), 0.65 D (2b), 2.24 D (3a), and 0.40 D (3b).
23. "MacSpartan Pro," Wavefunction, Inc., 18401 Von Karman Avenue, Suit 370 Irvine, CA 92612, USA (2000).