Reversing the reactivity of carbonyl functions with phosphonium salts: Enantioselective total synthesis of (+)-centrolobine

Angewandte Chemie - International Edition

Volumn 50, Issue 51, 2011, Pages 12232-12235

  Fujioka, Hiromichi ^a   Yahata, Kenzo ^a   Kubo, Ozora ^a   Sawama, Yoshinari ^a   Hamada, Tomohito ^a   Maegawa, Tomohiro ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

alkylations; carbonyl reactivity; natural products; phosphonium salts; reductions

Indexed keywords

ALKYLATION REACTIONS; ASYMMETRIC TOTAL SYNTHESIS; CARBONYL FUNCTION; CARBONYL GROUPS; ENANTIOSELECTIVE TOTAL SYNTHESIS; NATURAL PRODUCTS; PHOSPHONIUM SALTS; TRIMETHYLSILYL;

ALKYLATION; REDUCTION; SALTS;

SYNTHESIS (CHEMICAL);

ALDEHYDE; CENTROLOBIN; KETONE; ORGANOPHOSPHORUS COMPOUND; PYRAN DERIVATIVE;

ALKYLATION; ARTICLE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALDEHYDES; ALKYLATION; KETONES; ORGANOPHOSPHORUS COMPOUNDS; PYRANS; STEREOISOMERISM;

EID: 83755184128     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201106046     Document Type: Article

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