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Volumn 13, Issue 24, 2011, Pages 6556-6559

Electronic-state switching strategy in the photochemical synthesis of indanones from o-methyl phenacyl epoxides

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EID: 84055178151     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol202892r     Document Type: Article
Times cited : (11)

References (33)
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    • 84055221178 scopus 로고    scopus 로고
    • Note: In our case, the system of the two triplet states can be well described by single determinantal methods, such as DFT, as evidenced by preliminary CASSCF calculations
    • Note: In our case, the system of the two triplet states can be well described by single determinantal methods, such as DFT, as evidenced by preliminary CASSCF calculations.
  • 32
    • 84055221179 scopus 로고    scopus 로고
    • Note: In fact, the indanone 13 is poorly soluble in hexane and precipitates at the concentrations used, which may considerably decrease the efficiency of unwanted secondary photoreactions. Moreover, the yield of 13 formation could be, in principle, improved by setting the irradiation wavelength to approximately 266 nm, where the ratio of the absorption coefficients of 10 and 13 reaches its maximum (see Figures S24 and S25 in the Supporting Information)
    • (b) Note: In fact, the indanone 13 is poorly soluble in hexane and precipitates at the concentrations used, which may considerably decrease the efficiency of unwanted secondary photoreactions. Moreover, the yield of 13 formation could be, in principle, improved by setting the irradiation wavelength to approximately 266 nm, where the ratio of the absorption coefficients of 10 and 13 reaches its maximum (see Figures S24 and S25 in the Supporting Information).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.