Nanoscale inhomogeneities in thermoresponsive triblock copolymers

ChemPhysChem

Volumn 12, Issue 18, 2011, Pages 3566-3572

  Kurzbach, Dennis ^a   Reh, Miriam N ^a   Hinderberger, Dariush ^a  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

EPR ESR spectroscopy; nano inhomogeneities; Pluronics; polymers; spin probing

Indexed keywords

BLOCK COPOLYMERS; ETHYLENE; HYDROPHOBICITY; MOLECULES; PARAMAGNETIC RESONANCE; POLYETHYLENE OXIDES; POLYMERS; PROBES;

2 ,2 ,6 ,6-TETRAMETHYLPIPERIDINE-1-OXYL; BROAD TEMPERATURE RANGES; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; EPR/ESR; NANO-INHOMOGENEITIES; NANOSCALE INHOMOGENEITIES; PLURONICS; SPIN PROBING;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

EID: 83755172182     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.201100474     Document Type: Article

References (31)

1. A. V. Kabanov, E. V. Batrakova, V. Y. Alakhov, J. Controlled Release 2002, 82, 189-212.
2. P. Alexandridis, T. A. Hatton, Colloids Surf. A 1995, 96, 1-46
3. P. Linse, M. Malmsten, Macromolecules 1992, 25, 5434-5439
4. I. Goldmints, F. K. v. Gottberg, K. A. Smith, T. A. Hatton, Langmuir 1997, 13, 3659-3664
5. A. Åturcová, P. Schmidt, J. Dybal, J. Colloid Interface Sci. 2010, 352, 415-423
6. G. Wanka, H. Hoffmann, W. Ulbricht, Macromolecules 1994, 27, 4145-4159
7. P. Alexandridis, V. Athanassiou, S. Fukuda, T. A. Hatton, Langmuir 1994, 10, 2604-2612
8. M. Malmsten, B. Lindman, Macromolecules 1992, 25, 5440-5445.
9. A. V. Kabanov, I. R. Nazarova, I. V. Astafieva, E. V. Batrakova, V. Y. Alakhov, A. A. Yaroslavov, V. A. Kabanov, Macromolecules 1995, 28, 2303-2314
10. P. Alexandridis, J. F. Holzwarth, T. A. Hatton, Macromolecules 1994, 27, 2414-2425.
11. D. Baute, D. Goldfarb, J. Phys. Chem. C 2007, 111, 10931-10940
12. S. Ruthstein, A. Potapov, A. M. Raitsimring, D. Goldfarb, J. Phys. Chem. B 2005, 109, 22843-22851
13. S. Ruthstein, A. M. Raitsimring, R. Bitton, V. Frydman, A. Godt, D. Goldfarb, Phys. Chem. Chem. Phys. 2009, 11, 148-160
14. G. Martini, L. Ciani, Phys. Chem. Chem. Phys. 2009, 11, 211-254
15. M. Florent, R. Shvartzman-Cohen, D. Goldfarb, R. Yerushalmi-Rozen, Langmuir 2008, 24, 3773-3779.
16. M. J. N. Junk, W. Li, A. D. Schlüter, G. Wegner, H. W. Spiess, A. Zhang, D. Hinderberger, Angew. Chem. 2010, 122, 5818-5823
17. Angew. Chem. Int. Ed. 2010, 49, 5683-5687
18. M. J. N. Junk, U. Jonas, D. Hinderberger, Small 2008, 4, 1485-1493.
19. A. Caragheorgheopol, H. Caldararu, I. Dragutan, H. Joela, W. Brown, Langmuir 1997, 13, 6912-6921
20. A. Caragheorgheopol, S. Schlick, Macromolecules 1998, 31, 7736-7745
21. R. Shvartzman-Cohen, I. Monje, M. Florent, V. Frydman, D. Goldfarb, R. Yerushalmi-Rozen, Macromolecules 2010, 43, 606-614
22. M. Vasilescu, A. Caragheorgheopol, H. Caldararu, R. Bandula, H. Lemmetyinen, H. Joela, J. Phys. Chem. B 1998, 102, 7740-7751
23. L. Zhou, S. Schlick, Polymer 2000, 41, 4679-4689.
24. S. Stoll, A. Schweiger, J. Magn. Reson. 2006, 178, 42-55.
25. M. J. N. Junk, W. Li, A. D. Schlüter, G. Wegner, H. W. Spiess, A. Zhang, D. Hinderberger, Macromol. Chem. Phys. 2011, 212, 1229-1235
26. M. J. N. Junk, W. Li, A. D. Schlüter, G. Wegner, H. W. Spiess, A. Zhang, D. Hinderberger, J. Am. Chem. Soc. 2011, 133, 10832-10838.
27. Note that the high-field line of TEMPO in aqueous solutions also shifts to the low field, approximately 0.7 MHz between 10 and 90°C. Hence, the overall shift of 1.0 MHz of the highfield line of species A has to be corrected to ∼0.3 MHz.
28. P. Linse, Macromolecules 1993, 26, 4437-4449.
29. P. Alexandridis, T. Nivaggioli, T. A. Hatton, Langmuir 1995, 11, 1468-1476.
30. K. Mortensen, J. S. Petersen, Macromolecules 1993, 26, 805-812.
31. J. H. Freed, G. K. Fraenkel, J. Chem. Phys. 1963, 39, 326-348.