Interaction of morpholine and thiomorpholine with molecular diiodine: X-ray crystal structure of morpholinium triiodide

Heteroatom Chemistry

Volumn 8, Issue 2, 1997, Pages 139-146

  Arca, Massimiliano ^a   Cristiani, Franco ^a   Devillanova, Francesco A ^a   Garau, Alessandra ^a   Isaia, Francesco ^a   Lippolis, Vito ^a   Verani, Gaetano ^a   Demartin, Francesco ^b  

^a UNIVERSITY OF CAGLIARI   (Italy)

^b CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 8344228612     PISSN: 10427163     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1098-1071(1997)8:2<139::AID-HC6>3.0.CO;2-9     Document Type: Article

References (26)

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23. The bond order, n, is calculated according to Pauling's equation d = 2.677 - c log(n); d is the d(I-I) in the coordinated molecule in Å, 2.677 Å the d(I-I) in gaseous diiodine, and c = 0.85 Å an empirical constant.
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25. The comparison of the Ks of 1 and 3 underlines the inductive effect of the methyl on the donor properties of nitrogen, whereas that of 1 and 2 shows the influ-ence of the different chalcogen atoms (O,S) present in the ring.
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